Synthesis, Molecular Structure and Reactions of Stable Square-Planar 16-Electron Ruthenium(0) Complexes: trans-[RuCl(NO)(PR3)2]

Synthesis, Molecular Structure and Reactions of Stable Square-Planar 16-Electron Ruthenium(0) Complexes: trans-[RuCl(NO)(PR3)2]

The reduction of [RuCl3(NO)(PPh3)2] (1) with Zn/Cu generates [RuCl(NO)(PPh3)2] that by ligand exchange with PR3 (R3  iPr3, iPr2Ph) affords the stable 16‐electron ruthenium (0) complexes trans‐[RuCl(NO)(PR3)2] (2, 3). The X‐ray structural analysis of 2 confirmed the square‐planar geometry around the...

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Veröffentlicht in:Chemische Berichte 1996-09, Vol.129 (9), p.1007-1013
Hauptverfasser: Flügel, Ruth, Windmüller, Bettina, Gevert, Olaf, Werner, Helmut
Format: Artikel
Sprache:eng
Schlagworte:
Dioxygenruthenium complexes
metal-assisted oxidation of
Nitrosyl complexes
Oxidative addition reactions
Ruthenium complexes
Sulfur dioxide
Sulfur dioxide, metal‐assisted oxidation of
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container_end_page 1013
container_issue 9
container_start_page 1007
container_title Chemische Berichte
container_volume 129
creator Flügel, Ruth
Windmüller, Bettina
Gevert, Olaf
Werner, Helmut
description The reduction of [RuCl3(NO)(PPh3)2] (1) with Zn/Cu generates [RuCl(NO)(PPh3)2] that by ligand exchange with PR3 (R3  iPr3, iPr2Ph) affords the stable 16‐electron ruthenium (0) complexes trans‐[RuCl(NO)(PR3)2] (2, 3). The X‐ray structural analysis of 2 confirmed the square‐planar geometry around the metal center. HCl oxidatively adds to 2 and 3 to give the octahedral ruthenium(II) compounds [RuHCl2(NO)(PR3)2] (4, 5). On treatment of 2 and 3 with CO, TCNE, CH2 (generated from CH2N2) and O2, five‐coordinate 1:1 adducts [RuCl(NO)(L)(PR3)2] (6–12) are formed. The dioxygen complexes 11 and 12 react with SO2 to afford the sulfatoruthenium(II) derivatives [RuCl(NO){η2(O,O)‐O2SO2}(PR3)2] (13, 14). Compound 13 (R3  PiPr3) has been characterized by X‐ray structural analysis.
doi_str_mv 10.1002/cber.19961290906
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The X‐ray structural analysis of 2 confirmed the square‐planar geometry around the metal center. HCl oxidatively adds to 2 and 3 to give the octahedral ruthenium(II) compounds [RuHCl2(NO)(PR3)2] (4, 5). On treatment of 2 and 3 with CO, TCNE, CH2 (generated from CH2N2) and O2, five‐coordinate 1:1 adducts [RuCl(NO)(L)(PR3)2] (6–12) are formed. The dioxygen complexes 11 and 12 react with SO2 to afford the sulfatoruthenium(II) derivatives [RuCl(NO){η2(O,O)‐O2SO2}(PR3)2] (13, 14). Compound 13 (R3  PiPr3) has been characterized by X‐ray structural analysis.</description><identifier>ISSN: 0009-2940</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/cber.19961290906</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Dioxygenruthenium complexes ; metal-assisted oxidation of ; Nitrosyl complexes ; Oxidative addition reactions ; Ruthenium complexes ; Sulfur dioxide ; Sulfur dioxide, metal‐assisted oxidation of</subject><ispartof>Chemische Berichte, 1996-09, Vol.129 (9), p.1007-1013</ispartof><rights>Copyright © 1996 WILEY‐VCH Verlag GmbH &amp; Co. 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Ber</addtitle><description>The reduction of [RuCl3(NO)(PPh3)2] (1) with Zn/Cu generates [RuCl(NO)(PPh3)2] that by ligand exchange with PR3 (R3  iPr3, iPr2Ph) affords the stable 16‐electron ruthenium (0) complexes trans‐[RuCl(NO)(PR3)2] (2, 3). The X‐ray structural analysis of 2 confirmed the square‐planar geometry around the metal center. HCl oxidatively adds to 2 and 3 to give the octahedral ruthenium(II) compounds [RuHCl2(NO)(PR3)2] (4, 5). On treatment of 2 and 3 with CO, TCNE, CH2 (generated from CH2N2) and O2, five‐coordinate 1:1 adducts [RuCl(NO)(L)(PR3)2] (6–12) are formed. The dioxygen complexes 11 and 12 react with SO2 to afford the sulfatoruthenium(II) derivatives [RuCl(NO){η2(O,O)‐O2SO2}(PR3)2] (13, 14). Compound 13 (R3  PiPr3) has been characterized by X‐ray structural analysis.</description><subject>Dioxygenruthenium complexes</subject><subject>metal-assisted oxidation of</subject><subject>Nitrosyl complexes</subject><subject>Oxidative addition reactions</subject><subject>Ruthenium complexes</subject><subject>Sulfur dioxide</subject><subject>Sulfur dioxide, metal‐assisted oxidation of</subject><issn>0009-2940</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNqF0M1LwzAYBvAgCs7p3WOOGxh9m3TJInjQOp343SmCIiFNU6x2rSYtbif_dSsT0ZOn9_A-v-fwILQZwHYAQHdMYt12ICUPqAQJfAl1ApCSAB_SZdQBAEmoDGEVrXn_DMBCwVkHfUzmZf1kfe638HlVWNMU2uFJ7RpTN85iXaY4ttrUeVV6XGXtSyeFxZO3RjtLrgpdtvmAk1Fra1eVOG7avjJvpj3o46iavhZ2Zv0urp0uPXmIm6joXVz2e1cx69PHdbSS6cLbje_bRbdHo5toTM4uj0-i_TNiGGOcCCqMSBOgMglEGg6HdBAy4FwbSDkTIQ2zQZrQRPKMGQpacMsgGWojs5BJM2BdBIte4yrvnc3Uq8un2s1VAOprQPU1oPo1YEv2FuQ9L-z837yKDkbxX08WPve1nf147V4UF0wM1N3Fsbq-Px0fXctDdcM-AUwAhJM</recordid><startdate>199609</startdate><enddate>199609</enddate><creator>Flügel, Ruth</creator><creator>Windmüller, Bettina</creator><creator>Gevert, Olaf</creator><creator>Werner, Helmut</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>199609</creationdate><title>Synthesis, Molecular Structure and Reactions of Stable Square-Planar 16-Electron Ruthenium(0) Complexes: trans-[RuCl(NO)(PR3)2]</title><author>Flügel, Ruth ; Windmüller, Bettina ; Gevert, Olaf ; Werner, Helmut</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3336-727c7db029b17d4882543066ac0d637424f5db2b96f3c20a76e30b8ac9f439c53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><topic>Dioxygenruthenium complexes</topic><topic>metal-assisted oxidation of</topic><topic>Nitrosyl complexes</topic><topic>Oxidative addition reactions</topic><topic>Ruthenium complexes</topic><topic>Sulfur dioxide</topic><topic>Sulfur dioxide, metal‐assisted oxidation of</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Flügel, Ruth</creatorcontrib><creatorcontrib>Windmüller, Bettina</creatorcontrib><creatorcontrib>Gevert, Olaf</creatorcontrib><creatorcontrib>Werner, Helmut</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Chemische Berichte</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Flügel, Ruth</au><au>Windmüller, Bettina</au><au>Gevert, Olaf</au><au>Werner, Helmut</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Molecular Structure and Reactions of Stable Square-Planar 16-Electron Ruthenium(0) Complexes: trans-[RuCl(NO)(PR3)2]</atitle><jtitle>Chemische Berichte</jtitle><addtitle>Chem. Ber</addtitle><date>1996-09</date><risdate>1996</risdate><volume>129</volume><issue>9</issue><spage>1007</spage><epage>1013</epage><pages>1007-1013</pages><issn>0009-2940</issn><eissn>1099-0682</eissn><abstract>The reduction of [RuCl3(NO)(PPh3)2] (1) with Zn/Cu generates [RuCl(NO)(PPh3)2] that by ligand exchange with PR3 (R3  iPr3, iPr2Ph) affords the stable 16‐electron ruthenium (0) complexes trans‐[RuCl(NO)(PR3)2] (2, 3). The X‐ray structural analysis of 2 confirmed the square‐planar geometry around the metal center. HCl oxidatively adds to 2 and 3 to give the octahedral ruthenium(II) compounds [RuHCl2(NO)(PR3)2] (4, 5). On treatment of 2 and 3 with CO, TCNE, CH2 (generated from CH2N2) and O2, five‐coordinate 1:1 adducts [RuCl(NO)(L)(PR3)2] (6–12) are formed. The dioxygen complexes 11 and 12 react with SO2 to afford the sulfatoruthenium(II) derivatives [RuCl(NO){η2(O,O)‐O2SO2}(PR3)2] (13, 14). Compound 13 (R3  PiPr3) has been characterized by X‐ray structural analysis.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/cber.19961290906</doi><tpages>7</tpages></addata></record>
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subjects Dioxygenruthenium complexes
metal-assisted oxidation of
Nitrosyl complexes
Oxidative addition reactions
Ruthenium complexes
Sulfur dioxide
Sulfur dioxide, metal‐assisted oxidation of
title Synthesis, Molecular Structure and Reactions of Stable Square-Planar 16-Electron Ruthenium(0) Complexes: trans-[RuCl(NO)(PR3)2]
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