The Catalytic Ring‐opening Cyclooligomerization (ROC) of Thietane by the Complexes M(CO) 5 L (M Cr and W; L = CO, thietane and 1,5,9‐Trithiacyclododecane)
The following four compounds have been synthesized: M(CO) 5 L ( 3 and 4 , where M = Cr and W, and L = H 2 ), W(CO) 5 (12S3) ( 5 , where 12S3 = 1,5,9‐trithia‐cyclododecane), and [W(CO) 5 ] 2 (12S3) ( 6 ). The molecular structures of 4 and 5 were established by single‐crystal X‐ray diffraction analyse...
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| Veröffentlicht in: | Chemische Berichte 1996-03, Vol.129 (3), p.313-318 |
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| creator | Adams, Richard D. Falloon, Stephen B. Perrin, Joseph L. Queisser, Joachim A. Yamamoto, John H. |
| description | The following four compounds have been synthesized: M(CO)
5
L (
3
and
4
, where M = Cr and W, and L =
H
2
), W(CO)
5
(12S3) (
5
, where 12S3 = 1,5,9‐trithia‐cyclododecane), and [W(CO)
5
]
2
(12S3) (
6
). The molecular structures of
4
and
5
were established by single‐crystal X‐ray diffraction analyses. Both compounds contain a W(CO)
5
group coordinated to one of the sulfur atoms of the hetero‐cycle. The ability of the compounds M(CO)
6
,
1
and
2
(M = Cr and W), and
3 – 5
to catalytically produce ring opening cyclooligomerization (ROC) of thietane into 12S3 and 24S6, (24S6 = 1,5,9,13,17,21‐hexathiacyclotetracosane) has been investigated. Compounds
1 – 3
have relatively low activity. Compounds
4
and
5
have the highest activity and selectivity for 12S3 formation. Crystal Data for
4
: space group =
P
2
1
2
1
2
1
,
a
= 12.906(2) Å,
b
= 13.730(4) Å,
c
= 6.427(1) Å,
Z
=
4
, 1306 reflections,
R
= 0.033; for
5
: space group =
P
1¯,
a
= 12.703(1) Å,
b
= 13.510(2) Å,
c
= 5.833(1) Å, α = 101.75(1)°, β = 97.54(1)°, γ = 101.70(1)°,
Z
= 2, 2225 reflections,
R
= 0.023. |
| doi_str_mv | 10.1002/cber.19961290311 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1002_cber_19961290311</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1002_cber_19961290311</sourcerecordid><originalsourceid>FETCH-LOGICAL-c881-d8ab7f2e86653d7f0a86b7b5b2995a6c276e32d2342131edf6cc6c82fcc2fec53</originalsourceid><addsrcrecordid>eNpNkMtKw0AUhrNQsFb3Ls-yhabOpZlkEBcyeIOWQAm4DJPJTDuSZsokC-PKR_AZ9D18GF_AVzDBLlydw89_gS8ILjCaY4TIpSq0n2POGSYcUYyPghFCiIeEL9BJcNo0zwjRRczoKPjIthqEbGXVtVbB2tab77d3t9d1_4HoVOVcZTdup719la11NUzWqZiCM5BtrW5lraHooB1q3G5f6RfdwGoi0ilEsITJCn4-v0B4kHUJT1e9dA0infWBQ3jQ8Sya8X4387bXpRpmS1dq1RumZ8GxkVWjzw93HGR3t5l4CJfp_aO4WYYqSXBYJrKIDdEJYxEtY4Nkwoq4iArCeSSZIjHTlJSELgimWJeGKcVUQoxSxGgV0XGA_mqVd03jtcn33u6k73KM8gFrPmDN_2Glv2c7b2M</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>The Catalytic Ring‐opening Cyclooligomerization (ROC) of Thietane by the Complexes M(CO) 5 L (M Cr and W; L = CO, thietane and 1,5,9‐Trithiacyclododecane)</title><source>Wiley Online Library All Journals</source><creator>Adams, Richard D. ; Falloon, Stephen B. ; Perrin, Joseph L. ; Queisser, Joachim A. ; Yamamoto, John H.</creator><creatorcontrib>Adams, Richard D. ; Falloon, Stephen B. ; Perrin, Joseph L. ; Queisser, Joachim A. ; Yamamoto, John H.</creatorcontrib><description>The following four compounds have been synthesized: M(CO)
5
L (
3
and
4
, where M = Cr and W, and L =
H
2
), W(CO)
5
(12S3) (
5
, where 12S3 = 1,5,9‐trithia‐cyclododecane), and [W(CO)
5
]
2
(12S3) (
6
). The molecular structures of
4
and
5
were established by single‐crystal X‐ray diffraction analyses. Both compounds contain a W(CO)
5
group coordinated to one of the sulfur atoms of the hetero‐cycle. The ability of the compounds M(CO)
6
,
1
and
2
(M = Cr and W), and
3 – 5
to catalytically produce ring opening cyclooligomerization (ROC) of thietane into 12S3 and 24S6, (24S6 = 1,5,9,13,17,21‐hexathiacyclotetracosane) has been investigated. Compounds
1 – 3
have relatively low activity. Compounds
4
and
5
have the highest activity and selectivity for 12S3 formation. Crystal Data for
4
: space group =
P
2
1
2
1
2
1
,
a
= 12.906(2) Å,
b
= 13.730(4) Å,
c
= 6.427(1) Å,
Z
=
4
, 1306 reflections,
R
= 0.033; for
5
: space group =
P
1¯,
a
= 12.703(1) Å,
b
= 13.510(2) Å,
c
= 5.833(1) Å, α = 101.75(1)°, β = 97.54(1)°, γ = 101.70(1)°,
Z
= 2, 2225 reflections,
R
= 0.023.</description><identifier>ISSN: 0009-2940</identifier><identifier>DOI: 10.1002/cber.19961290311</identifier><language>eng</language><ispartof>Chemische Berichte, 1996-03, Vol.129 (3), p.313-318</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c881-d8ab7f2e86653d7f0a86b7b5b2995a6c276e32d2342131edf6cc6c82fcc2fec53</citedby><cites>FETCH-LOGICAL-c881-d8ab7f2e86653d7f0a86b7b5b2995a6c276e32d2342131edf6cc6c82fcc2fec53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Adams, Richard D.</creatorcontrib><creatorcontrib>Falloon, Stephen B.</creatorcontrib><creatorcontrib>Perrin, Joseph L.</creatorcontrib><creatorcontrib>Queisser, Joachim A.</creatorcontrib><creatorcontrib>Yamamoto, John H.</creatorcontrib><title>The Catalytic Ring‐opening Cyclooligomerization (ROC) of Thietane by the Complexes M(CO) 5 L (M Cr and W; L = CO, thietane and 1,5,9‐Trithiacyclododecane)</title><title>Chemische Berichte</title><description>The following four compounds have been synthesized: M(CO)
5
L (
3
and
4
, where M = Cr and W, and L =
H
2
), W(CO)
5
(12S3) (
5
, where 12S3 = 1,5,9‐trithia‐cyclododecane), and [W(CO)
5
]
2
(12S3) (
6
). The molecular structures of
4
and
5
were established by single‐crystal X‐ray diffraction analyses. Both compounds contain a W(CO)
5
group coordinated to one of the sulfur atoms of the hetero‐cycle. The ability of the compounds M(CO)
6
,
1
and
2
(M = Cr and W), and
3 – 5
to catalytically produce ring opening cyclooligomerization (ROC) of thietane into 12S3 and 24S6, (24S6 = 1,5,9,13,17,21‐hexathiacyclotetracosane) has been investigated. Compounds
1 – 3
have relatively low activity. Compounds
4
and
5
have the highest activity and selectivity for 12S3 formation. Crystal Data for
4
: space group =
P
2
1
2
1
2
1
,
a
= 12.906(2) Å,
b
= 13.730(4) Å,
c
= 6.427(1) Å,
Z
=
4
, 1306 reflections,
R
= 0.033; for
5
: space group =
P
1¯,
a
= 12.703(1) Å,
b
= 13.510(2) Å,
c
= 5.833(1) Å, α = 101.75(1)°, β = 97.54(1)°, γ = 101.70(1)°,
Z
= 2, 2225 reflections,
R
= 0.023.</description><issn>0009-2940</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNpNkMtKw0AUhrNQsFb3Ls-yhabOpZlkEBcyeIOWQAm4DJPJTDuSZsokC-PKR_AZ9D18GF_AVzDBLlydw89_gS8ILjCaY4TIpSq0n2POGSYcUYyPghFCiIeEL9BJcNo0zwjRRczoKPjIthqEbGXVtVbB2tab77d3t9d1_4HoVOVcZTdup719la11NUzWqZiCM5BtrW5lraHooB1q3G5f6RfdwGoi0ilEsITJCn4-v0B4kHUJT1e9dA0infWBQ3jQ8Sya8X4387bXpRpmS1dq1RumZ8GxkVWjzw93HGR3t5l4CJfp_aO4WYYqSXBYJrKIDdEJYxEtY4Nkwoq4iArCeSSZIjHTlJSELgimWJeGKcVUQoxSxGgV0XGA_mqVd03jtcn33u6k73KM8gFrPmDN_2Glv2c7b2M</recordid><startdate>199603</startdate><enddate>199603</enddate><creator>Adams, Richard D.</creator><creator>Falloon, Stephen B.</creator><creator>Perrin, Joseph L.</creator><creator>Queisser, Joachim A.</creator><creator>Yamamoto, John H.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>199603</creationdate><title>The Catalytic Ring‐opening Cyclooligomerization (ROC) of Thietane by the Complexes M(CO) 5 L (M Cr and W; L = CO, thietane and 1,5,9‐Trithiacyclododecane)</title><author>Adams, Richard D. ; Falloon, Stephen B. ; Perrin, Joseph L. ; Queisser, Joachim A. ; Yamamoto, John H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c881-d8ab7f2e86653d7f0a86b7b5b2995a6c276e32d2342131edf6cc6c82fcc2fec53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Adams, Richard D.</creatorcontrib><creatorcontrib>Falloon, Stephen B.</creatorcontrib><creatorcontrib>Perrin, Joseph L.</creatorcontrib><creatorcontrib>Queisser, Joachim A.</creatorcontrib><creatorcontrib>Yamamoto, John H.</creatorcontrib><collection>CrossRef</collection><jtitle>Chemische Berichte</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Adams, Richard D.</au><au>Falloon, Stephen B.</au><au>Perrin, Joseph L.</au><au>Queisser, Joachim A.</au><au>Yamamoto, John H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Catalytic Ring‐opening Cyclooligomerization (ROC) of Thietane by the Complexes M(CO) 5 L (M Cr and W; L = CO, thietane and 1,5,9‐Trithiacyclododecane)</atitle><jtitle>Chemische Berichte</jtitle><date>1996-03</date><risdate>1996</risdate><volume>129</volume><issue>3</issue><spage>313</spage><epage>318</epage><pages>313-318</pages><issn>0009-2940</issn><abstract>The following four compounds have been synthesized: M(CO)
5
L (
3
and
4
, where M = Cr and W, and L =
H
2
), W(CO)
5
(12S3) (
5
, where 12S3 = 1,5,9‐trithia‐cyclododecane), and [W(CO)
5
]
2
(12S3) (
6
). The molecular structures of
4
and
5
were established by single‐crystal X‐ray diffraction analyses. Both compounds contain a W(CO)
5
group coordinated to one of the sulfur atoms of the hetero‐cycle. The ability of the compounds M(CO)
6
,
1
and
2
(M = Cr and W), and
3 – 5
to catalytically produce ring opening cyclooligomerization (ROC) of thietane into 12S3 and 24S6, (24S6 = 1,5,9,13,17,21‐hexathiacyclotetracosane) has been investigated. Compounds
1 – 3
have relatively low activity. Compounds
4
and
5
have the highest activity and selectivity for 12S3 formation. Crystal Data for
4
: space group =
P
2
1
2
1
2
1
,
a
= 12.906(2) Å,
b
= 13.730(4) Å,
c
= 6.427(1) Å,
Z
=
4
, 1306 reflections,
R
= 0.033; for
5
: space group =
P
1¯,
a
= 12.703(1) Å,
b
= 13.510(2) Å,
c
= 5.833(1) Å, α = 101.75(1)°, β = 97.54(1)°, γ = 101.70(1)°,
Z
= 2, 2225 reflections,
R
= 0.023.</abstract><doi>10.1002/cber.19961290311</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0009-2940 |
| ispartof | Chemische Berichte, 1996-03, Vol.129 (3), p.313-318 |
| issn | 0009-2940 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_cber_19961290311 |
| source | Wiley Online Library All Journals |
| title | The Catalytic Ring‐opening Cyclooligomerization (ROC) of Thietane by the Complexes M(CO) 5 L (M Cr and W; L = CO, thietane and 1,5,9‐Trithiacyclododecane) |
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