Nickel Hemiporphyrazines as Bisdienes and Bisdienophiles: Synthesis and Characterization
The bisdienophilic (hemiporphyrazinato)nickel complexes 1a‐d bearing various alkoxy groups were synthesized from diiminoisoindoles 9a‐d, diaminopyridines 10a, d, and nickel acetate. Reaction of 1a‐d with an excess of pentaene 3 delivered the macrocyclic bisdienes 2a‐d. The hemiporphyrezines were cha...
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| Veröffentlicht in: | Chemische Berichte 1996-02, Vol.129 (2), p.237-242 |
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| container_title | Chemische Berichte |
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| creator | Rack, Michael Hauschel, Bernd Hanack, Michael |
| description | The bisdienophilic (hemiporphyrazinato)nickel complexes 1a‐d bearing various alkoxy groups were synthesized from diiminoisoindoles 9a‐d, diaminopyridines 10a, d, and nickel acetate. Reaction of 1a‐d with an excess of pentaene 3 delivered the macrocyclic bisdienes 2a‐d. The hemiporphyrezines were characterized by 1H‐ and 13C‐NMR spectroscopy. The NMR spectra of the 1,6,16,21‐tetrabutoxy‐substituted compounds 1b and 2b are discussed with respect to the presence of syn/anti isomers. |
| doi_str_mv | 10.1002/cber.19961290220 |
| format | Article |
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Reaction of 1a‐d with an excess of pentaene 3 delivered the macrocyclic bisdienes 2a‐d. The hemiporphyrezines were characterized by 1H‐ and 13C‐NMR spectroscopy. The NMR spectra of the 1,6,16,21‐tetrabutoxy‐substituted compounds 1b and 2b are discussed with respect to the presence of syn/anti isomers.</description><identifier>ISSN: 0009-2940</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/cber.19961290220</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Hemiporphyrazines ; Macrocyclic bisdienes and bisdienophiles ; Nickel complexes</subject><ispartof>Chemische Berichte, 1996-02, Vol.129 (2), p.237-242</ispartof><rights>Copyright © 1996 WILEY‐VCH Verlag GmbH & Co. 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Ber</addtitle><description>The bisdienophilic (hemiporphyrazinato)nickel complexes 1a‐d bearing various alkoxy groups were synthesized from diiminoisoindoles 9a‐d, diaminopyridines 10a, d, and nickel acetate. Reaction of 1a‐d with an excess of pentaene 3 delivered the macrocyclic bisdienes 2a‐d. The hemiporphyrezines were characterized by 1H‐ and 13C‐NMR spectroscopy. The NMR spectra of the 1,6,16,21‐tetrabutoxy‐substituted compounds 1b and 2b are discussed with respect to the presence of syn/anti isomers.</description><subject>Hemiporphyrazines</subject><subject>Macrocyclic bisdienes and bisdienophiles</subject><subject>Nickel complexes</subject><issn>0009-2940</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNqFkNFKwzAUhoMoOKf3XvYFOk-StmkEL1xxmzAn6ETvQpqkNG5rS1LQ7undrIpeeXX4Of934HwInWMYYQByoXLjRpjzBBMOhMABGmDgPIQkJYdoAAA8JDyCY3Ti_SsAjVhCB-hlYdXKrIOZ2dimdk3ZObm1lfGB9MHYem3NZ6j0d6qb0q6Nvwweu6otjbf9Niulk6o1zm5la-vqFB0Vcu3N2dccoqfJzTKbhfP76W12PQ8VpRRCxSlmLNYMS6Zjxou0oBorlaucMJKqmOURSJ5iJSlRkS50JI2mWlJpIlVQOkTQ31Wu9t6ZQjTObqTrBAaxNyP2ZsQvMzvkqkfedo90__ZFNr55-MuHPW99a95_eOlWImGUxeJ5MRWTZZKQ5ZyJO_oB6Y56jA</recordid><startdate>199602</startdate><enddate>199602</enddate><creator>Rack, Michael</creator><creator>Hauschel, Bernd</creator><creator>Hanack, Michael</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>199602</creationdate><title>Nickel Hemiporphyrazines as Bisdienes and Bisdienophiles: Synthesis and Characterization</title><author>Rack, Michael ; Hauschel, Bernd ; Hanack, Michael</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3330-c931775d71a7d579f8f3d1ccbcb2728c57b40a981ca32c4dfd4aed3da3ae4cf33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><topic>Hemiporphyrazines</topic><topic>Macrocyclic bisdienes and bisdienophiles</topic><topic>Nickel complexes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rack, Michael</creatorcontrib><creatorcontrib>Hauschel, Bernd</creatorcontrib><creatorcontrib>Hanack, Michael</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Chemische Berichte</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rack, Michael</au><au>Hauschel, Bernd</au><au>Hanack, Michael</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nickel Hemiporphyrazines as Bisdienes and Bisdienophiles: Synthesis and Characterization</atitle><jtitle>Chemische Berichte</jtitle><addtitle>Chem. Ber</addtitle><date>1996-02</date><risdate>1996</risdate><volume>129</volume><issue>2</issue><spage>237</spage><epage>242</epage><pages>237-242</pages><issn>0009-2940</issn><eissn>1099-0682</eissn><abstract>The bisdienophilic (hemiporphyrazinato)nickel complexes 1a‐d bearing various alkoxy groups were synthesized from diiminoisoindoles 9a‐d, diaminopyridines 10a, d, and nickel acetate. Reaction of 1a‐d with an excess of pentaene 3 delivered the macrocyclic bisdienes 2a‐d. The hemiporphyrezines were characterized by 1H‐ and 13C‐NMR spectroscopy. The NMR spectra of the 1,6,16,21‐tetrabutoxy‐substituted compounds 1b and 2b are discussed with respect to the presence of syn/anti isomers.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/cber.19961290220</doi><tpages>6</tpages></addata></record> |
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| source | Access via Wiley Online Library |
| subjects | Hemiporphyrazines Macrocyclic bisdienes and bisdienophiles Nickel complexes |
| title | Nickel Hemiporphyrazines as Bisdienes and Bisdienophiles: Synthesis and Characterization |
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