Synthesis of N- and p-(Diphenylmethyl)anilines. ESR Study of their Photofragmentation

The reaction of N‐substituted anilines 2 with diphenylmethyl halides 1 at room temperature in the presence of AlCl3 affords p‐substituted derivatives 3 in good yields according to an electrophilic aromatic substitution. In contrast, aniline itself is only converted to the N‐substituted compounds 4....

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Veröffentlicht in:	Chemische Berichte 1992-11, Vol.125 (11), p.2477-2481
Hauptverfasser:	Siskos, Michael G., Garas, Stylianos K., Zarkadis, Antonios K., Bokaris, Efthymios P.
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzenamine derivatives Benzenamine derivatives, synthesis of Chemistry Diphenylmethyl radicals ENDOR measurements ESR measurements Exact sciences and technology General and physical chemistry Hofmann-Martius Photochemistry Physical chemistry of induced reactions (with radiations, particles and ultrasonics) Rearrangement Rearrangement, Hofmann‐Martius synthesis of
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