The Pagodane Route to Dodecahedranes Directed Conversions - The Pagodane → Bissecododecahedradiene Stage

Three conceptual routes (A, B, C) from [1.1.1.1]pagodane (1) to pentagonal dodecahedrane (2) are evaluated by MM2 (MM3) calculations. After limited experimental success with a catalytic one‐pot route (A), a more selective transformation along one of two stepwise routes (B/C) is explored. An expediti...

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Veröffentlicht in:	Chemische Berichte 1992-07, Vol.125 (7), p.1697-1717
Hauptverfasser:	Fessner, Wolf-Dieter, Murty, Bulusu A. R. C., Spurr, Paul R., Pinkos, Rolf, Melder, Johann-Peter, Fritz, Hans, Prinzbach, Horst
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Cage effects Chemistry Exact sciences and technology Organic chemistry Pagodane opening reactions Pagodane → dodecahedrane pathways Preparations and properties
Online-Zugang:	Volltext
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