Synthesis and Characterization of O‐Triorganosilyl Selenocarboxylates
A series of O‐triorganosilyl selenocarboxylates 2 are prepared by the reaction of sodium or potassium selenocarboxylate 1 with triorganosilyl chlorides. The selenone esters 2 are stable towards heat, but labile towards moisture, and are formed via Se‐triorganosilyl selenocarboxylate 3. In the mass s...
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| Veröffentlicht in: | Chemische Berichte 1992-02, Vol.125 (2), p.417-422 |
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| container_title | Chemische Berichte |
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| creator | Kato, Shinzi Kageyama, Hideki Kawahara, Yasuyuki Murai, Toshiaki Ishihara, Hideharu |
| description | A series of O‐triorganosilyl selenocarboxylates 2 are prepared by the reaction of sodium or potassium selenocarboxylate 1 with triorganosilyl chlorides. The selenone esters 2 are stable towards heat, but labile towards moisture, and are formed via Se‐triorganosilyl selenocarboxylate 3. In the mass spectrometer, isomerization of 2 to its less stable selenol ester 3 takes place, resembling the Schönberg thione‐thiol rearrangement. |
| doi_str_mv | 10.1002/cber.19921250220 |
| format | Article |
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The selenone esters 2 are stable towards heat, but labile towards moisture, and are formed via Se‐triorganosilyl selenocarboxylate 3. In the mass spectrometer, isomerization of 2 to its less stable selenol ester 3 takes place, resembling the Schönberg thione‐thiol rearrangement.</description><identifier>ISSN: 0009-2940</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/cber.19921250220</identifier><identifier>CODEN: CHBEAM</identifier><language>eng</language><publisher>Weinheim: WILEY‐VCH Verlag</publisher><subject>Chemistry ; Chemistry, Multidisciplinary ; Exact sciences and technology ; Noncondensed benzenic compounds ; Organic chemistry ; Physical Sciences ; Preparations and properties ; Science & Technology ; Selenocarboxylates, O‐triorganosilyl ; Selenone esters ; Seleno‐selenol rearrangement</subject><ispartof>Chemische Berichte, 1992-02, Vol.125 (2), p.417-422</ispartof><rights>Copyright © 1992 WILEY‐VCH Verlag GmbH & Co. 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The selenone esters 2 are stable towards heat, but labile towards moisture, and are formed via Se‐triorganosilyl selenocarboxylate 3. In the mass spectrometer, isomerization of 2 to its less stable selenol ester 3 takes place, resembling the Schönberg thione‐thiol rearrangement.</description><subject>Chemistry</subject><subject>Chemistry, Multidisciplinary</subject><subject>Exact sciences and technology</subject><subject>Noncondensed benzenic compounds</subject><subject>Organic chemistry</subject><subject>Physical Sciences</subject><subject>Preparations and properties</subject><subject>Science & Technology</subject><subject>Selenocarboxylates, O‐triorganosilyl</subject><subject>Selenone esters</subject><subject>Seleno‐selenol rearrangement</subject><issn>0009-2940</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><sourceid>EZCTM</sourceid><recordid>eNqNkD1PwzAQQC0EEqWwM2ZgQylnO18eGEpUWqRKlWiZI8c9U6MQV3YQhImfwG_kl5DSqmKD6Zb3TnePkHMKAwrArlSJbkCFYJTFwBgckB4FIUJIMnZIegAgQiYiOCYn3j8B8ChNeI-M523drNAbH8h6GeQr6aRq0Jl32RhbB1YHs6-Pz4Uz1j3K2npTtVUwxwprq6Qr7VtbyQb9KTnSsvJ4tpt98nA7WuSTcDob3-XDaah4d1SIacxlRkuIRKTTWCqpkItIUL1MQWUspkxpDZkAhUkaQamSsqSaoeYYpVryPoHtXuWs9w51sXbmWbq2oFBsQhSbEMWvEJ1ysVXW0itZaSdrZfzeizlPObAOu9xir1ha7ZXBWuGeGm42TsaMJl1JKjo6-z-dm-anZm5f6qZTr3eqqbD98_4ivxnd__7nG4jHk3k</recordid><startdate>199202</startdate><enddate>199202</enddate><creator>Kato, Shinzi</creator><creator>Kageyama, Hideki</creator><creator>Kawahara, Yasuyuki</creator><creator>Murai, Toshiaki</creator><creator>Ishihara, Hideharu</creator><general>WILEY‐VCH Verlag</general><general>Wiley</general><general>VCH</general><scope>BLEPL</scope><scope>DTL</scope><scope>EZCTM</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>199202</creationdate><title>Synthesis and Characterization of O‐Triorganosilyl Selenocarboxylates</title><author>Kato, Shinzi ; Kageyama, Hideki ; Kawahara, Yasuyuki ; Murai, Toshiaki ; Ishihara, Hideharu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3220-e753a81b0494f75acace39491fd70c82512cff0890ce6740bc6bb1f2ef3e47fa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>Chemistry</topic><topic>Chemistry, Multidisciplinary</topic><topic>Exact sciences and technology</topic><topic>Noncondensed benzenic compounds</topic><topic>Organic chemistry</topic><topic>Physical Sciences</topic><topic>Preparations and properties</topic><topic>Science & Technology</topic><topic>Selenocarboxylates, O‐triorganosilyl</topic><topic>Selenone esters</topic><topic>Seleno‐selenol rearrangement</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kato, Shinzi</creatorcontrib><creatorcontrib>Kageyama, Hideki</creatorcontrib><creatorcontrib>Kawahara, Yasuyuki</creatorcontrib><creatorcontrib>Murai, Toshiaki</creatorcontrib><creatorcontrib>Ishihara, Hideharu</creatorcontrib><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Web of Science - Science Citation Index Expanded - 1992</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Chemische Berichte</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kato, Shinzi</au><au>Kageyama, Hideki</au><au>Kawahara, Yasuyuki</au><au>Murai, Toshiaki</au><au>Ishihara, Hideharu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Characterization of O‐Triorganosilyl Selenocarboxylates</atitle><jtitle>Chemische Berichte</jtitle><stitle>CHEM BER-RECL</stitle><date>1992-02</date><risdate>1992</risdate><volume>125</volume><issue>2</issue><spage>417</spage><epage>422</epage><pages>417-422</pages><issn>0009-2940</issn><eissn>1099-0682</eissn><coden>CHBEAM</coden><abstract>A series of O‐triorganosilyl selenocarboxylates 2 are prepared by the reaction of sodium or potassium selenocarboxylate 1 with triorganosilyl chlorides. The selenone esters 2 are stable towards heat, but labile towards moisture, and are formed via Se‐triorganosilyl selenocarboxylate 3. In the mass spectrometer, isomerization of 2 to its less stable selenol ester 3 takes place, resembling the Schönberg thione‐thiol rearrangement.</abstract><cop>Weinheim</cop><pub>WILEY‐VCH Verlag</pub><doi>10.1002/cber.19921250220</doi><tpages>6</tpages></addata></record> |
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| ispartof | Chemische Berichte, 1992-02, Vol.125 (2), p.417-422 |
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| language | eng |
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| source | Wiley Journals |
| subjects | Chemistry Chemistry, Multidisciplinary Exact sciences and technology Noncondensed benzenic compounds Organic chemistry Physical Sciences Preparations and properties Science & Technology Selenocarboxylates, O‐triorganosilyl Selenone esters Seleno‐selenol rearrangement |
| title | Synthesis and Characterization of O‐Triorganosilyl Selenocarboxylates |
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