A Novel Methylenation Method of aldehydes Mediated by Dibutyl Telluride

In the presence of dibutyl telluride, (iodomethyl)triphenylphosphonium iodide (1) reacted with aldehydes 2 in THF at 80°C yielding he methylenation products 3 under neutral conditions in good yields.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemische Berichte 1990-06, Vol.123 (6), p.1441-1442
Hauptverfasser:	Li, Sao-Wei, Huang, Yao-Zeng, Shi, Li-Lan
Format:	Artikel
Sprache:	eng
Schlagworte:	(Iodomethyl)triphenylphosphonium iodide Aldehydes Chemistry Dibutyl telluride Exact sciences and technology Methylenation Noncondensed benzenic compounds Organic chemistry Preparations and properties
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Beschreibung
Zusammenfassung:	In the presence of dibutyl telluride, (iodomethyl)triphenylphosphonium iodide (1) reacted with aldehydes 2 in THF at 80°C yielding he methylenation products 3 under neutral conditions in good yields.
ISSN:	0009-2940 1099-0682
DOI:	10.1002/cber.19901230639