9,10‐Phenanthrenocyaninatoeisen(II) (PhcFe) und axial koordinierte Isocyanid‐Komplexe
9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) and Axially Coordinated Isocyanide Complexes 9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) is synthesized from 9,10‐dicyanophenanthrene (3) and pentacarbonyliron. PhcFe exhibits similar spectroscopic properties (UV/VIS and Mößbauer spectra) and similar oxidati...
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| Veröffentlicht in: | Chemische Berichte 1990-05, Vol.123 (5), p.1105-1110 |
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| creator | Hanack, Michael Renz, Günter |
| description | 9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) and Axially Coordinated Isocyanide Complexes
9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) is synthesized from 9,10‐dicyanophenanthrene (3) and pentacarbonyliron. PhcFe exhibits similar spectroscopic properties (UV/VIS and Mößbauer spectra) and similar oxidation potentials as 1,2‐Naphthalocyaninatoiron(II) (1,2‐NcFe) and Phthalocyaninatoiron(II) (PcFe). Isocyanides RNC (R = tBu, cHx, Bzl, Me2Ph) react with PhcFe to form the corresponding bisaxially substituted 9,10‐phenanthrenocyaninatoiron(II) compounds 4–7. Reaction of PhcFe with 1,4‐diisocyanobenzene (dib) yields the bridged complex [PhcFe(dib)]n. |
| doi_str_mv | 10.1002/cber.19901230525 |
| format | Article |
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9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) is synthesized from 9,10‐dicyanophenanthrene (3) and pentacarbonyliron. PhcFe exhibits similar spectroscopic properties (UV/VIS and Mößbauer spectra) and similar oxidation potentials as 1,2‐Naphthalocyaninatoiron(II) (1,2‐NcFe) and Phthalocyaninatoiron(II) (PcFe). Isocyanides RNC (R = tBu, cHx, Bzl, Me2Ph) react with PhcFe to form the corresponding bisaxially substituted 9,10‐phenanthrenocyaninatoiron(II) compounds 4–7. Reaction of PhcFe with 1,4‐diisocyanobenzene (dib) yields the bridged complex [PhcFe(dib)]n.</description><identifier>ISSN: 0009-2940</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/cber.19901230525</identifier><language>eng</language><publisher>Weinheim: WILEY‐VCH Verlag</publisher><subject>9,10‐Phenanthrenocyaninatoiron(II) ; Isocyanide complexes ; Porphyrin derivatives ; Semiconductors, organic</subject><ispartof>Chemische Berichte, 1990-05, Vol.123 (5), p.1105-1110</ispartof><rights>Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2085-e22109ba32bb285ffa0253d57cc2fbda37c4df7f6346f17688bcb11576f9ef7b3</citedby><cites>FETCH-LOGICAL-c2085-e22109ba32bb285ffa0253d57cc2fbda37c4df7f6346f17688bcb11576f9ef7b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcber.19901230525$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcber.19901230525$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Hanack, Michael</creatorcontrib><creatorcontrib>Renz, Günter</creatorcontrib><title>9,10‐Phenanthrenocyaninatoeisen(II) (PhcFe) und axial koordinierte Isocyanid‐Komplexe</title><title>Chemische Berichte</title><description>9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) and Axially Coordinated Isocyanide Complexes
9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) is synthesized from 9,10‐dicyanophenanthrene (3) and pentacarbonyliron. PhcFe exhibits similar spectroscopic properties (UV/VIS and Mößbauer spectra) and similar oxidation potentials as 1,2‐Naphthalocyaninatoiron(II) (1,2‐NcFe) and Phthalocyaninatoiron(II) (PcFe). Isocyanides RNC (R = tBu, cHx, Bzl, Me2Ph) react with PhcFe to form the corresponding bisaxially substituted 9,10‐phenanthrenocyaninatoiron(II) compounds 4–7. Reaction of PhcFe with 1,4‐diisocyanobenzene (dib) yields the bridged complex [PhcFe(dib)]n.</description><subject>9,10‐Phenanthrenocyaninatoiron(II)</subject><subject>Isocyanide complexes</subject><subject>Porphyrin derivatives</subject><subject>Semiconductors, organic</subject><issn>0009-2940</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNqFkLFOwzAURS0EEqWwM2ZsJVKe7TiJBwaoWoioRIVgYIps51kNpE5lt6Ld-AS-kS-hVRm6Md3lnqurQ8glhQEFYNdGox9QKYEyDoKJI9KhIGUMac6OSQcAZMxkAqfkLIR3AJ5kKe-QN3lF4efrezpDp9xy5tG1ZqNc7dSyxTqg6xVFP-pNZ2aM_Wjlqkita9VEH23rq9rV6JcYFWEPVdulx3a-aHCN5-TEqibgxV92yet49DJ8iCdP98XwdhIbBrmIkbHtT60405rlwloFTPBKZMYwqyvFM5NUNrMpT1JLszTPtdGUiiy1Em2meZfAftf4NgSPtlz4eq78pqRQ7tSUOzXlgZotcrNHPusGN__2y-Hd6PmQ_wXmGWvH</recordid><startdate>199005</startdate><enddate>199005</enddate><creator>Hanack, Michael</creator><creator>Renz, Günter</creator><general>WILEY‐VCH Verlag</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>199005</creationdate><title>9,10‐Phenanthrenocyaninatoeisen(II) (PhcFe) und axial koordinierte Isocyanid‐Komplexe</title><author>Hanack, Michael ; Renz, Günter</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2085-e22109ba32bb285ffa0253d57cc2fbda37c4df7f6346f17688bcb11576f9ef7b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>9,10‐Phenanthrenocyaninatoiron(II)</topic><topic>Isocyanide complexes</topic><topic>Porphyrin derivatives</topic><topic>Semiconductors, organic</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hanack, Michael</creatorcontrib><creatorcontrib>Renz, Günter</creatorcontrib><collection>CrossRef</collection><jtitle>Chemische Berichte</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hanack, Michael</au><au>Renz, Günter</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>9,10‐Phenanthrenocyaninatoeisen(II) (PhcFe) und axial koordinierte Isocyanid‐Komplexe</atitle><jtitle>Chemische Berichte</jtitle><date>1990-05</date><risdate>1990</risdate><volume>123</volume><issue>5</issue><spage>1105</spage><epage>1110</epage><pages>1105-1110</pages><issn>0009-2940</issn><eissn>1099-0682</eissn><abstract>9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) and Axially Coordinated Isocyanide Complexes
9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) is synthesized from 9,10‐dicyanophenanthrene (3) and pentacarbonyliron. PhcFe exhibits similar spectroscopic properties (UV/VIS and Mößbauer spectra) and similar oxidation potentials as 1,2‐Naphthalocyaninatoiron(II) (1,2‐NcFe) and Phthalocyaninatoiron(II) (PcFe). Isocyanides RNC (R = tBu, cHx, Bzl, Me2Ph) react with PhcFe to form the corresponding bisaxially substituted 9,10‐phenanthrenocyaninatoiron(II) compounds 4–7. Reaction of PhcFe with 1,4‐diisocyanobenzene (dib) yields the bridged complex [PhcFe(dib)]n.</abstract><cop>Weinheim</cop><pub>WILEY‐VCH Verlag</pub><doi>10.1002/cber.19901230525</doi><tpages>6</tpages></addata></record> |
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| subjects | 9,10‐Phenanthrenocyaninatoiron(II) Isocyanide complexes Porphyrin derivatives Semiconductors, organic |
| title | 9,10‐Phenanthrenocyaninatoeisen(II) (PhcFe) und axial koordinierte Isocyanid‐Komplexe |
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