The Structure of Amine Adducts of Triorganylboroxines
In a series of donor‐acceptor adducts of amines to triorganylboroxines (Tables 1, 2) it has been shown by 1H and 11B NMR spectroscopy that in solution the amine undergoes a temperature dependent fluctuation between the boron atoms of the boroxine ring. In the solid state, as determined by X‐ray stru...
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| Veröffentlicht in: | Chemische Berichte 1983-10, Vol.116 (10), p.3347-3358 |
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| creator | Yalpani, Mohamed Boese, Roland |
| description | In a series of donor‐acceptor adducts of amines to triorganylboroxines (Tables 1, 2) it has been shown by 1H and 11B NMR spectroscopy that in solution the amine undergoes a temperature dependent fluctuation between the boron atoms of the boroxine ring. In the solid state, as determined by X‐ray structural analysis of two selected 3:2 and 1:2 adducts (3 and 6) (boron‐nitrogen ratios of 1:1 and 3:1, respectively), only one boron atom of each boroxine ring is involved in adduct formation.
Die Struktur von Amin‐Addukten von Triorganylboroxinen
In einer Reihe von Donor‐Acceptor‐Addukten von Aminen mit Triorganylboroxinen (Tabb. 1, 2) wird gezeigt, daß in Lösung die Aminmoleküle zwischen den drei Boratomen des Boroxin‐Rings fluktuieren. Im festen Zustand, wie es aus den Röntgenstrukturanalysen von zwei ausgewählten 3:2‐ und 1:1‐Addukten (3 und 6) (mit Bor‐Stickstoff‐Verhältnissen von 1:1 bzw. 3:1) hervorgeht, ist nur ein Bor‐Atom des Boroxin‐Rings an der Adduktbildung beteiligt. |
| doi_str_mv | 10.1002/cber.19831161011 |
| format | Article |
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Die Struktur von Amin‐Addukten von Triorganylboroxinen
In einer Reihe von Donor‐Acceptor‐Addukten von Aminen mit Triorganylboroxinen (Tabb. 1, 2) wird gezeigt, daß in Lösung die Aminmoleküle zwischen den drei Boratomen des Boroxin‐Rings fluktuieren. Im festen Zustand, wie es aus den Röntgenstrukturanalysen von zwei ausgewählten 3:2‐ und 1:1‐Addukten (3 und 6) (mit Bor‐Stickstoff‐Verhältnissen von 1:1 bzw. 3:1) hervorgeht, ist nur ein Bor‐Atom des Boroxin‐Rings an der Adduktbildung beteiligt.</description><identifier>ISSN: 0009-2940</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/cber.19831161011</identifier><identifier>CODEN: CHBEAM</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Atomic and molecular physics ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Molecular properties and interactions with photons ; Nuclear resonance and relaxation ; Organic compounds ; Organometalloidal and organometallic compounds ; Physics ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Chemische Berichte, 1983-10, Vol.116 (10), p.3347-3358</ispartof><rights>Copyright © 1983 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>1984 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4281-f62c3c27f6720da41450aaabd3b2d4c146144b9b102182426191b244817f5ce93</citedby><cites>FETCH-LOGICAL-c4281-f62c3c27f6720da41450aaabd3b2d4c146144b9b102182426191b244817f5ce93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcber.19831161011$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcber.19831161011$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27922,27923,45572,45573</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=9325578$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Yalpani, Mohamed</creatorcontrib><creatorcontrib>Boese, Roland</creatorcontrib><title>The Structure of Amine Adducts of Triorganylboroxines</title><title>Chemische Berichte</title><addtitle>Chem. Ber</addtitle><description>In a series of donor‐acceptor adducts of amines to triorganylboroxines (Tables 1, 2) it has been shown by 1H and 11B NMR spectroscopy that in solution the amine undergoes a temperature dependent fluctuation between the boron atoms of the boroxine ring. In the solid state, as determined by X‐ray structural analysis of two selected 3:2 and 1:2 adducts (3 and 6) (boron‐nitrogen ratios of 1:1 and 3:1, respectively), only one boron atom of each boroxine ring is involved in adduct formation.
Die Struktur von Amin‐Addukten von Triorganylboroxinen
In einer Reihe von Donor‐Acceptor‐Addukten von Aminen mit Triorganylboroxinen (Tabb. 1, 2) wird gezeigt, daß in Lösung die Aminmoleküle zwischen den drei Boratomen des Boroxin‐Rings fluktuieren. Im festen Zustand, wie es aus den Röntgenstrukturanalysen von zwei ausgewählten 3:2‐ und 1:1‐Addukten (3 und 6) (mit Bor‐Stickstoff‐Verhältnissen von 1:1 bzw. 3:1) hervorgeht, ist nur ein Bor‐Atom des Boroxin‐Rings an der Adduktbildung beteiligt.</description><subject>Atomic and molecular physics</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Molecular properties and interactions with photons</subject><subject>Nuclear resonance and relaxation</subject><subject>Organic compounds</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>0009-2940</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1983</creationdate><recordtype>article</recordtype><recordid>eNqFj8FLwzAYxYMoOKd3jz147fy-JE2bg4c5tikMFa0Mdglpmmq1W0fS4fbf21EZevL0wfve7z0eIZcIAwSg1yazboAyYYgCAfGI9BCkDEEk9Jj0AECGVHI4JWfefwAwHgvWI1H6boOXxm1Ms3E2qItguCxXNhjmeSv5vZC6snZverWrstrV2_brz8lJoStvL35un7xOxunoLpw9Tu9Hw1loOE0wLAQ1zNC4EDGFXHPkEWits5xlNOcGuUDOM5khUEwopwIlZpTzBOMiMlayPoEu17jae2cLtXblUrudQlD72Wo_W_2a3SJXHbLW3uiqcHplSn_gJKNRFCet7aazfZWV3f0bq0a34-e_NWHHl76x2wOv3acSMYsjNX-YqqcFzieLBFTKvgGMyneT</recordid><startdate>198310</startdate><enddate>198310</enddate><creator>Yalpani, Mohamed</creator><creator>Boese, Roland</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>VCH</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>198310</creationdate><title>The Structure of Amine Adducts of Triorganylboroxines</title><author>Yalpani, Mohamed ; Boese, Roland</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4281-f62c3c27f6720da41450aaabd3b2d4c146144b9b102182426191b244817f5ce93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1983</creationdate><topic>Atomic and molecular physics</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Molecular properties and interactions with photons</topic><topic>Nuclear resonance and relaxation</topic><topic>Organic compounds</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yalpani, Mohamed</creatorcontrib><creatorcontrib>Boese, Roland</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Chemische Berichte</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yalpani, Mohamed</au><au>Boese, Roland</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Structure of Amine Adducts of Triorganylboroxines</atitle><jtitle>Chemische Berichte</jtitle><addtitle>Chem. Ber</addtitle><date>1983-10</date><risdate>1983</risdate><volume>116</volume><issue>10</issue><spage>3347</spage><epage>3358</epage><pages>3347-3358</pages><issn>0009-2940</issn><eissn>1099-0682</eissn><coden>CHBEAM</coden><abstract>In a series of donor‐acceptor adducts of amines to triorganylboroxines (Tables 1, 2) it has been shown by 1H and 11B NMR spectroscopy that in solution the amine undergoes a temperature dependent fluctuation between the boron atoms of the boroxine ring. In the solid state, as determined by X‐ray structural analysis of two selected 3:2 and 1:2 adducts (3 and 6) (boron‐nitrogen ratios of 1:1 and 3:1, respectively), only one boron atom of each boroxine ring is involved in adduct formation.
Die Struktur von Amin‐Addukten von Triorganylboroxinen
In einer Reihe von Donor‐Acceptor‐Addukten von Aminen mit Triorganylboroxinen (Tabb. 1, 2) wird gezeigt, daß in Lösung die Aminmoleküle zwischen den drei Boratomen des Boroxin‐Rings fluktuieren. Im festen Zustand, wie es aus den Röntgenstrukturanalysen von zwei ausgewählten 3:2‐ und 1:1‐Addukten (3 und 6) (mit Bor‐Stickstoff‐Verhältnissen von 1:1 bzw. 3:1) hervorgeht, ist nur ein Bor‐Atom des Boroxin‐Rings an der Adduktbildung beteiligt.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/cber.19831161011</doi><tpages>12</tpages></addata></record> |
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| subjects | Atomic and molecular physics Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Molecular properties and interactions with photons Nuclear resonance and relaxation Organic compounds Organometalloidal and organometallic compounds Physics Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | The Structure of Amine Adducts of Triorganylboroxines |
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