Zur Umsetzung des Tricarbonyl(η4‐6,6‐diphenylpentafulven)eisens mit Nucleophilen

Zur Umsetzung des Tricarbonyl(η4‐6,6‐diphenylpentafulven)eisens mit Nucleophilen

Conversion of Tricarbonyl(η4‐6,6‐diphenylpentafulvene)iron with Nucleophiles Tricarbonyl(η4‐6,6‐diphenylpentafulvene)iron (2a), reacts with methanol/methoxide to form the “metalloester” 7a via nucleophilic attack of the carbon monoxide ligand. This is contrary to an earlier report in which a bridged...

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Veröffentlicht in:Chemische Berichte 1981-04, Vol.114 (4), p.1559-1561
Hauptverfasser: Eilbracht, Peter, Henkes, Erhard
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container_title Chemische Berichte
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creator Eilbracht, Peter
Henkes, Erhard
description Conversion of Tricarbonyl(η4‐6,6‐diphenylpentafulvene)iron with Nucleophiles Tricarbonyl(η4‐6,6‐diphenylpentafulvene)iron (2a), reacts with methanol/methoxide to form the “metalloester” 7a via nucleophilic attack of the carbon monoxide ligand. This is contrary to an earlier report in which a bridged cyclopentadiene system 6 has been proposed as reaction product.
doi_str_mv 10.1002/cber.19811140435
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title Zur Umsetzung des Tricarbonyl(η4‐6,6‐diphenylpentafulven)eisens mit Nucleophilen
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