Blue Light‐promoted Carbene Transfer Reactions of Tosylhydrazones
Metal‐free photochemical carbene‐transfer reactions of tosylhydrazones were developed under blue light irradiation at room temperature. This reaction constructs C−X (X=C, N, O, S) bonds and cyclopropanes from readily available and stable starting materials. Metal‐free photochemical X−H insertions an...
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| Veröffentlicht in: | Chemistry, an Asian journal an Asian journal, 2020-07, Vol.15 (13), p.1945-1947 |
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| container_end_page | 1947 |
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| container_issue | 13 |
| container_start_page | 1945 |
| container_title | Chemistry, an Asian journal |
| container_volume | 15 |
| creator | Xu, Yingying Lv, Guanghui Yan, Kaichuan He, Hua Li, Jianglian Luo, Yi Lai, Ruizhi Hai, Li Wu, Yong |
| description | Metal‐free photochemical carbene‐transfer reactions of tosylhydrazones were developed under blue light irradiation at room temperature. This reaction constructs C−X (X=C, N, O, S) bonds and cyclopropanes from readily available and stable starting materials.
Metal‐free photochemical X−H insertions and cyclopropanelation of tosylhydrazones were developed under blue light irradiation at room temperature. |
| doi_str_mv | 10.1002/asia.202000378 |
| format | Article |
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Metal‐free photochemical X−H insertions and cyclopropanelation of tosylhydrazones were developed under blue light irradiation at room temperature.</description><identifier>ISSN: 1861-4728</identifier><identifier>EISSN: 1861-471X</identifier><identifier>DOI: 10.1002/asia.202000378</identifier><identifier>PMID: 32427419</identifier><language>eng</language><publisher>WEINHEIM: Wiley</publisher><subject>Carbene ; Chemistry ; Chemistry, Multidisciplinary ; Cyclopropanation ; Light irradiation ; Organic compounds ; Photochemical reactions ; Photochemistry ; Physical Sciences ; Room temperature ; Science & Technology ; Tosylhydrazones ; X−H insertions</subject><ispartof>Chemistry, an Asian journal, 2020-07, Vol.15 (13), p.1945-1947</ispartof><rights>2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>19</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000537519800001</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c4108-69fb0381f9c5ac1a419a5e861acebef7f918aa80f3d843f005ba393e252e50cb3</citedby><cites>FETCH-LOGICAL-c4108-69fb0381f9c5ac1a419a5e861acebef7f918aa80f3d843f005ba393e252e50cb3</cites><orcidid>0000-0003-0719-4963</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fasia.202000378$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fasia.202000378$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27929,27930,28253,45579,45580</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32427419$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Xu, Yingying</creatorcontrib><creatorcontrib>Lv, Guanghui</creatorcontrib><creatorcontrib>Yan, Kaichuan</creatorcontrib><creatorcontrib>He, Hua</creatorcontrib><creatorcontrib>Li, Jianglian</creatorcontrib><creatorcontrib>Luo, Yi</creatorcontrib><creatorcontrib>Lai, Ruizhi</creatorcontrib><creatorcontrib>Hai, Li</creatorcontrib><creatorcontrib>Wu, Yong</creatorcontrib><title>Blue Light‐promoted Carbene Transfer Reactions of Tosylhydrazones</title><title>Chemistry, an Asian journal</title><addtitle>CHEM-ASIAN J</addtitle><addtitle>Chem Asian J</addtitle><description>Metal‐free photochemical carbene‐transfer reactions of tosylhydrazones were developed under blue light irradiation at room temperature. This reaction constructs C−X (X=C, N, O, S) bonds and cyclopropanes from readily available and stable starting materials.
Metal‐free photochemical X−H insertions and cyclopropanelation of tosylhydrazones were developed under blue light irradiation at room temperature.</description><subject>Carbene</subject><subject>Chemistry</subject><subject>Chemistry, Multidisciplinary</subject><subject>Cyclopropanation</subject><subject>Light irradiation</subject><subject>Organic compounds</subject><subject>Photochemical reactions</subject><subject>Photochemistry</subject><subject>Physical Sciences</subject><subject>Room temperature</subject><subject>Science & Technology</subject><subject>Tosylhydrazones</subject><subject>X−H insertions</subject><issn>1861-4728</issn><issn>1861-471X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqNkU-LE0EQxRtRTIxePcrAXgRJrP4zme5jdnB1ISBoBG9DTafaTJhMx-4ZlnjyI-xn9JPYITGCl_VUdfi9V69fM_aSw4wDiLcYG5wJEAAgC_2Ijbme86kq-NfHl13oEXsW4xYgF2D0UzaSQolCcTNm5XU7ULZsvm36Xz_v98HvfE_rrMRQU0fZKmAXHYXsE6HtG9_FzLts5eOh3RzWAX_4juJz9sRhG-nFeU7Yl5t3q_LDdPnx_W25WE6t4qCnc-NqkJo7Y3O0HNN9zClFREs1ucIZrhE1OLnWSrqUtkZpJIlcUA62lhP2-uSbYn4fKPbVromW2hY78kOshAI1VzA3kNCrf9CtH0KX0iWKayMVF0WiZifKBh9jIFftQ7PDcKg4VMd6q2O91aXeJHh1th3qHa0v-J8-E_DmBNxR7V20DXWWLlhyyWWRc6PTBjzR-v_psunx-AOlH7o-Sc1Z2rR0eCB3tfh8u_j7it-IbKe2</recordid><startdate>20200701</startdate><enddate>20200701</enddate><creator>Xu, Yingying</creator><creator>Lv, Guanghui</creator><creator>Yan, Kaichuan</creator><creator>He, Hua</creator><creator>Li, Jianglian</creator><creator>Luo, Yi</creator><creator>Lai, Ruizhi</creator><creator>Hai, Li</creator><creator>Wu, Yong</creator><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-0719-4963</orcidid></search><sort><creationdate>20200701</creationdate><title>Blue Light‐promoted Carbene Transfer Reactions of Tosylhydrazones</title><author>Xu, Yingying ; Lv, Guanghui ; Yan, Kaichuan ; He, Hua ; Li, Jianglian ; Luo, Yi ; Lai, Ruizhi ; Hai, Li ; Wu, Yong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4108-69fb0381f9c5ac1a419a5e861acebef7f918aa80f3d843f005ba393e252e50cb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Carbene</topic><topic>Chemistry</topic><topic>Chemistry, Multidisciplinary</topic><topic>Cyclopropanation</topic><topic>Light irradiation</topic><topic>Organic compounds</topic><topic>Photochemical reactions</topic><topic>Photochemistry</topic><topic>Physical Sciences</topic><topic>Room temperature</topic><topic>Science & Technology</topic><topic>Tosylhydrazones</topic><topic>X−H insertions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Yingying</creatorcontrib><creatorcontrib>Lv, Guanghui</creatorcontrib><creatorcontrib>Yan, Kaichuan</creatorcontrib><creatorcontrib>He, Hua</creatorcontrib><creatorcontrib>Li, Jianglian</creatorcontrib><creatorcontrib>Luo, Yi</creatorcontrib><creatorcontrib>Lai, Ruizhi</creatorcontrib><creatorcontrib>Hai, Li</creatorcontrib><creatorcontrib>Wu, Yong</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry, an Asian journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Yingying</au><au>Lv, Guanghui</au><au>Yan, Kaichuan</au><au>He, Hua</au><au>Li, Jianglian</au><au>Luo, Yi</au><au>Lai, Ruizhi</au><au>Hai, Li</au><au>Wu, Yong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Blue Light‐promoted Carbene Transfer Reactions of Tosylhydrazones</atitle><jtitle>Chemistry, an Asian journal</jtitle><stitle>CHEM-ASIAN J</stitle><addtitle>Chem Asian J</addtitle><date>2020-07-01</date><risdate>2020</risdate><volume>15</volume><issue>13</issue><spage>1945</spage><epage>1947</epage><pages>1945-1947</pages><issn>1861-4728</issn><eissn>1861-471X</eissn><abstract>Metal‐free photochemical carbene‐transfer reactions of tosylhydrazones were developed under blue light irradiation at room temperature. This reaction constructs C−X (X=C, N, O, S) bonds and cyclopropanes from readily available and stable starting materials.
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| ispartof | Chemistry, an Asian journal, 2020-07, Vol.15 (13), p.1945-1947 |
| issn | 1861-4728 1861-471X |
| language | eng |
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| source | Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" />; Wiley Online Library All Journals |
| subjects | Carbene Chemistry Chemistry, Multidisciplinary Cyclopropanation Light irradiation Organic compounds Photochemical reactions Photochemistry Physical Sciences Room temperature Science & Technology Tosylhydrazones X−H insertions |
| title | Blue Light‐promoted Carbene Transfer Reactions of Tosylhydrazones |
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