Mechanical, thermal, and conductivity performances of novel thermoplastic natural rubber/graphene nanoplates/polyaniline composites
ABSTRACT Conventional polymer blending has a shortcoming in conductivity characteristic. This research addresses the preparation of conductive thermoplastic natural rubber (TPNR) blends with graphene nanoplates (GNPs)/polyaniline (PANI) through melt blending using an internal mixer. The effect of PA...
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| Veröffentlicht in: | Journal of applied polymer science 2020-07, Vol.137 (28), p.n/a, Article 48873 |
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| creator | Tarawneh, Mou'ad Ahmad Saraireh, Sherin Abdelkader Chen, Ruey Shan Ahmad, Sahrim Hj Al‐Tarawni, Musab Ahmad Mohammad Al‐Tweissi, Mohammed Yu, Lih Jiun |
| description | ABSTRACT
Conventional polymer blending has a shortcoming in conductivity characteristic. This research addresses the preparation of conductive thermoplastic natural rubber (TPNR) blends with graphene nanoplates (GNPs)/polyaniline (PANI) through melt blending using an internal mixer. The effect of PANI content (10, 20, 30, and 40 wt %) on the mechanical and thermal properties, thermal and electrical conductivities, and morphology observation of the TPNR/GNPs/PANI nanocomposites was investigated. The results showed that the tensile and impact properties as well as thermal conductivity of nanocomposite had improved with the incorporation of 3 wt % of GNPs and 20 wt % of PANI as compared to neat TPNR and reduced with further increase of the PANI content. It was observed that the GNPs and PANI acted as a critical component to improve the thermal stability and electrical conductivity of the TPNR/GNPs/PANI nanocomposites. The most improved conductivity of 5.22 E‐5 S/cm was observed at 3 wt % GNPs and 40 wt % PANI. Variable‐pressure scanning electron microscopy micrograph revealed the good interaction and distribution of GNPs and PANI within TPNR matrix at PANI loadings lower than 30 wt %. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48873. |
| doi_str_mv | 10.1002/app.48873 |
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Conventional polymer blending has a shortcoming in conductivity characteristic. This research addresses the preparation of conductive thermoplastic natural rubber (TPNR) blends with graphene nanoplates (GNPs)/polyaniline (PANI) through melt blending using an internal mixer. The effect of PANI content (10, 20, 30, and 40 wt %) on the mechanical and thermal properties, thermal and electrical conductivities, and morphology observation of the TPNR/GNPs/PANI nanocomposites was investigated. The results showed that the tensile and impact properties as well as thermal conductivity of nanocomposite had improved with the incorporation of 3 wt % of GNPs and 20 wt % of PANI as compared to neat TPNR and reduced with further increase of the PANI content. It was observed that the GNPs and PANI acted as a critical component to improve the thermal stability and electrical conductivity of the TPNR/GNPs/PANI nanocomposites. The most improved conductivity of 5.22 E‐5 S/cm was observed at 3 wt % GNPs and 40 wt % PANI. Variable‐pressure scanning electron microscopy micrograph revealed the good interaction and distribution of GNPs and PANI within TPNR matrix at PANI loadings lower than 30 wt %. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48873.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.48873</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Blending effects ; blends ; Conductivity ; Critical components ; elastomers ; Electrical resistivity ; Graphene ; Materials science ; mechanical properties ; Melt blending ; Morphology ; Nanocomposites ; Natural rubber ; Photomicrographs ; Physical Sciences ; Polyanilines ; Polymer blends ; Polymer matrix composites ; Polymer Science ; Polymers ; Science & Technology ; Thermal conductivity ; Thermal stability ; Thermodynamic properties ; thermoplastics</subject><ispartof>Journal of applied polymer science, 2020-07, Vol.137 (28), p.n/a, Article 48873</ispartof><rights>2019 Wiley Periodicals, Inc.</rights><rights>2020 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>20</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000504184900001</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c3343-ab2b69e1b6849c7ecc39b5fdd2402e9fcc3ac22f2abd7395594c1fe1e297b9ed3</citedby><cites>FETCH-LOGICAL-c3343-ab2b69e1b6849c7ecc39b5fdd2402e9fcc3ac22f2abd7395594c1fe1e297b9ed3</cites><orcidid>0000-0002-2713-942X ; 0000-0002-0426-0972</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.48873$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.48873$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,782,786,1419,27931,27932,28255,45581,45582</link.rule.ids></links><search><creatorcontrib>Tarawneh, Mou'ad Ahmad</creatorcontrib><creatorcontrib>Saraireh, Sherin Abdelkader</creatorcontrib><creatorcontrib>Chen, Ruey Shan</creatorcontrib><creatorcontrib>Ahmad, Sahrim Hj</creatorcontrib><creatorcontrib>Al‐Tarawni, Musab Ahmad Mohammad</creatorcontrib><creatorcontrib>Al‐Tweissi, Mohammed</creatorcontrib><creatorcontrib>Yu, Lih Jiun</creatorcontrib><title>Mechanical, thermal, and conductivity performances of novel thermoplastic natural rubber/graphene nanoplates/polyaniline composites</title><title>Journal of applied polymer science</title><addtitle>J APPL POLYM SCI</addtitle><description>ABSTRACT
Conventional polymer blending has a shortcoming in conductivity characteristic. This research addresses the preparation of conductive thermoplastic natural rubber (TPNR) blends with graphene nanoplates (GNPs)/polyaniline (PANI) through melt blending using an internal mixer. The effect of PANI content (10, 20, 30, and 40 wt %) on the mechanical and thermal properties, thermal and electrical conductivities, and morphology observation of the TPNR/GNPs/PANI nanocomposites was investigated. The results showed that the tensile and impact properties as well as thermal conductivity of nanocomposite had improved with the incorporation of 3 wt % of GNPs and 20 wt % of PANI as compared to neat TPNR and reduced with further increase of the PANI content. It was observed that the GNPs and PANI acted as a critical component to improve the thermal stability and electrical conductivity of the TPNR/GNPs/PANI nanocomposites. The most improved conductivity of 5.22 E‐5 S/cm was observed at 3 wt % GNPs and 40 wt % PANI. Variable‐pressure scanning electron microscopy micrograph revealed the good interaction and distribution of GNPs and PANI within TPNR matrix at PANI loadings lower than 30 wt %. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48873.</description><subject>Blending effects</subject><subject>blends</subject><subject>Conductivity</subject><subject>Critical components</subject><subject>elastomers</subject><subject>Electrical resistivity</subject><subject>Graphene</subject><subject>Materials science</subject><subject>mechanical properties</subject><subject>Melt blending</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Natural rubber</subject><subject>Photomicrographs</subject><subject>Physical Sciences</subject><subject>Polyanilines</subject><subject>Polymer blends</subject><subject>Polymer matrix composites</subject><subject>Polymer Science</subject><subject>Polymers</subject><subject>Science & Technology</subject><subject>Thermal conductivity</subject><subject>Thermal stability</subject><subject>Thermodynamic properties</subject><subject>thermoplastics</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqNkMtKBDEQRYMoOD4W_kGDK9F2kvQzSxl8gaILXTdJuuJEepKYpJVZ--NmbHEnuErl1qmqy0XoiOBzgjGdc-fOy7Ztii00I5g1eVnTdhvNUo_kLWPVLtoL4RVjQipcz9DnPcglN1ry4SyLS_CrTcFNn0lr-lFG_a7jOnPglU09IyFkVmXGvsMw8dYNPEQtM8Pj6PmQ-VEI8PMXz90SDCTdbJgIYe7ssE7HBp1kaVfOBp3kA7Sj-BDg8OfdR89Xl0-Lm_zu4fp2cXGXy6Ioi5wLKmoGRNRtyWQDUhZMVKrvaYkpMJX-XFKqKBd9U7CqYqUkCghQ1ggGfbGPjqe9ztu3EULsXu3oTTrZ0YJRXGNasUSdTJT0NgQPqnNer7hfdwR3m4y7lHH3nXFi24n9AGFVkBpSQL88xrjCJUluU4XJQkcetTULO5qYRk__P5ro-Q-tB1j_7ai7eHycrH0BXBqjDA</recordid><startdate>20200720</startdate><enddate>20200720</enddate><creator>Tarawneh, Mou'ad Ahmad</creator><creator>Saraireh, Sherin Abdelkader</creator><creator>Chen, Ruey Shan</creator><creator>Ahmad, Sahrim Hj</creator><creator>Al‐Tarawni, Musab Ahmad Mohammad</creator><creator>Al‐Tweissi, Mohammed</creator><creator>Yu, Lih Jiun</creator><general>John Wiley & Sons, Inc</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-2713-942X</orcidid><orcidid>https://orcid.org/0000-0002-0426-0972</orcidid></search><sort><creationdate>20200720</creationdate><title>Mechanical, thermal, and conductivity performances of novel thermoplastic natural rubber/graphene nanoplates/polyaniline composites</title><author>Tarawneh, Mou'ad Ahmad ; Saraireh, Sherin Abdelkader ; Chen, Ruey Shan ; Ahmad, Sahrim Hj ; Al‐Tarawni, Musab Ahmad Mohammad ; Al‐Tweissi, Mohammed ; Yu, Lih Jiun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3343-ab2b69e1b6849c7ecc39b5fdd2402e9fcc3ac22f2abd7395594c1fe1e297b9ed3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Blending effects</topic><topic>blends</topic><topic>Conductivity</topic><topic>Critical components</topic><topic>elastomers</topic><topic>Electrical resistivity</topic><topic>Graphene</topic><topic>Materials science</topic><topic>mechanical properties</topic><topic>Melt blending</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Natural rubber</topic><topic>Photomicrographs</topic><topic>Physical Sciences</topic><topic>Polyanilines</topic><topic>Polymer blends</topic><topic>Polymer matrix composites</topic><topic>Polymer Science</topic><topic>Polymers</topic><topic>Science & Technology</topic><topic>Thermal conductivity</topic><topic>Thermal stability</topic><topic>Thermodynamic properties</topic><topic>thermoplastics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tarawneh, Mou'ad Ahmad</creatorcontrib><creatorcontrib>Saraireh, Sherin Abdelkader</creatorcontrib><creatorcontrib>Chen, Ruey Shan</creatorcontrib><creatorcontrib>Ahmad, Sahrim Hj</creatorcontrib><creatorcontrib>Al‐Tarawni, Musab Ahmad Mohammad</creatorcontrib><creatorcontrib>Al‐Tweissi, Mohammed</creatorcontrib><creatorcontrib>Yu, Lih Jiun</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tarawneh, Mou'ad Ahmad</au><au>Saraireh, Sherin Abdelkader</au><au>Chen, Ruey Shan</au><au>Ahmad, Sahrim Hj</au><au>Al‐Tarawni, Musab Ahmad Mohammad</au><au>Al‐Tweissi, Mohammed</au><au>Yu, Lih Jiun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanical, thermal, and conductivity performances of novel thermoplastic natural rubber/graphene nanoplates/polyaniline composites</atitle><jtitle>Journal of applied polymer science</jtitle><stitle>J APPL POLYM SCI</stitle><date>2020-07-20</date><risdate>2020</risdate><volume>137</volume><issue>28</issue><epage>n/a</epage><artnum>48873</artnum><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>ABSTRACT
Conventional polymer blending has a shortcoming in conductivity characteristic. This research addresses the preparation of conductive thermoplastic natural rubber (TPNR) blends with graphene nanoplates (GNPs)/polyaniline (PANI) through melt blending using an internal mixer. The effect of PANI content (10, 20, 30, and 40 wt %) on the mechanical and thermal properties, thermal and electrical conductivities, and morphology observation of the TPNR/GNPs/PANI nanocomposites was investigated. The results showed that the tensile and impact properties as well as thermal conductivity of nanocomposite had improved with the incorporation of 3 wt % of GNPs and 20 wt % of PANI as compared to neat TPNR and reduced with further increase of the PANI content. It was observed that the GNPs and PANI acted as a critical component to improve the thermal stability and electrical conductivity of the TPNR/GNPs/PANI nanocomposites. The most improved conductivity of 5.22 E‐5 S/cm was observed at 3 wt % GNPs and 40 wt % PANI. Variable‐pressure scanning electron microscopy micrograph revealed the good interaction and distribution of GNPs and PANI within TPNR matrix at PANI loadings lower than 30 wt %. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48873.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.48873</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-2713-942X</orcidid><orcidid>https://orcid.org/0000-0002-0426-0972</orcidid></addata></record> |
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| subjects | Blending effects blends Conductivity Critical components elastomers Electrical resistivity Graphene Materials science mechanical properties Melt blending Morphology Nanocomposites Natural rubber Photomicrographs Physical Sciences Polyanilines Polymer blends Polymer matrix composites Polymer Science Polymers Science & Technology Thermal conductivity Thermal stability Thermodynamic properties thermoplastics |
| title | Mechanical, thermal, and conductivity performances of novel thermoplastic natural rubber/graphene nanoplates/polyaniline composites |
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