Soluble low-κ poly (aryl ether ketone) copolymers containing pendant adamantyl group and long aliphatic side chains
The aromatic diphenol monomers, 4‐(1‐adamantyl)‐1,3‐benzene diol (AdRES) and 4‐(6‐(4‐hydroxyphenyl)undecan‐6‐yl)phenol (BISPR5R5) were successfully synthesized and used to synthesize a new series of poly (aryl ether ketone) copolymers (AdRES‐BISPR5R5‐PEEKs) with different percentages of two diphenol...
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| Veröffentlicht in: | Journal of applied polymer science 2013-10, Vol.130 (1), p.193-200 |
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| creator | Ba, Jinyu Geng, Zhi Mu, Jianxin |
| description | The aromatic diphenol monomers, 4‐(1‐adamantyl)‐1,3‐benzene diol (AdRES) and 4‐(6‐(4‐hydroxyphenyl)undecan‐6‐yl)phenol (BISPR5R5) were successfully synthesized and used to synthesize a new series of poly (aryl ether ketone) copolymers (AdRES‐BISPR5R5‐PEEKs) with different percentages of two diphenol monomers by nucleophilic aromatic substitution polycondensation. The structure of copolymers was confirmed using FTIR and 1H NMR spectroscopy and their thermal and mechanical properties and solubilities were determined. It was found that the flexibility and toughness properties of the copolymers could be controlled by varying the molar ratio of diphenol monomers containing the pendent rigid adamantyl group and the flexible long side chains. They also showed low dielectric constants (κ = 2.50–2.88 at 1 MHz) and low water absorptions. It revealed that the symmetrical long aliphatic side chains were more conducive for reducing the polarity of the polymer chains, loosening the polymer packing, and subsequently reducing polymers' density and dielectric constants than the pendent rigid adamantyl group. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 |
| doi_str_mv | 10.1002/app.39146 |
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The structure of copolymers was confirmed using FTIR and 1H NMR spectroscopy and their thermal and mechanical properties and solubilities were determined. It was found that the flexibility and toughness properties of the copolymers could be controlled by varying the molar ratio of diphenol monomers containing the pendent rigid adamantyl group and the flexible long side chains. They also showed low dielectric constants (κ = 2.50–2.88 at 1 MHz) and low water absorptions. It revealed that the symmetrical long aliphatic side chains were more conducive for reducing the polarity of the polymer chains, loosening the polymer packing, and subsequently reducing polymers' density and dielectric constants than the pendent rigid adamantyl group. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.39146</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; copolymers ; dielectric properties ; Exact sciences and technology ; mechanical properties ; Organic polymers ; Physicochemistry of polymers ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; structure-property relations</subject><ispartof>Journal of applied polymer science, 2013-10, Vol.130 (1), p.193-200</ispartof><rights>Copyright © 2013 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2526-f3ba19c1f3d4761aa84eedffedf50106134f81779e86c2b6f9b8ccc907a27ac13</citedby><cites>FETCH-LOGICAL-c2526-f3ba19c1f3d4761aa84eedffedf50106134f81779e86c2b6f9b8ccc907a27ac13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.39146$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.39146$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27923,27924,45573,45574</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27553580$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ba, Jinyu</creatorcontrib><creatorcontrib>Geng, Zhi</creatorcontrib><creatorcontrib>Mu, Jianxin</creatorcontrib><title>Soluble low-κ poly (aryl ether ketone) copolymers containing pendant adamantyl group and long aliphatic side chains</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The aromatic diphenol monomers, 4‐(1‐adamantyl)‐1,3‐benzene diol (AdRES) and 4‐(6‐(4‐hydroxyphenyl)undecan‐6‐yl)phenol (BISPR5R5) were successfully synthesized and used to synthesize a new series of poly (aryl ether ketone) copolymers (AdRES‐BISPR5R5‐PEEKs) with different percentages of two diphenol monomers by nucleophilic aromatic substitution polycondensation. The structure of copolymers was confirmed using FTIR and 1H NMR spectroscopy and their thermal and mechanical properties and solubilities were determined. It was found that the flexibility and toughness properties of the copolymers could be controlled by varying the molar ratio of diphenol monomers containing the pendent rigid adamantyl group and the flexible long side chains. They also showed low dielectric constants (κ = 2.50–2.88 at 1 MHz) and low water absorptions. It revealed that the symmetrical long aliphatic side chains were more conducive for reducing the polarity of the polymer chains, loosening the polymer packing, and subsequently reducing polymers' density and dielectric constants than the pendent rigid adamantyl group. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</description><subject>Applied sciences</subject><subject>copolymers</subject><subject>dielectric properties</subject><subject>Exact sciences and technology</subject><subject>mechanical properties</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>structure-property relations</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp1kM1KxDAURoMoOI4ufINsBF10JmnapF2K_yA6ouIy3KaJE820Jemg82o-hM9kxqo7F-EG7jkf3A-hfUomlJB0Cl03YSXN-AYaUVKKJONpsYlGcUeToizzbbQTwgshlOaEj1B_37pl5TR27Vvy-YG71q3wIfiVw7qfa49fdd82-girdr1aaB_it-nBNrZ5xp1uamh6DDUs4ozWs2-XHYamjokRAGe7OfRW4WBrjdU8imEXbRlwQe_9zDF6PD97OLlMrm8vrk6OrxOV5ilPDKuAlooaVmeCU4Ai07o2Jr6cUMIpy0xBhSh1wVVacVNWhVKqJAJSAYqyMToacpVvQ_DayM7bRTxOUiLXdclYl_yuK7IHA9tBUOCMh0bZ8CekIs9ZXpDITQfuzTq9-j9QHs9mv8nJYNjQ6_c_A_yr5IKJXD7dXMiM8dmsYHfylH0B322LWg</recordid><startdate>20131005</startdate><enddate>20131005</enddate><creator>Ba, Jinyu</creator><creator>Geng, Zhi</creator><creator>Mu, Jianxin</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20131005</creationdate><title>Soluble low-κ poly (aryl ether ketone) copolymers containing pendant adamantyl group and long aliphatic side chains</title><author>Ba, Jinyu ; Geng, Zhi ; Mu, Jianxin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2526-f3ba19c1f3d4761aa84eedffedf50106134f81779e86c2b6f9b8ccc907a27ac13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Applied sciences</topic><topic>copolymers</topic><topic>dielectric properties</topic><topic>Exact sciences and technology</topic><topic>mechanical properties</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>structure-property relations</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ba, Jinyu</creatorcontrib><creatorcontrib>Geng, Zhi</creatorcontrib><creatorcontrib>Mu, Jianxin</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ba, Jinyu</au><au>Geng, Zhi</au><au>Mu, Jianxin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Soluble low-κ poly (aryl ether ketone) copolymers containing pendant adamantyl group and long aliphatic side chains</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. 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They also showed low dielectric constants (κ = 2.50–2.88 at 1 MHz) and low water absorptions. It revealed that the symmetrical long aliphatic side chains were more conducive for reducing the polarity of the polymer chains, loosening the polymer packing, and subsequently reducing polymers' density and dielectric constants than the pendent rigid adamantyl group. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.39146</doi><tpages>8</tpages></addata></record> |
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| subjects | Applied sciences copolymers dielectric properties Exact sciences and technology mechanical properties Organic polymers Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts structure-property relations |
| title | Soluble low-κ poly (aryl ether ketone) copolymers containing pendant adamantyl group and long aliphatic side chains |
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