Synthesis, characterization, and hydrolytic degradation of biodegradable poly(ether ester)-urethane copolymers based on ε-caprolactone and poly(ethylene glycol)
In this article, a new kind of biodegradable poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone)-based polyurethane (PCEC-U) copolymers were successfully synthesized by melt-polycondensation method from ε-caprolactone (ε-CL), poly(ethylene glycol) (PEG), 1,4-butanediol (BD), and isophoro...
Gespeichert in:
| Veröffentlicht in: | Journal of applied polymer science 2009-07, Vol.113 (2), p.1111-1119 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1119 |
|---|---|
| container_issue | 2 |
| container_start_page | 1111 |
| container_title | Journal of applied polymer science |
| container_volume | 113 |
| creator | Gong, Chang Yang Fu, Shao Zhi Gu, Ying Chun Liu, Cai Bing Kan, Bing Deng, Hong Xin Luo, Feng Qian, Zhi Yong |
| description | In this article, a new kind of biodegradable poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone)-based polyurethane (PCEC-U) copolymers were successfully synthesized by melt-polycondensation method from ε-caprolactone (ε-CL), poly(ethylene glycol) (PEG), 1,4-butanediol (BD), and isophorone diisocyanate (IPDI). The obtained copolymers were characterized by ¹H-nuclear magnetic resonance (¹H-NMR), FTIR, and gel permeation chromatography (GPC). Thermal properties of PCEC-U copolymers were studied by DSC and TGA/DTG under nitrogen atmosphere. Water absorption and hydrolytic degradation behavior of these copolymers were also investigated. Hydrolytic degradation behavior was studied by weight loss method. ¹H-NMR and GPC were also used to characterize the hydrolytic degradation behavior of PCEC-U copolymers. The molecular weight of PCL block and PEG block in soft segment and the content of hard segment strongly affected the water absorption and hydrolytic degradation behavior of PCEC-U copolymers. |
| doi_str_mv | 10.1002/app.29946 |
| format | Article |
| fullrecord | <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_app_29946</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>APP29946</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4026-6927f915a172ceccfad123a31e6e19ab2c1b921b7be819f69253c6d2d7d9ab613</originalsourceid><addsrcrecordid>eNp1kMFu1DAQhi1EJZaWA0-AL0is1LQeZ-2sj21FC1VVKpUKiYs1sZ3dQBpH9lYQ3oaH4DV4JmabtjdOluf__n9GP2OvQRyAEPIQh-FAGrPQz9gMhKmKhZbL52xGGhRLY9QL9jLnb0IAKKFn7Pf12G_WIbd5n7s1JnSbkNpfuGljv8-x93w9-hS7cdM67sMqob_XeGx43caHSd0FPhD0LlBW4iFTyLy4S_TFPnAXt-JtSJnXmIPn5P_7p3A4UDJtjMRsVz1GjF2gyaobXezme2ynwS6HVw_vLrs5ff_55ENx8ens48nRReEWQupCG1k1BhRCJV1wrkEPssQSgg5gsJYOaiOhruqwBNMQrkqnvfSVJ1VDucvmU65LMecUGjuk9hbTaEHYbbeWurX33RL7dmIHzA67JmHv2vxkkKCkNrDlDifuR9uF8f-B9ujq6jG5mBwtdfjzyYHpu9VVWSn75fLMqq_m9FgdK3tO_JuJbzBaXCW64uZaCigFaFnSCeU_EEGlsg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis, characterization, and hydrolytic degradation of biodegradable poly(ether ester)-urethane copolymers based on ε-caprolactone and poly(ethylene glycol)</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Gong, Chang Yang ; Fu, Shao Zhi ; Gu, Ying Chun ; Liu, Cai Bing ; Kan, Bing ; Deng, Hong Xin ; Luo, Feng ; Qian, Zhi Yong</creator><creatorcontrib>Gong, Chang Yang ; Fu, Shao Zhi ; Gu, Ying Chun ; Liu, Cai Bing ; Kan, Bing ; Deng, Hong Xin ; Luo, Feng ; Qian, Zhi Yong</creatorcontrib><description>In this article, a new kind of biodegradable poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone)-based polyurethane (PCEC-U) copolymers were successfully synthesized by melt-polycondensation method from ε-caprolactone (ε-CL), poly(ethylene glycol) (PEG), 1,4-butanediol (BD), and isophorone diisocyanate (IPDI). The obtained copolymers were characterized by ¹H-nuclear magnetic resonance (¹H-NMR), FTIR, and gel permeation chromatography (GPC). Thermal properties of PCEC-U copolymers were studied by DSC and TGA/DTG under nitrogen atmosphere. Water absorption and hydrolytic degradation behavior of these copolymers were also investigated. Hydrolytic degradation behavior was studied by weight loss method. ¹H-NMR and GPC were also used to characterize the hydrolytic degradation behavior of PCEC-U copolymers. The molecular weight of PCL block and PEG block in soft segment and the content of hard segment strongly affected the water absorption and hydrolytic degradation behavior of PCEC-U copolymers.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.29946</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; biodegradable ; Exact sciences and technology ; hydrolytic degradation ; Organic polymers ; Physicochemistry of polymers ; poly(ethylene glycol) ; poly(ε-caprolactone) ; Polycondensation ; polyurethane ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; water absorption</subject><ispartof>Journal of applied polymer science, 2009-07, Vol.113 (2), p.1111-1119</ispartof><rights>Copyright © 2009 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4026-6927f915a172ceccfad123a31e6e19ab2c1b921b7be819f69253c6d2d7d9ab613</citedby><cites>FETCH-LOGICAL-c4026-6927f915a172ceccfad123a31e6e19ab2c1b921b7be819f69253c6d2d7d9ab613</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.29946$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.29946$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21526916$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Gong, Chang Yang</creatorcontrib><creatorcontrib>Fu, Shao Zhi</creatorcontrib><creatorcontrib>Gu, Ying Chun</creatorcontrib><creatorcontrib>Liu, Cai Bing</creatorcontrib><creatorcontrib>Kan, Bing</creatorcontrib><creatorcontrib>Deng, Hong Xin</creatorcontrib><creatorcontrib>Luo, Feng</creatorcontrib><creatorcontrib>Qian, Zhi Yong</creatorcontrib><title>Synthesis, characterization, and hydrolytic degradation of biodegradable poly(ether ester)-urethane copolymers based on ε-caprolactone and poly(ethylene glycol)</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>In this article, a new kind of biodegradable poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone)-based polyurethane (PCEC-U) copolymers were successfully synthesized by melt-polycondensation method from ε-caprolactone (ε-CL), poly(ethylene glycol) (PEG), 1,4-butanediol (BD), and isophorone diisocyanate (IPDI). The obtained copolymers were characterized by ¹H-nuclear magnetic resonance (¹H-NMR), FTIR, and gel permeation chromatography (GPC). Thermal properties of PCEC-U copolymers were studied by DSC and TGA/DTG under nitrogen atmosphere. Water absorption and hydrolytic degradation behavior of these copolymers were also investigated. Hydrolytic degradation behavior was studied by weight loss method. ¹H-NMR and GPC were also used to characterize the hydrolytic degradation behavior of PCEC-U copolymers. The molecular weight of PCL block and PEG block in soft segment and the content of hard segment strongly affected the water absorption and hydrolytic degradation behavior of PCEC-U copolymers.</description><subject>Applied sciences</subject><subject>biodegradable</subject><subject>Exact sciences and technology</subject><subject>hydrolytic degradation</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>poly(ethylene glycol)</subject><subject>poly(ε-caprolactone)</subject><subject>Polycondensation</subject><subject>polyurethane</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>water absorption</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp1kMFu1DAQhi1EJZaWA0-AL0is1LQeZ-2sj21FC1VVKpUKiYs1sZ3dQBpH9lYQ3oaH4DV4JmabtjdOluf__n9GP2OvQRyAEPIQh-FAGrPQz9gMhKmKhZbL52xGGhRLY9QL9jLnb0IAKKFn7Pf12G_WIbd5n7s1JnSbkNpfuGljv8-x93w9-hS7cdM67sMqob_XeGx43caHSd0FPhD0LlBW4iFTyLy4S_TFPnAXt-JtSJnXmIPn5P_7p3A4UDJtjMRsVz1GjF2gyaobXezme2ynwS6HVw_vLrs5ff_55ENx8ens48nRReEWQupCG1k1BhRCJV1wrkEPssQSgg5gsJYOaiOhruqwBNMQrkqnvfSVJ1VDucvmU65LMecUGjuk9hbTaEHYbbeWurX33RL7dmIHzA67JmHv2vxkkKCkNrDlDifuR9uF8f-B9ujq6jG5mBwtdfjzyYHpu9VVWSn75fLMqq_m9FgdK3tO_JuJbzBaXCW64uZaCigFaFnSCeU_EEGlsg</recordid><startdate>20090715</startdate><enddate>20090715</enddate><creator>Gong, Chang Yang</creator><creator>Fu, Shao Zhi</creator><creator>Gu, Ying Chun</creator><creator>Liu, Cai Bing</creator><creator>Kan, Bing</creator><creator>Deng, Hong Xin</creator><creator>Luo, Feng</creator><creator>Qian, Zhi Yong</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20090715</creationdate><title>Synthesis, characterization, and hydrolytic degradation of biodegradable poly(ether ester)-urethane copolymers based on ε-caprolactone and poly(ethylene glycol)</title><author>Gong, Chang Yang ; Fu, Shao Zhi ; Gu, Ying Chun ; Liu, Cai Bing ; Kan, Bing ; Deng, Hong Xin ; Luo, Feng ; Qian, Zhi Yong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4026-6927f915a172ceccfad123a31e6e19ab2c1b921b7be819f69253c6d2d7d9ab613</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>biodegradable</topic><topic>Exact sciences and technology</topic><topic>hydrolytic degradation</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>poly(ethylene glycol)</topic><topic>poly(ε-caprolactone)</topic><topic>Polycondensation</topic><topic>polyurethane</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>water absorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gong, Chang Yang</creatorcontrib><creatorcontrib>Fu, Shao Zhi</creatorcontrib><creatorcontrib>Gu, Ying Chun</creatorcontrib><creatorcontrib>Liu, Cai Bing</creatorcontrib><creatorcontrib>Kan, Bing</creatorcontrib><creatorcontrib>Deng, Hong Xin</creatorcontrib><creatorcontrib>Luo, Feng</creatorcontrib><creatorcontrib>Qian, Zhi Yong</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gong, Chang Yang</au><au>Fu, Shao Zhi</au><au>Gu, Ying Chun</au><au>Liu, Cai Bing</au><au>Kan, Bing</au><au>Deng, Hong Xin</au><au>Luo, Feng</au><au>Qian, Zhi Yong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, characterization, and hydrolytic degradation of biodegradable poly(ether ester)-urethane copolymers based on ε-caprolactone and poly(ethylene glycol)</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2009-07-15</date><risdate>2009</risdate><volume>113</volume><issue>2</issue><spage>1111</spage><epage>1119</epage><pages>1111-1119</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>In this article, a new kind of biodegradable poly(ε-caprolactone)-poly(ethylene glycol)-poly(ε-caprolactone)-based polyurethane (PCEC-U) copolymers were successfully synthesized by melt-polycondensation method from ε-caprolactone (ε-CL), poly(ethylene glycol) (PEG), 1,4-butanediol (BD), and isophorone diisocyanate (IPDI). The obtained copolymers were characterized by ¹H-nuclear magnetic resonance (¹H-NMR), FTIR, and gel permeation chromatography (GPC). Thermal properties of PCEC-U copolymers were studied by DSC and TGA/DTG under nitrogen atmosphere. Water absorption and hydrolytic degradation behavior of these copolymers were also investigated. Hydrolytic degradation behavior was studied by weight loss method. ¹H-NMR and GPC were also used to characterize the hydrolytic degradation behavior of PCEC-U copolymers. The molecular weight of PCL block and PEG block in soft segment and the content of hard segment strongly affected the water absorption and hydrolytic degradation behavior of PCEC-U copolymers.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.29946</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8995 |
| ispartof | Journal of applied polymer science, 2009-07, Vol.113 (2), p.1111-1119 |
| issn | 0021-8995 1097-4628 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_app_29946 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences biodegradable Exact sciences and technology hydrolytic degradation Organic polymers Physicochemistry of polymers poly(ethylene glycol) poly(ε-caprolactone) Polycondensation polyurethane Preparation, kinetics, thermodynamics, mechanism and catalysts water absorption |
| title | Synthesis, characterization, and hydrolytic degradation of biodegradable poly(ether ester)-urethane copolymers based on ε-caprolactone and poly(ethylene glycol) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T02%3A44%3A56IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis,%20characterization,%20and%20hydrolytic%20degradation%20of%20biodegradable%20poly(ether%20ester)-urethane%20copolymers%20based%20on%20%CE%B5-caprolactone%20and%20poly(ethylene%20glycol)&rft.jtitle=Journal%20of%20applied%20polymer%20science&rft.au=Gong,%20Chang%20Yang&rft.date=2009-07-15&rft.volume=113&rft.issue=2&rft.spage=1111&rft.epage=1119&rft.pages=1111-1119&rft.issn=0021-8995&rft.eissn=1097-4628&rft.coden=JAPNAB&rft_id=info:doi/10.1002/app.29946&rft_dat=%3Cwiley_cross%3EAPP29946%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |