ZnS deposition on oxadiazole-terpyridine copolymer
The combination of inorganic salts and macromolecules leads to supramolecular structures with new interesting physical and chemical properties. The deposition of ZnS (Wurtzite) on oxadiazole–terpyridine copolymer P‐90/10 synthesized by free radical copolymerization were investigated. The apparent or...
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| Veröffentlicht in: | Journal of applied polymer science 2006-08, Vol.101 (3), p.1913-1918 |
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| container_end_page | 1918 |
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| container_issue | 3 |
| container_start_page | 1913 |
| container_title | Journal of applied polymer science |
| container_volume | 101 |
| creator | Chrissanthopoulos, A. Tzanetos, N. P. Andreopoulou, A. K. Kallitsis, J. Dalas, E. |
| description | The combination of inorganic salts and macromolecules leads to supramolecular structures with new interesting physical and chemical properties. The deposition of ZnS (Wurtzite) on oxadiazole–terpyridine copolymer P‐90/10 synthesized by free radical copolymerization were investigated. The apparent order of the crystallization process was found to be 2 that indicated a surface diffusion‐controlled mechanism. Critical nucleus formation proceeds via complexation of the ZnS molecules to the N atoms as concluded from computational chemistry calculations. The number of ions forming the critical nucleus was found experimentally to be (n*exp = 1.71 ± 0.24) in accordance with the computational chemistry calculations by the PM3 method of the MOPAC program package. The surface energy of the growing ZnS phase was found to be 121 mJ/m2 typical for sparingly soluble salts. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1913–1918, 2006 |
| doi_str_mv | 10.1002/app.23656 |
| format | Article |
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P. ; Andreopoulou, A. K. ; Kallitsis, J. ; Dalas, E.</creator><creatorcontrib>Chrissanthopoulos, A. ; Tzanetos, N. P. ; Andreopoulou, A. K. ; Kallitsis, J. ; Dalas, E.</creatorcontrib><description>The combination of inorganic salts and macromolecules leads to supramolecular structures with new interesting physical and chemical properties. The deposition of ZnS (Wurtzite) on oxadiazole–terpyridine copolymer P‐90/10 synthesized by free radical copolymerization were investigated. The apparent order of the crystallization process was found to be 2 that indicated a surface diffusion‐controlled mechanism. Critical nucleus formation proceeds via complexation of the ZnS molecules to the N atoms as concluded from computational chemistry calculations. The number of ions forming the critical nucleus was found experimentally to be (n*exp = 1.71 ± 0.24) in accordance with the computational chemistry calculations by the PM3 method of the MOPAC program package. The surface energy of the growing ZnS phase was found to be 121 mJ/m2 typical for sparingly soluble salts. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1913–1918, 2006</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.23656</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; crystallization ; Exact sciences and technology ; functionalization of polymers ; metal-polymer complexes ; molecular modeling ; nucleation ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization ; Special properties (catalyst, reagent or carrier)</subject><ispartof>Journal of applied polymer science, 2006-08, Vol.101 (3), p.1913-1918</ispartof><rights>Copyright © 2006 Wiley Periodicals, Inc.</rights><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2976-7ad8c421a580a156f96cb57509ae6b9f925fb1ef4d567513a4762ce93a6995673</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.23656$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.23656$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17924078$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Chrissanthopoulos, A.</creatorcontrib><creatorcontrib>Tzanetos, N. P.</creatorcontrib><creatorcontrib>Andreopoulou, A. K.</creatorcontrib><creatorcontrib>Kallitsis, J.</creatorcontrib><creatorcontrib>Dalas, E.</creatorcontrib><title>ZnS deposition on oxadiazole-terpyridine copolymer</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The combination of inorganic salts and macromolecules leads to supramolecular structures with new interesting physical and chemical properties. The deposition of ZnS (Wurtzite) on oxadiazole–terpyridine copolymer P‐90/10 synthesized by free radical copolymerization were investigated. The apparent order of the crystallization process was found to be 2 that indicated a surface diffusion‐controlled mechanism. Critical nucleus formation proceeds via complexation of the ZnS molecules to the N atoms as concluded from computational chemistry calculations. The number of ions forming the critical nucleus was found experimentally to be (n*exp = 1.71 ± 0.24) in accordance with the computational chemistry calculations by the PM3 method of the MOPAC program package. The surface energy of the growing ZnS phase was found to be 121 mJ/m2 typical for sparingly soluble salts. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1913–1918, 2006</description><subject>Applied sciences</subject><subject>crystallization</subject><subject>Exact sciences and technology</subject><subject>functionalization of polymers</subject><subject>metal-polymer complexes</subject><subject>molecular modeling</subject><subject>nucleation</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Special properties (catalyst, reagent or carrier)</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNp1j09LAzEUxIMoWKsHv0EvHjxsm2Q3yeZYqq1i1UIVwUt4zSYQ3e6GpNCun96t65-T8GAO7zfDDELnBA8JxnQE3g9pyhk_QD2CpUgyTvND1Gt_JMmlZMfoJMY3jAlhmPcQfa2Wg8L4OrqNq6vB_nZQOPioS5NsTPBNcIWrzEDXvi6btQmn6MhCGc3Zt_bR8_T6aXKTzB9nt5PxPNFUCp4IKHKdUQIsx0AYt5LrFRMMSzB8Ja2kzK6IsVnBuGAkhUxwqo1Mgbc1uUj76LLL1aGOMRirfHBrCI0iWO3Hqnas-hrbshcd6yFqKG2ASrv4ZxCSZljkLTfquK0rTfN_oBovFj_JSedwcWN2vw4I76rtKJh6eZip6Z28v0o5V8v0ExXDcXc</recordid><startdate>20060805</startdate><enddate>20060805</enddate><creator>Chrissanthopoulos, A.</creator><creator>Tzanetos, N. 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K.</creatorcontrib><creatorcontrib>Kallitsis, J.</creatorcontrib><creatorcontrib>Dalas, E.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chrissanthopoulos, A.</au><au>Tzanetos, N. P.</au><au>Andreopoulou, A. K.</au><au>Kallitsis, J.</au><au>Dalas, E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>ZnS deposition on oxadiazole-terpyridine copolymer</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2006-08-05</date><risdate>2006</risdate><volume>101</volume><issue>3</issue><spage>1913</spage><epage>1918</epage><pages>1913-1918</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The combination of inorganic salts and macromolecules leads to supramolecular structures with new interesting physical and chemical properties. The deposition of ZnS (Wurtzite) on oxadiazole–terpyridine copolymer P‐90/10 synthesized by free radical copolymerization were investigated. The apparent order of the crystallization process was found to be 2 that indicated a surface diffusion‐controlled mechanism. Critical nucleus formation proceeds via complexation of the ZnS molecules to the N atoms as concluded from computational chemistry calculations. The number of ions forming the critical nucleus was found experimentally to be (n*exp = 1.71 ± 0.24) in accordance with the computational chemistry calculations by the PM3 method of the MOPAC program package. The surface energy of the growing ZnS phase was found to be 121 mJ/m2 typical for sparingly soluble salts. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1913–1918, 2006</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.23656</doi><tpages>6</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences crystallization Exact sciences and technology functionalization of polymers metal-polymer complexes molecular modeling nucleation Organic polymers Physicochemistry of polymers Properties and characterization Special properties (catalyst, reagent or carrier) |
| title | ZnS deposition on oxadiazole-terpyridine copolymer |
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