Hydroxyalkylation of parabanic acid. III. Polymers from parabanic acid and ethylene carbonate

The influence of initial molar ratio of reagents, amount of catalyst, and temperature of reaction between parabanic acid and ethylene carbonate on structure of product was studied. The reaction led to the opening of the trioxoimidazolidine ring, resulting in formation of thermally resistant linear p...

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Veröffentlicht in:Journal of applied polymer science 2006-04, Vol.100 (2), p.1443-1449
Hauptverfasser: Zarzyka-Niemiec, Iwona, Naróg, Dorota, Lubczak, Jacek
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creator Zarzyka-Niemiec, Iwona
Naróg, Dorota
Lubczak, Jacek
description The influence of initial molar ratio of reagents, amount of catalyst, and temperature of reaction between parabanic acid and ethylene carbonate on structure of product was studied. The reaction led to the opening of the trioxoimidazolidine ring, resulting in formation of thermally resistant linear polymeric products constructed of urea and oxoamidoester subunits linked via imide bond. The percentage of side products was estimated. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1443–1449, 2006
doi_str_mv 10.1002/app.23506
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J Appl Polym Sci 100: 1443–1449, 2006</description><subject>Applied sciences</subject><subject>ethylene carbonate</subject><subject>Exact sciences and technology</subject><subject>hydroxyalkylation</subject><subject>Organic polymers</subject><subject>parabanic acid</subject><subject>Physicochemistry of polymers</subject><subject>Polycondensation</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>ring-opening polymerization</subject><subject>structure</subject><subject>thermal stability</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLw0AUhQdRsFYX_oPZuHCRdB6ZTLqUom2g1SIVQZDhZjKDsWkSZgI2_95ofIDg6i7u9x0OB6FzSkJKCJtA04SMCxIfoBElUxlEMUsO0aj_0SCZTsUxOvH-lRBKe2iEnhdd7up9B-W2K6Et6grXFjfgIIOq0Bh0kYc4TdMQr-uy2xnnsXX17g-CocqxaV-60lQGa3BZXUFrTtGRhdKbs687Rg8315vZIljezdPZ1TLQnMs4EJHgkaHUEpYk0lhqE8JsJnKqE82M5maqo0z2pXXEsoRyzmhMRCR5LkQcxXyMLodc7WrvnbGqccUOXKcoUR-7qH4X9blLz14MbANeQ2kdVLrwv4LsuyRC9txk4N6K0nT_B6qr9fo7ORiMwrdm_2OA26pYcinU4-1cbVZP9F6uZorwd041f6Q</recordid><startdate>20060415</startdate><enddate>20060415</enddate><creator>Zarzyka-Niemiec, Iwona</creator><creator>Naróg, Dorota</creator><creator>Lubczak, Jacek</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20060415</creationdate><title>Hydroxyalkylation of parabanic acid. 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subjects Applied sciences
ethylene carbonate
Exact sciences and technology
hydroxyalkylation
Organic polymers
parabanic acid
Physicochemistry of polymers
Polycondensation
Preparation, kinetics, thermodynamics, mechanism and catalysts
ring-opening polymerization
structure
thermal stability
title Hydroxyalkylation of parabanic acid. III. Polymers from parabanic acid and ethylene carbonate
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