Synthesis of 1,3-benzodioxole end-functionalized polymers via reversible addition-fragmentation chain transfer polymerization
Reversible addition–fragmentation chain transfer (RAFT) polymerization of styrene was carried out in the presence of a novel RAFT reagent, bearing 1,3‐benzodioxole group, benzo [1,3]dioxole‐5‐carbodithioic acid benzo [1,3]dioxol‐5‐ylmethyl ester (BDCB), to prepare end‐functionalized polystyrene. The...
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| Veröffentlicht in: | Journal of applied polymer science 2006-03, Vol.99 (6), p.3535-3539 |
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| container_title | Journal of applied polymer science |
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| creator | Zhou, Nianchen Lu, Lude Zhu, Xiulin Yang, Xujie Wang, Xin Zhu, Jian Cheng, Zhenping |
| description | Reversible addition–fragmentation chain transfer (RAFT) polymerization of styrene was carried out in the presence of a novel RAFT reagent, bearing 1,3‐benzodioxole group, benzo [1,3]dioxole‐5‐carbodithioic acid benzo [1,3]dioxol‐5‐ylmethyl ester (BDCB), to prepare end‐functionalized polystyrene. The polymerization results showed that RAFT polymerization of styrene could be well controlled. Number–average molecular weight (Mn(GPC)) increased linearly with monomer conversion, and molecular weight distributions were narrow (Mw/Mn < 1.4). The successful reaction of chain extension and analysis of 1H NMR spectra confirmed the existence of the functional 1,3‐benzodioxole group at the chain‐end of polystyrene. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3535–3539, 2006 |
| doi_str_mv | 10.1002/app.22918 |
| format | Article |
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The polymerization results showed that RAFT polymerization of styrene could be well controlled. Number–average molecular weight (Mn(GPC)) increased linearly with monomer conversion, and molecular weight distributions were narrow (Mw/Mn < 1.4). The successful reaction of chain extension and analysis of 1H NMR spectra confirmed the existence of the functional 1,3‐benzodioxole group at the chain‐end of polystyrene. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3535–3539, 2006</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.22918</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>1,3‐benzodioxole ; 3-benzodioxole ; Applied sciences ; Chemical reactions and properties ; Crosslinking, vulcanization ; Exact sciences and technology ; functional material ; Organic polymers ; Physicochemistry of polymers ; piperonic acid ; RAFT ; styrene</subject><ispartof>Journal of applied polymer science, 2006-03, Vol.99 (6), p.3535-3539</ispartof><rights>Copyright © 2006 Wiley Periodicals, Inc.</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3378-64b4b3942cb2cfabe25fd72337404a80c8125e995a3de7dd87213908ef213ada3</citedby><cites>FETCH-LOGICAL-c3378-64b4b3942cb2cfabe25fd72337404a80c8125e995a3de7dd87213908ef213ada3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.22918$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.22918$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17595556$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhou, Nianchen</creatorcontrib><creatorcontrib>Lu, Lude</creatorcontrib><creatorcontrib>Zhu, Xiulin</creatorcontrib><creatorcontrib>Yang, Xujie</creatorcontrib><creatorcontrib>Wang, Xin</creatorcontrib><creatorcontrib>Zhu, Jian</creatorcontrib><creatorcontrib>Cheng, Zhenping</creatorcontrib><title>Synthesis of 1,3-benzodioxole end-functionalized polymers via reversible addition-fragmentation chain transfer polymerization</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Reversible addition–fragmentation chain transfer (RAFT) polymerization of styrene was carried out in the presence of a novel RAFT reagent, bearing 1,3‐benzodioxole group, benzo [1,3]dioxole‐5‐carbodithioic acid benzo [1,3]dioxol‐5‐ylmethyl ester (BDCB), to prepare end‐functionalized polystyrene. The polymerization results showed that RAFT polymerization of styrene could be well controlled. Number–average molecular weight (Mn(GPC)) increased linearly with monomer conversion, and molecular weight distributions were narrow (Mw/Mn < 1.4). The successful reaction of chain extension and analysis of 1H NMR spectra confirmed the existence of the functional 1,3‐benzodioxole group at the chain‐end of polystyrene. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3535–3539, 2006</description><subject>1,3‐benzodioxole</subject><subject>3-benzodioxole</subject><subject>Applied sciences</subject><subject>Chemical reactions and properties</subject><subject>Crosslinking, vulcanization</subject><subject>Exact sciences and technology</subject><subject>functional material</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>piperonic acid</subject><subject>RAFT</subject><subject>styrene</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNp1kE9PFTEUxRuiCU904TeYDQsTC_0znekskQiSECSikV1zp72F6rzOpB2R9xK_O3080JWre2_O75zkHkLecnbAGROHME0HQnRc75AFZ11L60boF2RRNE5116ld8irnH4xxrlizIH-uVnG-xRxyNfqKv5e0x7geXRjvxwErjI76X9HOYYwwhDW6ahqH1RJTru4CVAnvyhr6goJzYYNRn-BmiXGGzVXZWwixmhPE7DE9u8P6UX1NXnoYMr55mnvk28nHr8ef6Pnn07Pjo3NqpWw1beq-7mVXC9sL66FHobxrRdFqVoNmVnOhsDwH0mHrnG4Flx3T6MsEB3KPvNvm2jTmnNCbKYUlpJXhzGx6M6U389hbYfe37ATZwlC-iTbkf4ZWdUqppnCHW-53GHD1_0BzdHn5nEy3jpBnvP_rgPTTNK1slfl-cWqu9MkH_uX62mj5AK_JjvY</recordid><startdate>20060315</startdate><enddate>20060315</enddate><creator>Zhou, Nianchen</creator><creator>Lu, Lude</creator><creator>Zhu, Xiulin</creator><creator>Yang, Xujie</creator><creator>Wang, Xin</creator><creator>Zhu, Jian</creator><creator>Cheng, Zhenping</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20060315</creationdate><title>Synthesis of 1,3-benzodioxole end-functionalized polymers via reversible addition-fragmentation chain transfer polymerization</title><author>Zhou, Nianchen ; Lu, Lude ; Zhu, Xiulin ; Yang, Xujie ; Wang, Xin ; Zhu, Jian ; Cheng, Zhenping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3378-64b4b3942cb2cfabe25fd72337404a80c8125e995a3de7dd87213908ef213ada3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>1,3‐benzodioxole</topic><topic>3-benzodioxole</topic><topic>Applied sciences</topic><topic>Chemical reactions and properties</topic><topic>Crosslinking, vulcanization</topic><topic>Exact sciences and technology</topic><topic>functional material</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>piperonic acid</topic><topic>RAFT</topic><topic>styrene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Nianchen</creatorcontrib><creatorcontrib>Lu, Lude</creatorcontrib><creatorcontrib>Zhu, Xiulin</creatorcontrib><creatorcontrib>Yang, Xujie</creatorcontrib><creatorcontrib>Wang, Xin</creatorcontrib><creatorcontrib>Zhu, Jian</creatorcontrib><creatorcontrib>Cheng, Zhenping</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Nianchen</au><au>Lu, Lude</au><au>Zhu, Xiulin</au><au>Yang, Xujie</au><au>Wang, Xin</au><au>Zhu, Jian</au><au>Cheng, Zhenping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of 1,3-benzodioxole end-functionalized polymers via reversible addition-fragmentation chain transfer polymerization</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2006-03-15</date><risdate>2006</risdate><volume>99</volume><issue>6</issue><spage>3535</spage><epage>3539</epage><pages>3535-3539</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Reversible addition–fragmentation chain transfer (RAFT) polymerization of styrene was carried out in the presence of a novel RAFT reagent, bearing 1,3‐benzodioxole group, benzo [1,3]dioxole‐5‐carbodithioic acid benzo [1,3]dioxol‐5‐ylmethyl ester (BDCB), to prepare end‐functionalized polystyrene. The polymerization results showed that RAFT polymerization of styrene could be well controlled. Number–average molecular weight (Mn(GPC)) increased linearly with monomer conversion, and molecular weight distributions were narrow (Mw/Mn < 1.4). The successful reaction of chain extension and analysis of 1H NMR spectra confirmed the existence of the functional 1,3‐benzodioxole group at the chain‐end of polystyrene. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3535–3539, 2006</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.22918</doi><tpages>5</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | 1,3‐benzodioxole 3-benzodioxole Applied sciences Chemical reactions and properties Crosslinking, vulcanization Exact sciences and technology functional material Organic polymers Physicochemistry of polymers piperonic acid RAFT styrene |
| title | Synthesis of 1,3-benzodioxole end-functionalized polymers via reversible addition-fragmentation chain transfer polymerization |
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