Fluorescence quantum yield of poly(3-octylthiophene) upon electrochemical doping

The in situ optical absorption and fluorescence of poly(3‐octylthiophene) (POT) upon electrochemical doping were studied. Fluorescence from the undoped POT was observed in the acetonitrile electrolyte. It was quenched by the electrochemical doping. The effect of a dopant molecule on the intensity ch...

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Veröffentlicht in:Journal of applied polymer science 2006-05, Vol.100 (4), p.3111-3115
Hauptverfasser: Danno, T., Kobayashi, K., Tanioka, A.
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Kobayashi, K.
Tanioka, A.
description The in situ optical absorption and fluorescence of poly(3‐octylthiophene) (POT) upon electrochemical doping were studied. Fluorescence from the undoped POT was observed in the acetonitrile electrolyte. It was quenched by the electrochemical doping. The effect of a dopant molecule on the intensity change of the fluorescence is 7.5 times greater than the one for the optical absorption. Thus, the fluorescence quantum yield decreased after electrochemical doping. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3111–3115, 2006
doi_str_mv 10.1002/app.22523
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subjects absorption
Applied sciences
Electrical, magnetic and optical properties
electrochemical doping
Exact sciences and technology
fluorescence
Nernst equation
Organic polymers
Physicochemistry of polymers
poly(3-octylthiophene)
Properties and characterization
quantum yield
title Fluorescence quantum yield of poly(3-octylthiophene) upon electrochemical doping
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