Chemical polymerization of pyrrole in the presence of ketone-formaldehyde resins
The chemical polymerizations of pyrrole in the presence of acetophenone and formaldehyde, cyclohexanone, acetaldehyde, and formaldehyde, cyclohexanone and formaldehyde, cyclohexanone, resorcinol, and formaldehyde, cyclohexanone and lignosulfonate formaldehyde, and cyclohexanone, pyrrole, and formald...
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Veröffentlicht in: | Journal of applied polymer science 2005-05, Vol.96 (3), p.618-624 |
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creator | KIZILCAN, Nilgun USTAMEHMETOGLU, Belkis |
description | The chemical polymerizations of pyrrole in the presence of acetophenone and formaldehyde, cyclohexanone, acetaldehyde, and formaldehyde, cyclohexanone and formaldehyde, cyclohexanone, resorcinol, and formaldehyde, cyclohexanone and lignosulfonate formaldehyde, and cyclohexanone, pyrrole, and formaldehyde were accomplished with Ce(IV) salt in acetonitrile solutions. The roles of the resin type, the addition order of the reactants, and the concentrations of the pyrrole and resin on the solubility and conductivity of the resulting products were investigated. The cyclohexanone–acetaldehyde–formaldehyde resin/polypyrrole copolymer had the highest solubility in dimethylformamide. The conductivity and solubility of the copolymers could be controlled by the Ce(IV)/pyrrole/resin molar ratio. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 618–624, 2005 |
doi_str_mv | 10.1002/app.21437 |
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The roles of the resin type, the addition order of the reactants, and the concentrations of the pyrrole and resin on the solubility and conductivity of the resulting products were investigated. The cyclohexanone–acetaldehyde–formaldehyde resin/polypyrrole copolymer had the highest solubility in dimethylformamide. The conductivity and solubility of the copolymers could be controlled by the Ce(IV)/pyrrole/resin molar ratio. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 618–624, 2005</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.21437</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; conducting polymers ; copolymerization ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polymers with particular properties ; polypyrroles ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; redox polymers ; resins</subject><ispartof>Journal of applied polymer science, 2005-05, Vol.96 (3), p.618-624</ispartof><rights>Copyright © 2005 Wiley Periodicals, Inc.</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3377-308075674878153558405767625dd26f46bc0b12a1d88ff6f50194a4df9ae3ad3</citedby><cites>FETCH-LOGICAL-c3377-308075674878153558405767625dd26f46bc0b12a1d88ff6f50194a4df9ae3ad3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.21437$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.21437$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16633546$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>KIZILCAN, Nilgun</creatorcontrib><creatorcontrib>USTAMEHMETOGLU, Belkis</creatorcontrib><title>Chemical polymerization of pyrrole in the presence of ketone-formaldehyde resins</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The chemical polymerizations of pyrrole in the presence of acetophenone and formaldehyde, cyclohexanone, acetaldehyde, and formaldehyde, cyclohexanone and formaldehyde, cyclohexanone, resorcinol, and formaldehyde, cyclohexanone and lignosulfonate formaldehyde, and cyclohexanone, pyrrole, and formaldehyde were accomplished with Ce(IV) salt in acetonitrile solutions. The roles of the resin type, the addition order of the reactants, and the concentrations of the pyrrole and resin on the solubility and conductivity of the resulting products were investigated. The cyclohexanone–acetaldehyde–formaldehyde resin/polypyrrole copolymer had the highest solubility in dimethylformamide. The conductivity and solubility of the copolymers could be controlled by the Ce(IV)/pyrrole/resin molar ratio. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 618–624, 2005</description><subject>Applied sciences</subject><subject>conducting polymers</subject><subject>copolymerization</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>polypyrroles</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>redox polymers</subject><subject>resins</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNp1kDtPwzAUhS0EEqUw8A-yMDCkteP4kbFEUJAKVAJUxGK5ybVqmpfsSBB-PSnhMTHd4Xzfke5B6JTgCcE4muqmmUQkpmIPjQhORBjzSO6jUZ-RUCYJO0RH3r9iTAjDfISW6QZKm-kiaOqiK8HZD93augpqEzSdc3UBga2CdgNB48BDlcEu2kJbVxCa2pW6yGHT5RD0sa38MTowuvBw8n3H6Onq8jG9Dhf385t0tggzSoUIKZZYMC5iKSRhlDEZYya44BHL84ibmK8zvCaRJrmUxnDDMEliHecm0UB1TsfofOjNXO29A6MaZ0vtOkWw2k2h-inU1xQ9ezawjfb9q8bpKrP-T-CcUhbznpsO3JstoPu_UM2Wy5_mcDCsb-H919Buq7iggqnV3VxdpBcr8vxyqx7oJ-h_fC0</recordid><startdate>20050505</startdate><enddate>20050505</enddate><creator>KIZILCAN, Nilgun</creator><creator>USTAMEHMETOGLU, Belkis</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20050505</creationdate><title>Chemical polymerization of pyrrole in the presence of ketone-formaldehyde resins</title><author>KIZILCAN, Nilgun ; USTAMEHMETOGLU, Belkis</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3377-308075674878153558405767625dd26f46bc0b12a1d88ff6f50194a4df9ae3ad3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Applied sciences</topic><topic>conducting polymers</topic><topic>copolymerization</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular properties</topic><topic>polypyrroles</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>redox polymers</topic><topic>resins</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>KIZILCAN, Nilgun</creatorcontrib><creatorcontrib>USTAMEHMETOGLU, Belkis</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>KIZILCAN, Nilgun</au><au>USTAMEHMETOGLU, Belkis</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chemical polymerization of pyrrole in the presence of ketone-formaldehyde resins</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. 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The conductivity and solubility of the copolymers could be controlled by the Ce(IV)/pyrrole/resin molar ratio. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 618–624, 2005</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.21437</doi><tpages>7</tpages></addata></record> |
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subjects | Applied sciences conducting polymers copolymerization Exact sciences and technology Organic polymers Physicochemistry of polymers Polymers with particular properties polypyrroles Preparation, kinetics, thermodynamics, mechanism and catalysts redox polymers resins |
title | Chemical polymerization of pyrrole in the presence of ketone-formaldehyde resins |
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