Application of hindered piperidine amine and/or tertiary amine in the modification of polyamide 6
PA 6 resin was produced in a hydrolytic‐polymeric process in which ε‐caprolactam was polymerized in the presence of water as initiator, isophthalic acid and benzoic acid as chain regulators, by polymerizing caprolactam in the presence of 7.5% by weight of water, 0.2% by weight of isophthalic acid, 0...
Gespeichert in:
| Veröffentlicht in: | Journal of applied polymer science 2004-12, Vol.94 (6), p.2489-2493 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2493 |
|---|---|
| container_issue | 6 |
| container_start_page | 2489 |
| container_title | Journal of applied polymer science |
| container_volume | 94 |
| creator | Guo, Xitao Zhao, Yaoming Ning, Ping Ai, Xiying |
| description | PA 6 resin was produced in a hydrolytic‐polymeric process in which ε‐caprolactam was polymerized in the presence of water as initiator, isophthalic acid and benzoic acid as chain regulators, by polymerizing caprolactam in the presence of 7.5% by weight of water, 0.2% by weight of isophthalic acid, 0.1% by weight of benzoic acid, each percentage being based on caprolactam. By adding hindered piperidine amine and/or tertiary amine to the polymeric system, the effects of additives on the polymer were studied. The results showed that: the addition of 0.1 ∼ 0.2% additives can improve the melt stability of polyamide 6; the addition of 0.2% additives can protect mechanical properties of polyamide 6 fibers after exposure to high temperature; and the addition of 0.05 ∼ 0.25% additives can increase the amino end group content of polyamide 6 and thereby increase the dyeability of polyamide fibers. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2489–2493, 2004 |
| doi_str_mv | 10.1002/app.21209 |
| format | Article |
| fullrecord | <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_app_21209</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>APP21209</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3359-2a4aef5541d623223d62b6db70cf570cee3fb106c3c51a521711789550ac1ed93</originalsourceid><addsrcrecordid>eNp1kEtLAzEUhYMoWKsL_0E2LlxMm8ckM7MsVatQtBSly5DmQaPTmZAMaP-9sVMfGzf3wL3fOVwOAJcYjTBCZCy9HxFMUHUEBhhVRZZzUh6DQbrhrKwqdgrOYnxFCGOG-ADIife1U7JzbQNbCzeu0SYYDb3zJjjtGgPldj8bPW4D7EzonAy7w9Y1sNsYuG21s39ifFvvEqAN5OfgxMo6mouDDsHL3e3z9D6bP80eppN5pihlVUZkLo1lLMeaE0oITbLmel0gZVkaxlC7xogrqhiWjOAC46KsGENSYaMrOgTXfa4KbYzBWOGD26ZPBUbiqxuRuhH7bhJ71bNeRiVrG2SjXPw1cJLT1FDixj337mqz-z9QTBaL7-Ssd7jYmY8fhwxvghe0YGL1OBPzm3K5zB-RWNFPpoqCGg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Application of hindered piperidine amine and/or tertiary amine in the modification of polyamide 6</title><source>Wiley Online Library All Journals</source><creator>Guo, Xitao ; Zhao, Yaoming ; Ning, Ping ; Ai, Xiying</creator><creatorcontrib>Guo, Xitao ; Zhao, Yaoming ; Ning, Ping ; Ai, Xiying</creatorcontrib><description>PA 6 resin was produced in a hydrolytic‐polymeric process in which ε‐caprolactam was polymerized in the presence of water as initiator, isophthalic acid and benzoic acid as chain regulators, by polymerizing caprolactam in the presence of 7.5% by weight of water, 0.2% by weight of isophthalic acid, 0.1% by weight of benzoic acid, each percentage being based on caprolactam. By adding hindered piperidine amine and/or tertiary amine to the polymeric system, the effects of additives on the polymer were studied. The results showed that: the addition of 0.1 ∼ 0.2% additives can improve the melt stability of polyamide 6; the addition of 0.2% additives can protect mechanical properties of polyamide 6 fibers after exposure to high temperature; and the addition of 0.05 ∼ 0.25% additives can increase the amino end group content of polyamide 6 and thereby increase the dyeability of polyamide fibers. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2489–2493, 2004</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.21209</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; dyeability ; Exact sciences and technology ; Fibers and threads ; Forms of application and semi-finished materials ; hindered amine ; PA 6 ; Polymer industry, paints, wood ; stability ; Technology of polymers ; tertiary amine</subject><ispartof>Journal of applied polymer science, 2004-12, Vol.94 (6), p.2489-2493</ispartof><rights>Copyright © 2004 Wiley Periodicals, Inc.</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3359-2a4aef5541d623223d62b6db70cf570cee3fb106c3c51a521711789550ac1ed93</citedby><cites>FETCH-LOGICAL-c3359-2a4aef5541d623223d62b6db70cf570cee3fb106c3c51a521711789550ac1ed93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.21209$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.21209$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16243011$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Guo, Xitao</creatorcontrib><creatorcontrib>Zhao, Yaoming</creatorcontrib><creatorcontrib>Ning, Ping</creatorcontrib><creatorcontrib>Ai, Xiying</creatorcontrib><title>Application of hindered piperidine amine and/or tertiary amine in the modification of polyamide 6</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>PA 6 resin was produced in a hydrolytic‐polymeric process in which ε‐caprolactam was polymerized in the presence of water as initiator, isophthalic acid and benzoic acid as chain regulators, by polymerizing caprolactam in the presence of 7.5% by weight of water, 0.2% by weight of isophthalic acid, 0.1% by weight of benzoic acid, each percentage being based on caprolactam. By adding hindered piperidine amine and/or tertiary amine to the polymeric system, the effects of additives on the polymer were studied. The results showed that: the addition of 0.1 ∼ 0.2% additives can improve the melt stability of polyamide 6; the addition of 0.2% additives can protect mechanical properties of polyamide 6 fibers after exposure to high temperature; and the addition of 0.05 ∼ 0.25% additives can increase the amino end group content of polyamide 6 and thereby increase the dyeability of polyamide fibers. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2489–2493, 2004</description><subject>Applied sciences</subject><subject>dyeability</subject><subject>Exact sciences and technology</subject><subject>Fibers and threads</subject><subject>Forms of application and semi-finished materials</subject><subject>hindered amine</subject><subject>PA 6</subject><subject>Polymer industry, paints, wood</subject><subject>stability</subject><subject>Technology of polymers</subject><subject>tertiary amine</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLAzEUhYMoWKsL_0E2LlxMm8ckM7MsVatQtBSly5DmQaPTmZAMaP-9sVMfGzf3wL3fOVwOAJcYjTBCZCy9HxFMUHUEBhhVRZZzUh6DQbrhrKwqdgrOYnxFCGOG-ADIife1U7JzbQNbCzeu0SYYDb3zJjjtGgPldj8bPW4D7EzonAy7w9Y1sNsYuG21s39ifFvvEqAN5OfgxMo6mouDDsHL3e3z9D6bP80eppN5pihlVUZkLo1lLMeaE0oITbLmel0gZVkaxlC7xogrqhiWjOAC46KsGENSYaMrOgTXfa4KbYzBWOGD26ZPBUbiqxuRuhH7bhJ71bNeRiVrG2SjXPw1cJLT1FDixj337mqz-z9QTBaL7-Ssd7jYmY8fhwxvghe0YGL1OBPzm3K5zB-RWNFPpoqCGg</recordid><startdate>20041215</startdate><enddate>20041215</enddate><creator>Guo, Xitao</creator><creator>Zhao, Yaoming</creator><creator>Ning, Ping</creator><creator>Ai, Xiying</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20041215</creationdate><title>Application of hindered piperidine amine and/or tertiary amine in the modification of polyamide 6</title><author>Guo, Xitao ; Zhao, Yaoming ; Ning, Ping ; Ai, Xiying</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3359-2a4aef5541d623223d62b6db70cf570cee3fb106c3c51a521711789550ac1ed93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>dyeability</topic><topic>Exact sciences and technology</topic><topic>Fibers and threads</topic><topic>Forms of application and semi-finished materials</topic><topic>hindered amine</topic><topic>PA 6</topic><topic>Polymer industry, paints, wood</topic><topic>stability</topic><topic>Technology of polymers</topic><topic>tertiary amine</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guo, Xitao</creatorcontrib><creatorcontrib>Zhao, Yaoming</creatorcontrib><creatorcontrib>Ning, Ping</creatorcontrib><creatorcontrib>Ai, Xiying</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guo, Xitao</au><au>Zhao, Yaoming</au><au>Ning, Ping</au><au>Ai, Xiying</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Application of hindered piperidine amine and/or tertiary amine in the modification of polyamide 6</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2004-12-15</date><risdate>2004</risdate><volume>94</volume><issue>6</issue><spage>2489</spage><epage>2493</epage><pages>2489-2493</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>PA 6 resin was produced in a hydrolytic‐polymeric process in which ε‐caprolactam was polymerized in the presence of water as initiator, isophthalic acid and benzoic acid as chain regulators, by polymerizing caprolactam in the presence of 7.5% by weight of water, 0.2% by weight of isophthalic acid, 0.1% by weight of benzoic acid, each percentage being based on caprolactam. By adding hindered piperidine amine and/or tertiary amine to the polymeric system, the effects of additives on the polymer were studied. The results showed that: the addition of 0.1 ∼ 0.2% additives can improve the melt stability of polyamide 6; the addition of 0.2% additives can protect mechanical properties of polyamide 6 fibers after exposure to high temperature; and the addition of 0.05 ∼ 0.25% additives can increase the amino end group content of polyamide 6 and thereby increase the dyeability of polyamide fibers. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2489–2493, 2004</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.21209</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8995 |
| ispartof | Journal of applied polymer science, 2004-12, Vol.94 (6), p.2489-2493 |
| issn | 0021-8995 1097-4628 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_app_21209 |
| source | Wiley Online Library All Journals |
| subjects | Applied sciences dyeability Exact sciences and technology Fibers and threads Forms of application and semi-finished materials hindered amine PA 6 Polymer industry, paints, wood stability Technology of polymers tertiary amine |
| title | Application of hindered piperidine amine and/or tertiary amine in the modification of polyamide 6 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T01%3A01%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Application%20of%20hindered%20piperidine%20amine%20and/or%20tertiary%20amine%20in%20the%20modification%20of%20polyamide%206&rft.jtitle=Journal%20of%20applied%20polymer%20science&rft.au=Guo,%20Xitao&rft.date=2004-12-15&rft.volume=94&rft.issue=6&rft.spage=2489&rft.epage=2493&rft.pages=2489-2493&rft.issn=0021-8995&rft.eissn=1097-4628&rft.coden=JAPNAB&rft_id=info:doi/10.1002/app.21209&rft_dat=%3Cwiley_cross%3EAPP21209%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |