New liquid polysulfide polymer terminated with silyl group
The terminal SH of liquid polysulfide polymer was capped with a silyl group. This polymer was hydrolyzed immediately by moisture at ambient temperature and returned to the original polymer. The compounds of this new polymer and the various curing agents of the conventional polysulfide polymer became...
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Veröffentlicht in: | Journal of applied polymer science 2004-09, Vol.93 (6), p.2642-2649 |
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creator | Matsui, Tatsuro Nakajima, Masashi Nonaka, Toshiaki Dokoshi, Noriaki |
description | The terminal SH of liquid polysulfide polymer was capped with a silyl group. This polymer was hydrolyzed immediately by moisture at ambient temperature and returned to the original polymer. The compounds of this new polymer and the various curing agents of the conventional polysulfide polymer became moisture curable and of use as one‐component sealants and adhesives. The curing speed of these compounds is very fast compared with that of not only conventional one‐component polysulfide sealants, by more than three times, but also of other one‐component sealants at 20°C under 30% humidity. Their storage stability is good. Their cured products showed physical properties comparable to those of the two‐component polysulfide compounds. In particular, the compound of this polymer and isocyanate prepolymer showed good elasticity and good weatherability. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2642–2649, 2004 |
doi_str_mv | 10.1002/app.20848 |
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This polymer was hydrolyzed immediately by moisture at ambient temperature and returned to the original polymer. The compounds of this new polymer and the various curing agents of the conventional polysulfide polymer became moisture curable and of use as one‐component sealants and adhesives. The curing speed of these compounds is very fast compared with that of not only conventional one‐component polysulfide sealants, by more than three times, but also of other one‐component sealants at 20°C under 30% humidity. Their storage stability is good. Their cured products showed physical properties comparable to those of the two‐component polysulfide compounds. In particular, the compound of this polymer and isocyanate prepolymer showed good elasticity and good weatherability. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2642–2649, 2004</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.20848</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; compounding ; curing of polymers ; Exact sciences and technology ; one-component sealants ; Physicochemistry of polymers ; Polymer industry, paints, wood ; polysulfides ; silyl group ; Technology of polymers</subject><ispartof>Journal of applied polymer science, 2004-09, Vol.93 (6), p.2642-2649</ispartof><rights>Copyright © 2004 Wiley Periodicals, Inc.</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3358-8ab9d83169935f802779c55dc0a2bb53cb4a2b5a6c1e21a46de883810c4e72473</citedby><cites>FETCH-LOGICAL-c3358-8ab9d83169935f802779c55dc0a2bb53cb4a2b5a6c1e21a46de883810c4e72473</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.20848$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.20848$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27923,27924,45573,45574</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16009061$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Matsui, Tatsuro</creatorcontrib><creatorcontrib>Nakajima, Masashi</creatorcontrib><creatorcontrib>Nonaka, Toshiaki</creatorcontrib><creatorcontrib>Dokoshi, Noriaki</creatorcontrib><title>New liquid polysulfide polymer terminated with silyl group</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The terminal SH of liquid polysulfide polymer was capped with a silyl group. This polymer was hydrolyzed immediately by moisture at ambient temperature and returned to the original polymer. The compounds of this new polymer and the various curing agents of the conventional polysulfide polymer became moisture curable and of use as one‐component sealants and adhesives. The curing speed of these compounds is very fast compared with that of not only conventional one‐component polysulfide sealants, by more than three times, but also of other one‐component sealants at 20°C under 30% humidity. Their storage stability is good. Their cured products showed physical properties comparable to those of the two‐component polysulfide compounds. In particular, the compound of this polymer and isocyanate prepolymer showed good elasticity and good weatherability. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2642–2649, 2004</description><subject>Applied sciences</subject><subject>compounding</subject><subject>curing of polymers</subject><subject>Exact sciences and technology</subject><subject>one-component sealants</subject><subject>Physicochemistry of polymers</subject><subject>Polymer industry, paints, wood</subject><subject>polysulfides</subject><subject>silyl group</subject><subject>Technology of polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp1jz1PwzAURS0EEqUw8A-yMDCkfY5jx2arKiigUjoAlVgsx3HA4NJgpyr594SGj4npXemde6SL0DGGAQZIhqqqBgnwlO-gHgaRxSlL-C7qtT8ccyHoPjoI4QUAYwqsh85mZhM5-762RVStXBPWrrSF2eal8VFt_NK-qdoU0cbWz1GwrnHRk1-tq0O0VyoXzNH37aP7i_O78WU8vZ1cjUfTWBNCecxVLgpOMBOC0JJDkmVCU1poUEmeU6LztA1UMY1NglXKCsM54Rh0arIkzUgfnXZe7VcheFPKytul8o3EIL9Gy3a03I5u2ZOOrVTQypVevWkb_goMQADDLTfsuI11pvlfKEfz-Y857ho21Objt6H8q2QZyahczCby5mGcLmbzR3lNPgFpgnTS</recordid><startdate>20040915</startdate><enddate>20040915</enddate><creator>Matsui, Tatsuro</creator><creator>Nakajima, Masashi</creator><creator>Nonaka, Toshiaki</creator><creator>Dokoshi, Noriaki</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20040915</creationdate><title>New liquid polysulfide polymer terminated with silyl group</title><author>Matsui, Tatsuro ; Nakajima, Masashi ; Nonaka, Toshiaki ; Dokoshi, Noriaki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3358-8ab9d83169935f802779c55dc0a2bb53cb4a2b5a6c1e21a46de883810c4e72473</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>compounding</topic><topic>curing of polymers</topic><topic>Exact sciences and technology</topic><topic>one-component sealants</topic><topic>Physicochemistry of polymers</topic><topic>Polymer industry, paints, wood</topic><topic>polysulfides</topic><topic>silyl group</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Matsui, Tatsuro</creatorcontrib><creatorcontrib>Nakajima, Masashi</creatorcontrib><creatorcontrib>Nonaka, Toshiaki</creatorcontrib><creatorcontrib>Dokoshi, Noriaki</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Matsui, Tatsuro</au><au>Nakajima, Masashi</au><au>Nonaka, Toshiaki</au><au>Dokoshi, Noriaki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New liquid polysulfide polymer terminated with silyl group</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2004-09-15</date><risdate>2004</risdate><volume>93</volume><issue>6</issue><spage>2642</spage><epage>2649</epage><pages>2642-2649</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The terminal SH of liquid polysulfide polymer was capped with a silyl group. This polymer was hydrolyzed immediately by moisture at ambient temperature and returned to the original polymer. The compounds of this new polymer and the various curing agents of the conventional polysulfide polymer became moisture curable and of use as one‐component sealants and adhesives. The curing speed of these compounds is very fast compared with that of not only conventional one‐component polysulfide sealants, by more than three times, but also of other one‐component sealants at 20°C under 30% humidity. Their storage stability is good. Their cured products showed physical properties comparable to those of the two‐component polysulfide compounds. In particular, the compound of this polymer and isocyanate prepolymer showed good elasticity and good weatherability. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2642–2649, 2004</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.20848</doi><tpages>8</tpages></addata></record> |
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subjects | Applied sciences compounding curing of polymers Exact sciences and technology one-component sealants Physicochemistry of polymers Polymer industry, paints, wood polysulfides silyl group Technology of polymers |
title | New liquid polysulfide polymer terminated with silyl group |
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