Emulsifier-minor emulsion copolymerization of BA-MMA-St-MAA (or AA)-N-MA
A novel emulsion polymerization technique referred to as emulsifier‐minor emulsion polymerization was achieved by the copolymerization of methyl methacrylate, butyl acrylate, and styrene (MMA‐BA‐St) with a combination of water‐soluble ionic monomers [methacrylic acid (MAA) or acrylic acid (AA)] and...
Gespeichert in:
| Veröffentlicht in: | Journal of applied polymer science 2004-06, Vol.92 (5), p.2923-2929 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2929 |
|---|---|
| container_issue | 5 |
| container_start_page | 2923 |
| container_title | Journal of applied polymer science |
| container_volume | 92 |
| creator | Tang, Linsheng Yang, Jingwei Zhang, Shufeng Yang, Jinzong Wu, Yumin |
| description | A novel emulsion polymerization technique referred to as emulsifier‐minor emulsion polymerization was achieved by the copolymerization of methyl methacrylate, butyl acrylate, and styrene (MMA‐BA‐St) with a combination of water‐soluble ionic monomers [methacrylic acid (MAA) or acrylic acid (AA)] and nonionic monomers (N‐methylol acrylamide). In the technique, water‐soluble monomers play a crucial role in the stabilization of the latex particles as they can be bound to the particle surface and form a hydrate protective layer, which exhibits steric and/or electrostatic effects to prevent particle coagulation. The minor but over its critical micelle concentration emulsifier sodium alkylated diphenyl ether disulfonate (DSB) results in the nucleation of particles mainly by the micelle nucleation mechanism and thus determines the polymerization rate, the particle size, and the number. The film water resistance of the latices can be improved, and the foaming capacity of can be lowered by using technique instead of conventional emulsion polymerization. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2923–2929, 2004 |
| doi_str_mv | 10.1002/app.20247 |
| format | Article |
| fullrecord | <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_app_20247</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>APP20247</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3357-b6ed9f9d3ef8799729b7d178c504b84da80a8507bc8ebf858c1ecd1b2904346e3</originalsourceid><addsrcrecordid>eNp1kD1PwzAYhC0EEqUw8A-yIMHg1k7i2B5NKS1SW4ooYrQcx5YMSRPZRVB-PWnDx8T06r177oYD4ByjAUYoHqqmGcQoTukB6GHEKUyzmB2CXuthyDgnx-AkhBeEMCYo64HpuHorg7POeFi5de0jsxfqdaTrpi63lfHuU212Qm2jawHncwEfN3AuRHTZ4kJcwUX7nYIjq8pgzr5vHzzdjlejKZzdT-5GYgZ1khAK88wU3PIiMZZRzmnMc1pgyjRBac7SQjGkGEE018zklhGmsdEFzmOO0iTNTNIHV12v9nUI3ljZeFcpv5UYyd0Esp1A7ido2YuObVTQqrRerbULfwGSYc5Q1nLDjnt3pdn-XyjFcvnTDLuECxvz8ZtQ_lVmNKFEPi8m8mG0iFeYE3mTfAE_lnc2</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Emulsifier-minor emulsion copolymerization of BA-MMA-St-MAA (or AA)-N-MA</title><source>Access via Wiley Online Library</source><creator>Tang, Linsheng ; Yang, Jingwei ; Zhang, Shufeng ; Yang, Jinzong ; Wu, Yumin</creator><creatorcontrib>Tang, Linsheng ; Yang, Jingwei ; Zhang, Shufeng ; Yang, Jinzong ; Wu, Yumin</creatorcontrib><description>A novel emulsion polymerization technique referred to as emulsifier‐minor emulsion polymerization was achieved by the copolymerization of methyl methacrylate, butyl acrylate, and styrene (MMA‐BA‐St) with a combination of water‐soluble ionic monomers [methacrylic acid (MAA) or acrylic acid (AA)] and nonionic monomers (N‐methylol acrylamide). In the technique, water‐soluble monomers play a crucial role in the stabilization of the latex particles as they can be bound to the particle surface and form a hydrate protective layer, which exhibits steric and/or electrostatic effects to prevent particle coagulation. The minor but over its critical micelle concentration emulsifier sodium alkylated diphenyl ether disulfonate (DSB) results in the nucleation of particles mainly by the micelle nucleation mechanism and thus determines the polymerization rate, the particle size, and the number. The film water resistance of the latices can be improved, and the foaming capacity of can be lowered by using technique instead of conventional emulsion polymerization. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2923–2929, 2004</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.20247</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>(meth)acrylic acid ; Applied sciences ; emulsifier-minor emulsion polymerization ; Exact sciences and technology ; micelle nucleation mechanism ; MMA-BA-St ; N-methylol acrylamide ; Physicochemistry of polymers ; Polymer industry, paints, wood ; Technology of polymers</subject><ispartof>Journal of applied polymer science, 2004-06, Vol.92 (5), p.2923-2929</ispartof><rights>Copyright © 2004 Wiley Periodicals, Inc.</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3357-b6ed9f9d3ef8799729b7d178c504b84da80a8507bc8ebf858c1ecd1b2904346e3</citedby><cites>FETCH-LOGICAL-c3357-b6ed9f9d3ef8799729b7d178c504b84da80a8507bc8ebf858c1ecd1b2904346e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.20247$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.20247$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27929,27930,45579,45580</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15619806$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Tang, Linsheng</creatorcontrib><creatorcontrib>Yang, Jingwei</creatorcontrib><creatorcontrib>Zhang, Shufeng</creatorcontrib><creatorcontrib>Yang, Jinzong</creatorcontrib><creatorcontrib>Wu, Yumin</creatorcontrib><title>Emulsifier-minor emulsion copolymerization of BA-MMA-St-MAA (or AA)-N-MA</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>A novel emulsion polymerization technique referred to as emulsifier‐minor emulsion polymerization was achieved by the copolymerization of methyl methacrylate, butyl acrylate, and styrene (MMA‐BA‐St) with a combination of water‐soluble ionic monomers [methacrylic acid (MAA) or acrylic acid (AA)] and nonionic monomers (N‐methylol acrylamide). In the technique, water‐soluble monomers play a crucial role in the stabilization of the latex particles as they can be bound to the particle surface and form a hydrate protective layer, which exhibits steric and/or electrostatic effects to prevent particle coagulation. The minor but over its critical micelle concentration emulsifier sodium alkylated diphenyl ether disulfonate (DSB) results in the nucleation of particles mainly by the micelle nucleation mechanism and thus determines the polymerization rate, the particle size, and the number. The film water resistance of the latices can be improved, and the foaming capacity of can be lowered by using technique instead of conventional emulsion polymerization. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2923–2929, 2004</description><subject>(meth)acrylic acid</subject><subject>Applied sciences</subject><subject>emulsifier-minor emulsion polymerization</subject><subject>Exact sciences and technology</subject><subject>micelle nucleation mechanism</subject><subject>MMA-BA-St</subject><subject>N-methylol acrylamide</subject><subject>Physicochemistry of polymers</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp1kD1PwzAYhC0EEqUw8A-yIMHg1k7i2B5NKS1SW4ooYrQcx5YMSRPZRVB-PWnDx8T06r177oYD4ByjAUYoHqqmGcQoTukB6GHEKUyzmB2CXuthyDgnx-AkhBeEMCYo64HpuHorg7POeFi5de0jsxfqdaTrpi63lfHuU212Qm2jawHncwEfN3AuRHTZ4kJcwUX7nYIjq8pgzr5vHzzdjlejKZzdT-5GYgZ1khAK88wU3PIiMZZRzmnMc1pgyjRBac7SQjGkGEE018zklhGmsdEFzmOO0iTNTNIHV12v9nUI3ljZeFcpv5UYyd0Esp1A7ido2YuObVTQqrRerbULfwGSYc5Q1nLDjnt3pdn-XyjFcvnTDLuECxvz8ZtQ_lVmNKFEPi8m8mG0iFeYE3mTfAE_lnc2</recordid><startdate>20040605</startdate><enddate>20040605</enddate><creator>Tang, Linsheng</creator><creator>Yang, Jingwei</creator><creator>Zhang, Shufeng</creator><creator>Yang, Jinzong</creator><creator>Wu, Yumin</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20040605</creationdate><title>Emulsifier-minor emulsion copolymerization of BA-MMA-St-MAA (or AA)-N-MA</title><author>Tang, Linsheng ; Yang, Jingwei ; Zhang, Shufeng ; Yang, Jinzong ; Wu, Yumin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3357-b6ed9f9d3ef8799729b7d178c504b84da80a8507bc8ebf858c1ecd1b2904346e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>(meth)acrylic acid</topic><topic>Applied sciences</topic><topic>emulsifier-minor emulsion polymerization</topic><topic>Exact sciences and technology</topic><topic>micelle nucleation mechanism</topic><topic>MMA-BA-St</topic><topic>N-methylol acrylamide</topic><topic>Physicochemistry of polymers</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tang, Linsheng</creatorcontrib><creatorcontrib>Yang, Jingwei</creatorcontrib><creatorcontrib>Zhang, Shufeng</creatorcontrib><creatorcontrib>Yang, Jinzong</creatorcontrib><creatorcontrib>Wu, Yumin</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tang, Linsheng</au><au>Yang, Jingwei</au><au>Zhang, Shufeng</au><au>Yang, Jinzong</au><au>Wu, Yumin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Emulsifier-minor emulsion copolymerization of BA-MMA-St-MAA (or AA)-N-MA</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2004-06-05</date><risdate>2004</risdate><volume>92</volume><issue>5</issue><spage>2923</spage><epage>2929</epage><pages>2923-2929</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>A novel emulsion polymerization technique referred to as emulsifier‐minor emulsion polymerization was achieved by the copolymerization of methyl methacrylate, butyl acrylate, and styrene (MMA‐BA‐St) with a combination of water‐soluble ionic monomers [methacrylic acid (MAA) or acrylic acid (AA)] and nonionic monomers (N‐methylol acrylamide). In the technique, water‐soluble monomers play a crucial role in the stabilization of the latex particles as they can be bound to the particle surface and form a hydrate protective layer, which exhibits steric and/or electrostatic effects to prevent particle coagulation. The minor but over its critical micelle concentration emulsifier sodium alkylated diphenyl ether disulfonate (DSB) results in the nucleation of particles mainly by the micelle nucleation mechanism and thus determines the polymerization rate, the particle size, and the number. The film water resistance of the latices can be improved, and the foaming capacity of can be lowered by using technique instead of conventional emulsion polymerization. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2923–2929, 2004</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.20247</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8995 |
| ispartof | Journal of applied polymer science, 2004-06, Vol.92 (5), p.2923-2929 |
| issn | 0021-8995 1097-4628 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_app_20247 |
| source | Access via Wiley Online Library |
| subjects | (meth)acrylic acid Applied sciences emulsifier-minor emulsion polymerization Exact sciences and technology micelle nucleation mechanism MMA-BA-St N-methylol acrylamide Physicochemistry of polymers Polymer industry, paints, wood Technology of polymers |
| title | Emulsifier-minor emulsion copolymerization of BA-MMA-St-MAA (or AA)-N-MA |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-13T09%3A09%3A48IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Emulsifier-minor%20emulsion%20copolymerization%20of%20BA-MMA-St-MAA%20(or%20AA)-N-MA&rft.jtitle=Journal%20of%20applied%20polymer%20science&rft.au=Tang,%20Linsheng&rft.date=2004-06-05&rft.volume=92&rft.issue=5&rft.spage=2923&rft.epage=2929&rft.pages=2923-2929&rft.issn=0021-8995&rft.eissn=1097-4628&rft.coden=JAPNAB&rft_id=info:doi/10.1002/app.20247&rft_dat=%3Cwiley_cross%3EAPP20247%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |