Bead-spring macromolecules: The kinetic contribution to the total stress

Using complete phase space distributions, this analysis predicts an isotropic kinetic contribution to the total stress for both the solvent and polymer. The solvent's contribution depends on the polymer's intramolecular potential energy, as well as the intermolecular potential between the...

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Veröffentlicht in:Journal of applied polymer science 1992-03, Vol.44 (8), p.1491-1498
1. Verfasser: Grisafi, S.
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description Using complete phase space distributions, this analysis predicts an isotropic kinetic contribution to the total stress for both the solvent and polymer. The solvent's contribution depends on the polymer's intramolecular potential energy, as well as the intermolecular potential between the solvent and polymer. The analysis questions whether single molecule distributions are capable of investigating the possibility of anisotropic kinetic distributions. The analysis uses the peculiar velocity fields in lieu of modeling molecular collisions.
doi_str_mv 10.1002/app.1992.070440820
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subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Solution and gel properties
title Bead-spring macromolecules: The kinetic contribution to the total stress
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