Swelling of PVC particles during gelation and fusion of plastisols as observed with small-angle light scattering

Small‐angle light scattering was employed as a nondestructive technique for the in situ observation of swelling of PVC particles during gelation and fusion. One typical plastisol grade of PVC and three different plasticizers were used. The results demonstrate that quantitative measurements of averag...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of applied polymer science 1990, Vol.41 (5-6), p.889-899
Hauptverfasser: Nakajima, N., Sadeghi, M. R., Kyu, T.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 899
container_issue 5-6
container_start_page 889
container_title Journal of applied polymer science
container_volume 41
creator Nakajima, N.
Sadeghi, M. R.
Kyu, T.
description Small‐angle light scattering was employed as a nondestructive technique for the in situ observation of swelling of PVC particles during gelation and fusion. One typical plastisol grade of PVC and three different plasticizers were used. The results demonstrate that quantitative measurements of average PVC particle size appear possible while they are in the process of swelling with plasticizers. From the degree of swelling the solvent power of plasticizers may be evaluated. The ranking of plasticizers made in this manner was in good agreement with the previous studies involving viscoelastic measurements.
doi_str_mv 10.1002/app.1990.070410501
format Article
fullrecord <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_app_1990_070410501</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>APP070410501</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3661-189bf50234644c350443ebba5543a6d6d6754fc6d8b8626d5fc5082769aca7453</originalsourceid><addsrcrecordid>eNqNkMtKxDAUhoMoOF5ewFU2LjueNJe24EYGbyA63pfhNE3HaGxLUh19e1tG1KVkccLh-_6En5A9BlMGkB5g101ZUcAUMhAMJLA1MmFQZIlQab5OJgPEkrwo5CbZivEZgDEJakK626X13jUL2tZ0_jCjHYbeGW8jrd7CuF9Yj71rG4pNReu3OF4HtvMYexdbHylG2pbRhndb0aXrn2h8Re8TbBbeUu8WTz2NBvvejnk7ZKNGH-3u99wm9yfHd7Oz5OLq9Hx2dJEYrhRLWF6UtYSUCyWE4RKE4LYsUUrBUVXDyaSojaryMlepqmRtJORppgo0mAnJt0m6yjWhjTHYWnfBvWL41Az02JkeOtNjZ_qns0HaX0kdDj_2dcDGuPhrFmLAIBu4wxW3dN5-_iNZH83nf59JVrqLvf340TG8aJXxTOrHy1PNT-bX6iYV-pp_AX7djjU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Swelling of PVC particles during gelation and fusion of plastisols as observed with small-angle light scattering</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Nakajima, N. ; Sadeghi, M. R. ; Kyu, T.</creator><creatorcontrib>Nakajima, N. ; Sadeghi, M. R. ; Kyu, T.</creatorcontrib><description>Small‐angle light scattering was employed as a nondestructive technique for the in situ observation of swelling of PVC particles during gelation and fusion. One typical plastisol grade of PVC and three different plasticizers were used. The results demonstrate that quantitative measurements of average PVC particle size appear possible while they are in the process of swelling with plasticizers. From the degree of swelling the solvent power of plasticizers may be evaluated. The ranking of plasticizers made in this manner was in good agreement with the previous studies involving viscoelastic measurements.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.1990.070410501</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>New York: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Exact sciences and technology ; Forms of application and semi-finished materials ; Latex and emulsion ; Polymer industry, paints, wood ; Technology of polymers</subject><ispartof>Journal of applied polymer science, 1990, Vol.41 (5-6), p.889-899</ispartof><rights>Copyright © 1990 John Wiley &amp; Sons, Inc.</rights><rights>1991 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3661-189bf50234644c350443ebba5543a6d6d6754fc6d8b8626d5fc5082769aca7453</citedby><cites>FETCH-LOGICAL-c3661-189bf50234644c350443ebba5543a6d6d6754fc6d8b8626d5fc5082769aca7453</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.1990.070410501$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.1990.070410501$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,778,782,1414,4012,27910,27911,27912,45561,45562</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=19405007$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Nakajima, N.</creatorcontrib><creatorcontrib>Sadeghi, M. R.</creatorcontrib><creatorcontrib>Kyu, T.</creatorcontrib><title>Swelling of PVC particles during gelation and fusion of plastisols as observed with small-angle light scattering</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Small‐angle light scattering was employed as a nondestructive technique for the in situ observation of swelling of PVC particles during gelation and fusion. One typical plastisol grade of PVC and three different plasticizers were used. The results demonstrate that quantitative measurements of average PVC particle size appear possible while they are in the process of swelling with plasticizers. From the degree of swelling the solvent power of plasticizers may be evaluated. The ranking of plasticizers made in this manner was in good agreement with the previous studies involving viscoelastic measurements.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Latex and emulsion</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNqNkMtKxDAUhoMoOF5ewFU2LjueNJe24EYGbyA63pfhNE3HaGxLUh19e1tG1KVkccLh-_6En5A9BlMGkB5g101ZUcAUMhAMJLA1MmFQZIlQab5OJgPEkrwo5CbZivEZgDEJakK626X13jUL2tZ0_jCjHYbeGW8jrd7CuF9Yj71rG4pNReu3OF4HtvMYexdbHylG2pbRhndb0aXrn2h8Re8TbBbeUu8WTz2NBvvejnk7ZKNGH-3u99wm9yfHd7Oz5OLq9Hx2dJEYrhRLWF6UtYSUCyWE4RKE4LYsUUrBUVXDyaSojaryMlepqmRtJORppgo0mAnJt0m6yjWhjTHYWnfBvWL41Az02JkeOtNjZ_qns0HaX0kdDj_2dcDGuPhrFmLAIBu4wxW3dN5-_iNZH83nf59JVrqLvf340TG8aJXxTOrHy1PNT-bX6iYV-pp_AX7djjU</recordid><startdate>1990</startdate><enddate>1990</enddate><creator>Nakajima, N.</creator><creator>Sadeghi, M. R.</creator><creator>Kyu, T.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>1990</creationdate><title>Swelling of PVC particles during gelation and fusion of plastisols as observed with small-angle light scattering</title><author>Nakajima, N. ; Sadeghi, M. R. ; Kyu, T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3661-189bf50234644c350443ebba5543a6d6d6754fc6d8b8626d5fc5082769aca7453</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Latex and emulsion</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nakajima, N.</creatorcontrib><creatorcontrib>Sadeghi, M. R.</creatorcontrib><creatorcontrib>Kyu, T.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nakajima, N.</au><au>Sadeghi, M. R.</au><au>Kyu, T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Swelling of PVC particles during gelation and fusion of plastisols as observed with small-angle light scattering</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>1990</date><risdate>1990</risdate><volume>41</volume><issue>5-6</issue><spage>889</spage><epage>899</epage><pages>889-899</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Small‐angle light scattering was employed as a nondestructive technique for the in situ observation of swelling of PVC particles during gelation and fusion. One typical plastisol grade of PVC and three different plasticizers were used. The results demonstrate that quantitative measurements of average PVC particle size appear possible while they are in the process of swelling with plasticizers. From the degree of swelling the solvent power of plasticizers may be evaluated. The ranking of plasticizers made in this manner was in good agreement with the previous studies involving viscoelastic measurements.</abstract><cop>New York</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.1990.070410501</doi><tpages>11</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-8995
ispartof Journal of applied polymer science, 1990, Vol.41 (5-6), p.889-899
issn 0021-8995
1097-4628
language eng
recordid cdi_crossref_primary_10_1002_app_1990_070410501
source Wiley Online Library Journals Frontfile Complete
subjects Applied sciences
Exact sciences and technology
Forms of application and semi-finished materials
Latex and emulsion
Polymer industry, paints, wood
Technology of polymers
title Swelling of PVC particles during gelation and fusion of plastisols as observed with small-angle light scattering
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T03%3A06%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Swelling%20of%20PVC%20particles%20during%20gelation%20and%20fusion%20of%20plastisols%20as%20observed%20with%20small-angle%20light%20scattering&rft.jtitle=Journal%20of%20applied%20polymer%20science&rft.au=Nakajima,%20N.&rft.date=1990&rft.volume=41&rft.issue=5-6&rft.spage=889&rft.epage=899&rft.pages=889-899&rft.issn=0021-8995&rft.eissn=1097-4628&rft.coden=JAPNAB&rft_id=info:doi/10.1002/app.1990.070410501&rft_dat=%3Cwiley_cross%3EAPP070410501%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true