Swelling of PVC particles during gelation and fusion of plastisols as observed with small-angle light scattering
Small‐angle light scattering was employed as a nondestructive technique for the in situ observation of swelling of PVC particles during gelation and fusion. One typical plastisol grade of PVC and three different plasticizers were used. The results demonstrate that quantitative measurements of averag...
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Veröffentlicht in: | Journal of applied polymer science 1990, Vol.41 (5-6), p.889-899 |
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creator | Nakajima, N. Sadeghi, M. R. Kyu, T. |
description | Small‐angle light scattering was employed as a nondestructive technique for the in situ observation of swelling of PVC particles during gelation and fusion. One typical plastisol grade of PVC and three different plasticizers were used. The results demonstrate that quantitative measurements of average PVC particle size appear possible while they are in the process of swelling with plasticizers. From the degree of swelling the solvent power of plasticizers may be evaluated. The ranking of plasticizers made in this manner was in good agreement with the previous studies involving viscoelastic measurements. |
doi_str_mv | 10.1002/app.1990.070410501 |
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R. ; Kyu, T.</creator><creatorcontrib>Nakajima, N. ; Sadeghi, M. R. ; Kyu, T.</creatorcontrib><description>Small‐angle light scattering was employed as a nondestructive technique for the in situ observation of swelling of PVC particles during gelation and fusion. One typical plastisol grade of PVC and three different plasticizers were used. The results demonstrate that quantitative measurements of average PVC particle size appear possible while they are in the process of swelling with plasticizers. From the degree of swelling the solvent power of plasticizers may be evaluated. The ranking of plasticizers made in this manner was in good agreement with the previous studies involving viscoelastic measurements.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.1990.070410501</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>New York: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Exact sciences and technology ; Forms of application and semi-finished materials ; Latex and emulsion ; Polymer industry, paints, wood ; Technology of polymers</subject><ispartof>Journal of applied polymer science, 1990, Vol.41 (5-6), p.889-899</ispartof><rights>Copyright © 1990 John Wiley & Sons, Inc.</rights><rights>1991 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3661-189bf50234644c350443ebba5543a6d6d6754fc6d8b8626d5fc5082769aca7453</citedby><cites>FETCH-LOGICAL-c3661-189bf50234644c350443ebba5543a6d6d6754fc6d8b8626d5fc5082769aca7453</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.1990.070410501$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.1990.070410501$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,778,782,1414,4012,27910,27911,27912,45561,45562</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=19405007$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Nakajima, N.</creatorcontrib><creatorcontrib>Sadeghi, M. R.</creatorcontrib><creatorcontrib>Kyu, T.</creatorcontrib><title>Swelling of PVC particles during gelation and fusion of plastisols as observed with small-angle light scattering</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Small‐angle light scattering was employed as a nondestructive technique for the in situ observation of swelling of PVC particles during gelation and fusion. One typical plastisol grade of PVC and three different plasticizers were used. The results demonstrate that quantitative measurements of average PVC particle size appear possible while they are in the process of swelling with plasticizers. From the degree of swelling the solvent power of plasticizers may be evaluated. The ranking of plasticizers made in this manner was in good agreement with the previous studies involving viscoelastic measurements.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Latex and emulsion</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNqNkMtKxDAUhoMoOF5ewFU2LjueNJe24EYGbyA63pfhNE3HaGxLUh19e1tG1KVkccLh-_6En5A9BlMGkB5g101ZUcAUMhAMJLA1MmFQZIlQab5OJgPEkrwo5CbZivEZgDEJakK626X13jUL2tZ0_jCjHYbeGW8jrd7CuF9Yj71rG4pNReu3OF4HtvMYexdbHylG2pbRhndb0aXrn2h8Re8TbBbeUu8WTz2NBvvejnk7ZKNGH-3u99wm9yfHd7Oz5OLq9Hx2dJEYrhRLWF6UtYSUCyWE4RKE4LYsUUrBUVXDyaSojaryMlepqmRtJORppgo0mAnJt0m6yjWhjTHYWnfBvWL41Az02JkeOtNjZ_qns0HaX0kdDj_2dcDGuPhrFmLAIBu4wxW3dN5-_iNZH83nf59JVrqLvf340TG8aJXxTOrHy1PNT-bX6iYV-pp_AX7djjU</recordid><startdate>1990</startdate><enddate>1990</enddate><creator>Nakajima, N.</creator><creator>Sadeghi, M. 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R. ; Kyu, T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3661-189bf50234644c350443ebba5543a6d6d6754fc6d8b8626d5fc5082769aca7453</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Latex and emulsion</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nakajima, N.</creatorcontrib><creatorcontrib>Sadeghi, M. R.</creatorcontrib><creatorcontrib>Kyu, T.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nakajima, N.</au><au>Sadeghi, M. R.</au><au>Kyu, T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Swelling of PVC particles during gelation and fusion of plastisols as observed with small-angle light scattering</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>1990</date><risdate>1990</risdate><volume>41</volume><issue>5-6</issue><spage>889</spage><epage>899</epage><pages>889-899</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Small‐angle light scattering was employed as a nondestructive technique for the in situ observation of swelling of PVC particles during gelation and fusion. One typical plastisol grade of PVC and three different plasticizers were used. The results demonstrate that quantitative measurements of average PVC particle size appear possible while they are in the process of swelling with plasticizers. From the degree of swelling the solvent power of plasticizers may be evaluated. The ranking of plasticizers made in this manner was in good agreement with the previous studies involving viscoelastic measurements.</abstract><cop>New York</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.1990.070410501</doi><tpages>11</tpages></addata></record> |
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source | Wiley Online Library Journals Frontfile Complete |
subjects | Applied sciences Exact sciences and technology Forms of application and semi-finished materials Latex and emulsion Polymer industry, paints, wood Technology of polymers |
title | Swelling of PVC particles during gelation and fusion of plastisols as observed with small-angle light scattering |
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