Rubber-modified epoxies: interfacial tension and morphology

The interfacial tension between carbomethoxy‐terminated butadiene–acrylonitrile copolymers and an epoxy resin as a function of temperature and copolymer composition is investigated. Using a digital image processing technique, the shape of a pendant drop of the epoxy in the copolymer is determined. A...

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Veröffentlicht in:Journal of applied polymer science 1989-05, Vol.37 (9), p.2627-2636
Hauptverfasser: Sohn, J.E, Emerson, J.A, Thompson, P.A, Koberstein, J.T
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container_end_page 2636
container_issue 9
container_start_page 2627
container_title Journal of applied polymer science
container_volume 37
creator Sohn, J.E
Emerson, J.A
Thompson, P.A
Koberstein, J.T
description The interfacial tension between carbomethoxy‐terminated butadiene–acrylonitrile copolymers and an epoxy resin as a function of temperature and copolymer composition is investigated. Using a digital image processing technique, the shape of a pendant drop of the epoxy in the copolymer is determined. Analysis of the drop shape is performed by profile discrimination and subsequent robust shape analysis. The data are used to examine the relationship between interfacial tension and particle size of the dispersed copolymer‐rich phase in rubber‐modified epoxy resins, that are immiscible in the uncured state.
doi_str_mv 10.1002/app.1989.070370914
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subjects Applied sciences
Blends
Exact sciences and technology
Forms of application and semi-finished materials
gelation
particle size
Polymer industry, paints, wood
polymers
rubber
Technology of polymers
title Rubber-modified epoxies: interfacial tension and morphology
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