Rubber-modified epoxies: interfacial tension and morphology
The interfacial tension between carbomethoxy‐terminated butadiene–acrylonitrile copolymers and an epoxy resin as a function of temperature and copolymer composition is investigated. Using a digital image processing technique, the shape of a pendant drop of the epoxy in the copolymer is determined. A...
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Veröffentlicht in: | Journal of applied polymer science 1989-05, Vol.37 (9), p.2627-2636 |
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container_title | Journal of applied polymer science |
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creator | Sohn, J.E Emerson, J.A Thompson, P.A Koberstein, J.T |
description | The interfacial tension between carbomethoxy‐terminated butadiene–acrylonitrile copolymers and an epoxy resin as a function of temperature and copolymer composition is investigated. Using a digital image processing technique, the shape of a pendant drop of the epoxy in the copolymer is determined. Analysis of the drop shape is performed by profile discrimination and subsequent robust shape analysis. The data are used to examine the relationship between interfacial tension and particle size of the dispersed copolymer‐rich phase in rubber‐modified epoxy resins, that are immiscible in the uncured state. |
doi_str_mv | 10.1002/app.1989.070370914 |
format | Article |
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Using a digital image processing technique, the shape of a pendant drop of the epoxy in the copolymer is determined. Analysis of the drop shape is performed by profile discrimination and subsequent robust shape analysis. The data are used to examine the relationship between interfacial tension and particle size of the dispersed copolymer‐rich phase in rubber‐modified epoxy resins, that are immiscible in the uncured state.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.1989.070370914</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>New York: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Blends ; Exact sciences and technology ; Forms of application and semi-finished materials ; gelation ; particle size ; Polymer industry, paints, wood ; polymers ; rubber ; Technology of polymers</subject><ispartof>Journal of applied polymer science, 1989-05, Vol.37 (9), p.2627-2636</ispartof><rights>Copyright © 1989 John Wiley & Sons, Inc.</rights><rights>1989 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3894-83e43b1221e3f82aaf08233ca8b68825bb3ca9066c652258e7c3bf2d3de4e29a3</citedby><cites>FETCH-LOGICAL-c3894-83e43b1221e3f82aaf08233ca8b68825bb3ca9066c652258e7c3bf2d3de4e29a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.1989.070370914$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.1989.070370914$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27929,27930,45579,45580</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7312122$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Sohn, J.E</creatorcontrib><creatorcontrib>Emerson, J.A</creatorcontrib><creatorcontrib>Thompson, P.A</creatorcontrib><creatorcontrib>Koberstein, J.T</creatorcontrib><title>Rubber-modified epoxies: interfacial tension and morphology</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The interfacial tension between carbomethoxy‐terminated butadiene–acrylonitrile copolymers and an epoxy resin as a function of temperature and copolymer composition is investigated. Using a digital image processing technique, the shape of a pendant drop of the epoxy in the copolymer is determined. Analysis of the drop shape is performed by profile discrimination and subsequent robust shape analysis. The data are used to examine the relationship between interfacial tension and particle size of the dispersed copolymer‐rich phase in rubber‐modified epoxy resins, that are immiscible in the uncured state.</description><subject>Applied sciences</subject><subject>Blends</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>gelation</subject><subject>particle size</subject><subject>Polymer industry, paints, wood</subject><subject>polymers</subject><subject>rubber</subject><subject>Technology of polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNqNj7tOwzAUQC0EEqXwAyxkYE3xI3FsYEG8UQWltDBajmMXQxpHdhHt3-MqqGJk8h3Oub4HgEMEBwhCfCLbdoA44wNYQFJAjrIt0EOQF2lGMdsGvQihlHGe74K9ED4gRCiHtAfOxl9lqX06d5U1VleJbt3S6nCa2GahvZHKyjpZ6CZY1ySyqZK58-27q91stQ92jKyDPvh9-2B6cz25vEuHT7f3lxfDVBHGs5QRnZESYYw0MQxLaSDDhCjJSsoYzssyzhxSqmiOcc50oUhpcEUqnWnMJekD3O1V3oXgtRGtt3PpVwJBsc4XMV-s88UmP0rHndTKoGRtvGyUDRuzIAjHkyJ23mHfttarfywWF6PR31_STrdhoZcbXfpPQQtS5OLt8Vbw8eTq9eEZiTV_1PFGOiFnPl40fcEQEYhpgWI--QFJsYSi</recordid><startdate>19890505</startdate><enddate>19890505</enddate><creator>Sohn, J.E</creator><creator>Emerson, J.A</creator><creator>Thompson, P.A</creator><creator>Koberstein, J.T</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19890505</creationdate><title>Rubber-modified epoxies: interfacial tension and morphology</title><author>Sohn, J.E ; Emerson, J.A ; Thompson, P.A ; Koberstein, J.T</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3894-83e43b1221e3f82aaf08233ca8b68825bb3ca9066c652258e7c3bf2d3de4e29a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>Applied sciences</topic><topic>Blends</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>gelation</topic><topic>particle size</topic><topic>Polymer industry, paints, wood</topic><topic>polymers</topic><topic>rubber</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sohn, J.E</creatorcontrib><creatorcontrib>Emerson, J.A</creatorcontrib><creatorcontrib>Thompson, P.A</creatorcontrib><creatorcontrib>Koberstein, J.T</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sohn, J.E</au><au>Emerson, J.A</au><au>Thompson, P.A</au><au>Koberstein, J.T</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rubber-modified epoxies: interfacial tension and morphology</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>1989-05-05</date><risdate>1989</risdate><volume>37</volume><issue>9</issue><spage>2627</spage><epage>2636</epage><pages>2627-2636</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The interfacial tension between carbomethoxy‐terminated butadiene–acrylonitrile copolymers and an epoxy resin as a function of temperature and copolymer composition is investigated. Using a digital image processing technique, the shape of a pendant drop of the epoxy in the copolymer is determined. Analysis of the drop shape is performed by profile discrimination and subsequent robust shape analysis. The data are used to examine the relationship between interfacial tension and particle size of the dispersed copolymer‐rich phase in rubber‐modified epoxy resins, that are immiscible in the uncured state.</abstract><cop>New York</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.1989.070370914</doi><tpages>10</tpages></addata></record> |
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subjects | Applied sciences Blends Exact sciences and technology Forms of application and semi-finished materials gelation particle size Polymer industry, paints, wood polymers rubber Technology of polymers |
title | Rubber-modified epoxies: interfacial tension and morphology |
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