Polymerization of olefins through heterogeneous catalysis. V. Gas-liquid mass transfer limitations in liquid slurry reactors
Many processes for polymerization of olefins employ laboratory, pilot plant, or full‐scale liquid‐phase polymerization reactors with monomer introduced as a gas. Criteria for the presence of gas‐liquid mass transfer resistance in these systems are determined in terms of observed reaction rate or loa...
Gespeichert in:
| Veröffentlicht in: | Journal of applied polymer science 1986-11, Vol.32 (6), p.5451-5479 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 5479 |
|---|---|
| container_issue | 6 |
| container_start_page | 5451 |
| container_title | Journal of applied polymer science |
| container_volume | 32 |
| creator | Floyd, S. Hutchinson, R. A. Ray, W. H. |
| description | Many processes for polymerization of olefins employ laboratory, pilot plant, or full‐scale liquid‐phase polymerization reactors with monomer introduced as a gas. Criteria for the presence of gas‐liquid mass transfer resistance in these systems are determined in terms of observed reaction rate or loading of a heterogeneous catalyst of given intrinsic activity. The effects of variables such as reactor size and configuration, temperature, and soluble polymer are also examined. The equilibrium monomer concentrations of ethylene in hexane and propylene in heptane are calculated through a modified Benedict‐Webb‐Rubin equation, and some calculations for ethylene‐propylene mixtures are tabulated. The general methodology for predicting gas‐liquid mass transfer resistance is readily extendible to copolymerization systems. |
| doi_str_mv | 10.1002/app.1986.070320617 |
| format | Article |
| fullrecord | <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_app_1986_070320617</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_WNG_RLBTHS7R_K</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3037-ee95db41e84ec8dc9d13e669eeb19255ecdad13a7588c1e7efe11bcef9b892923</originalsourceid><addsrcrecordid>eNqNkMuOEzEQRS0EEmHgB1ggL9h2Y_fLtsRmGEEGEUE0D1hajrucGJx2cHUEjfh4PPQoYsmqJOucW-VLyHPOSs5Y9cocDiVXsiuZYHXFOi4ekAVnShRNV8mHZJEhXkil2sfkCeJXxjhvWbcgv9cxTHtI_pcZfRxodDQGcH5AOu5SPG53dAcjpLiFAeIRqTWjCRN6LOnnki4NFsF_P_qe7g1mJ5kBHSQa_N6PfyOR-oHeMxiOKU00gbFjTPiUPHImIDy7n2fk9t3bm4vLYvVp-f7ifFXYmtWiAFBtv2k4yAas7K3qeQ1dpwA2XFVtC7Y3-cmIVkrLQYADzjcWnNpIVamqPiPVnGtTREzg9CH5vUmT5kzf9adzf_quP33qL0svZ-lg0Jrg8s-sx5MpmWxEU2fs9Yz98AGm_wjW5-v1v1uKWfc4ws-TbtI33YlatPrLx6W-Wr25ubwWV_pD5l_MvDNRm23KF91e5wWCsU61rKr_AKiunuQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Polymerization of olefins through heterogeneous catalysis. V. Gas-liquid mass transfer limitations in liquid slurry reactors</title><source>Access via Wiley Online Library</source><creator>Floyd, S. ; Hutchinson, R. A. ; Ray, W. H.</creator><creatorcontrib>Floyd, S. ; Hutchinson, R. A. ; Ray, W. H.</creatorcontrib><description>Many processes for polymerization of olefins employ laboratory, pilot plant, or full‐scale liquid‐phase polymerization reactors with monomer introduced as a gas. Criteria for the presence of gas‐liquid mass transfer resistance in these systems are determined in terms of observed reaction rate or loading of a heterogeneous catalyst of given intrinsic activity. The effects of variables such as reactor size and configuration, temperature, and soluble polymer are also examined. The equilibrium monomer concentrations of ethylene in hexane and propylene in heptane are calculated through a modified Benedict‐Webb‐Rubin equation, and some calculations for ethylene‐propylene mixtures are tabulated. The general methodology for predicting gas‐liquid mass transfer resistance is readily extendible to copolymerization systems.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.1986.070320617</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>New York: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>actividad catalitica ; activite catalytique ; Applied sciences ; catalytic activity ; Exact sciences and technology ; liquid manures ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; procesamiento ; processing ; purin ; traitement</subject><ispartof>Journal of applied polymer science, 1986-11, Vol.32 (6), p.5451-5479</ispartof><rights>Copyright © 1986 John Wiley & Sons, Inc.</rights><rights>1987 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3037-ee95db41e84ec8dc9d13e669eeb19255ecdad13a7588c1e7efe11bcef9b892923</citedby><cites>FETCH-LOGICAL-c3037-ee95db41e84ec8dc9d13e669eeb19255ecdad13a7588c1e7efe11bcef9b892923</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.1986.070320617$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.1986.070320617$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=8084743$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Floyd, S.</creatorcontrib><creatorcontrib>Hutchinson, R. A.</creatorcontrib><creatorcontrib>Ray, W. H.</creatorcontrib><title>Polymerization of olefins through heterogeneous catalysis. V. Gas-liquid mass transfer limitations in liquid slurry reactors</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Many processes for polymerization of olefins employ laboratory, pilot plant, or full‐scale liquid‐phase polymerization reactors with monomer introduced as a gas. Criteria for the presence of gas‐liquid mass transfer resistance in these systems are determined in terms of observed reaction rate or loading of a heterogeneous catalyst of given intrinsic activity. The effects of variables such as reactor size and configuration, temperature, and soluble polymer are also examined. The equilibrium monomer concentrations of ethylene in hexane and propylene in heptane are calculated through a modified Benedict‐Webb‐Rubin equation, and some calculations for ethylene‐propylene mixtures are tabulated. The general methodology for predicting gas‐liquid mass transfer resistance is readily extendible to copolymerization systems.</description><subject>actividad catalitica</subject><subject>activite catalytique</subject><subject>Applied sciences</subject><subject>catalytic activity</subject><subject>Exact sciences and technology</subject><subject>liquid manures</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>procesamiento</subject><subject>processing</subject><subject>purin</subject><subject>traitement</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1986</creationdate><recordtype>article</recordtype><recordid>eNqNkMuOEzEQRS0EEmHgB1ggL9h2Y_fLtsRmGEEGEUE0D1hajrucGJx2cHUEjfh4PPQoYsmqJOucW-VLyHPOSs5Y9cocDiVXsiuZYHXFOi4ekAVnShRNV8mHZJEhXkil2sfkCeJXxjhvWbcgv9cxTHtI_pcZfRxodDQGcH5AOu5SPG53dAcjpLiFAeIRqTWjCRN6LOnnki4NFsF_P_qe7g1mJ5kBHSQa_N6PfyOR-oHeMxiOKU00gbFjTPiUPHImIDy7n2fk9t3bm4vLYvVp-f7ifFXYmtWiAFBtv2k4yAas7K3qeQ1dpwA2XFVtC7Y3-cmIVkrLQYADzjcWnNpIVamqPiPVnGtTREzg9CH5vUmT5kzf9adzf_quP33qL0svZ-lg0Jrg8s-sx5MpmWxEU2fs9Yz98AGm_wjW5-v1v1uKWfc4ws-TbtI33YlatPrLx6W-Wr25ubwWV_pD5l_MvDNRm23KF91e5wWCsU61rKr_AKiunuQ</recordid><startdate>19861105</startdate><enddate>19861105</enddate><creator>Floyd, S.</creator><creator>Hutchinson, R. A.</creator><creator>Ray, W. H.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19861105</creationdate><title>Polymerization of olefins through heterogeneous catalysis. V. Gas-liquid mass transfer limitations in liquid slurry reactors</title><author>Floyd, S. ; Hutchinson, R. A. ; Ray, W. H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3037-ee95db41e84ec8dc9d13e669eeb19255ecdad13a7588c1e7efe11bcef9b892923</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1986</creationdate><topic>actividad catalitica</topic><topic>activite catalytique</topic><topic>Applied sciences</topic><topic>catalytic activity</topic><topic>Exact sciences and technology</topic><topic>liquid manures</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>procesamiento</topic><topic>processing</topic><topic>purin</topic><topic>traitement</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Floyd, S.</creatorcontrib><creatorcontrib>Hutchinson, R. A.</creatorcontrib><creatorcontrib>Ray, W. H.</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Floyd, S.</au><au>Hutchinson, R. A.</au><au>Ray, W. H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymerization of olefins through heterogeneous catalysis. V. Gas-liquid mass transfer limitations in liquid slurry reactors</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>1986-11-05</date><risdate>1986</risdate><volume>32</volume><issue>6</issue><spage>5451</spage><epage>5479</epage><pages>5451-5479</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Many processes for polymerization of olefins employ laboratory, pilot plant, or full‐scale liquid‐phase polymerization reactors with monomer introduced as a gas. Criteria for the presence of gas‐liquid mass transfer resistance in these systems are determined in terms of observed reaction rate or loading of a heterogeneous catalyst of given intrinsic activity. The effects of variables such as reactor size and configuration, temperature, and soluble polymer are also examined. The equilibrium monomer concentrations of ethylene in hexane and propylene in heptane are calculated through a modified Benedict‐Webb‐Rubin equation, and some calculations for ethylene‐propylene mixtures are tabulated. The general methodology for predicting gas‐liquid mass transfer resistance is readily extendible to copolymerization systems.</abstract><cop>New York</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.1986.070320617</doi><tpages>29</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8995 |
| ispartof | Journal of applied polymer science, 1986-11, Vol.32 (6), p.5451-5479 |
| issn | 0021-8995 1097-4628 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_app_1986_070320617 |
| source | Access via Wiley Online Library |
| subjects | actividad catalitica activite catalytique Applied sciences catalytic activity Exact sciences and technology liquid manures Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts procesamiento processing purin traitement |
| title | Polymerization of olefins through heterogeneous catalysis. V. Gas-liquid mass transfer limitations in liquid slurry reactors |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-22T03%3A41%3A17IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Polymerization%20of%20olefins%20through%20heterogeneous%20catalysis.%20V.%20Gas-liquid%20mass%20transfer%20limitations%20in%20liquid%20slurry%20reactors&rft.jtitle=Journal%20of%20applied%20polymer%20science&rft.au=Floyd,%20S.&rft.date=1986-11-05&rft.volume=32&rft.issue=6&rft.spage=5451&rft.epage=5479&rft.pages=5451-5479&rft.issn=0021-8995&rft.eissn=1097-4628&rft.coden=JAPNAB&rft_id=info:doi/10.1002/app.1986.070320617&rft_dat=%3Cistex_cross%3Eark_67375_WNG_RLBTHS7R_K%3C/istex_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |