Poly-1-hexene, synthesis and solubility in dense carbon dioxide
Several poly‐1‐hexene samples were prepared using different Ziegler‐Natta catalysts, and their solubilities in dense carbon dioxide (CO2) were studied. Despite the varied molecular weight distributions (MWD) in the polymers, a surprising correlation was found between intrinsic viscosity and dense CO...
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| Veröffentlicht in: | Journal of applied polymer science 1986-08, Vol.32 (2), p.3775-3781 |
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| container_end_page | 3781 |
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| container_issue | 2 |
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| container_title | Journal of applied polymer science |
| container_volume | 32 |
| creator | Dandge, D. K. Heller, J. P. Wilson, K. V. |
| description | Several poly‐1‐hexene samples were prepared using different Ziegler‐Natta catalysts, and their solubilities in dense carbon dioxide (CO2) were studied. Despite the varied molecular weight distributions (MWD) in the polymers, a surprising correlation was found between intrinsic viscosity and dense CO2 solubility. Due to the ability of dense CO2 to extract low‐molecular weight fractions preferentially, it is recommended that narrow MWD polymers be used, as far as possible, for dense CO2 solubility determinations. |
| doi_str_mv | 10.1002/app.1986.070320232 |
| format | Article |
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K. ; Heller, J. P. ; Wilson, K. V.</creator><creatorcontrib>Dandge, D. K. ; Heller, J. P. ; Wilson, K. V.</creatorcontrib><description>Several poly‐1‐hexene samples were prepared using different Ziegler‐Natta catalysts, and their solubilities in dense carbon dioxide (CO2) were studied. Despite the varied molecular weight distributions (MWD) in the polymers, a surprising correlation was found between intrinsic viscosity and dense CO2 solubility. Due to the ability of dense CO2 to extract low‐molecular weight fractions preferentially, it is recommended that narrow MWD polymers be used, as far as possible, for dense CO2 solubility determinations.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.1986.070320232</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>New York: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Journal of applied polymer science, 1986-08, Vol.32 (2), p.3775-3781</ispartof><rights>Copyright © 1986 John Wiley & Sons, Inc.</rights><rights>1987 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c3162-291dbdeab0923d7656ca77344aca7e4e50e60fb6326152f7885d3552e64aa6563</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.1986.070320232$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.1986.070320232$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7908394$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Dandge, D. K.</creatorcontrib><creatorcontrib>Heller, J. P.</creatorcontrib><creatorcontrib>Wilson, K. V.</creatorcontrib><title>Poly-1-hexene, synthesis and solubility in dense carbon dioxide</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Several poly‐1‐hexene samples were prepared using different Ziegler‐Natta catalysts, and their solubilities in dense carbon dioxide (CO2) were studied. Despite the varied molecular weight distributions (MWD) in the polymers, a surprising correlation was found between intrinsic viscosity and dense CO2 solubility. Due to the ability of dense CO2 to extract low‐molecular weight fractions preferentially, it is recommended that narrow MWD polymers be used, as far as possible, for dense CO2 solubility determinations.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1986</creationdate><recordtype>article</recordtype><recordid>eNqNkF1LwzAUhoMoOKd_wKteeGnmSdIkDQgy_NjEqUMUwZuQtqcsWtvSTFz_vR2T4aVXLwee5z3wEnLMYMQA-JlrmhEziRqBBsGBC75DBgyMprHiyS4Z9BCjiTFynxyE8A7AmAQ1IBfzuuwoowtcYYWnUeiq5QKDD5Gr8ijU5VfqS7_sIl9FOVYBo8y1ad0fvl75HA_JXuHKgEe_OSQvN9fPl1M6e5zcXo5nNBNMccoNy9McXQqGi1wrqTKntYhj1yfGKAEVFKkSXDHJC50kMhdSclSxcz0thoRverO2DqHFwjat_3RtZxnY9QS2n8CuJ7DbCXrpZCM1LmSuLFpXZT5sTW0gESbusfMN9u1L7P5RbMfz-d8vdKP7sMTVVnfth1VaaGlfHyb2PpZ3b9OrqX0SPzppe-E</recordid><startdate>19860805</startdate><enddate>19860805</enddate><creator>Dandge, D. 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V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3162-291dbdeab0923d7656ca77344aca7e4e50e60fb6326152f7885d3552e64aa6563</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1986</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dandge, D. K.</creatorcontrib><creatorcontrib>Heller, J. P.</creatorcontrib><creatorcontrib>Wilson, K. V.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dandge, D. K.</au><au>Heller, J. P.</au><au>Wilson, K. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Poly-1-hexene, synthesis and solubility in dense carbon dioxide</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>1986-08-05</date><risdate>1986</risdate><volume>32</volume><issue>2</issue><spage>3775</spage><epage>3781</epage><pages>3775-3781</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Several poly‐1‐hexene samples were prepared using different Ziegler‐Natta catalysts, and their solubilities in dense carbon dioxide (CO2) were studied. Despite the varied molecular weight distributions (MWD) in the polymers, a surprising correlation was found between intrinsic viscosity and dense CO2 solubility. Due to the ability of dense CO2 to extract low‐molecular weight fractions preferentially, it is recommended that narrow MWD polymers be used, as far as possible, for dense CO2 solubility determinations.</abstract><cop>New York</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.1986.070320232</doi><tpages>7</tpages></addata></record> |
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| source | Access via Wiley Online Library |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Poly-1-hexene, synthesis and solubility in dense carbon dioxide |
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