Uniaxial orientation of linear low density polyethylene
Only a few reported studies have involved the uniaxial orientation of LDPE and even less on LLDPE. It is our purpose to report on characteristics of uniaxially oriented films of LLDPE that contribute to property development. The LLDPE has been coextruded at 25 and at 80°C layered as ribbons within l...
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Veröffentlicht in: | Journal of applied polymer science 1985-11, Vol.30 (11), p.4251-4259 |
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container_title | Journal of applied polymer science |
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creator | Pezzutti, Jose L. Porter, Roger S. |
description | Only a few reported studies have involved the uniaxial orientation of LDPE and even less on LLDPE. It is our purpose to report on characteristics of uniaxially oriented films of LLDPE that contribute to property development. The LLDPE has been coextruded at 25 and at 80°C layered as ribbons within longitudinally split billets of HDPE. The LLDPE so drawn was characterized by thermal analysis, birefringence, elastic recovery, and wide angle X‐ray measurements. As a result, we can conclude that the drawing of LLDPE at the lower temperature produces a relatively high content of monoclinic crystals; the orientation behavior of LLDPE is similar to that of HDPE. The molecular network formed by entanglements and crystals reduces the draw to a maximum below 15. |
doi_str_mv | 10.1002/app.1985.070301104 |
format | Article |
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It is our purpose to report on characteristics of uniaxially oriented films of LLDPE that contribute to property development. The LLDPE has been coextruded at 25 and at 80°C layered as ribbons within longitudinally split billets of HDPE. The LLDPE so drawn was characterized by thermal analysis, birefringence, elastic recovery, and wide angle X‐ray measurements. As a result, we can conclude that the drawing of LLDPE at the lower temperature produces a relatively high content of monoclinic crystals; the orientation behavior of LLDPE is similar to that of HDPE. The molecular network formed by entanglements and crystals reduces the draw to a maximum below 15.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.1985.070301104</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>New York: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization ; Structure, morphology and analysis</subject><ispartof>Journal of applied polymer science, 1985-11, Vol.30 (11), p.4251-4259</ispartof><rights>Copyright © 1985 John Wiley & Sons, Inc.</rights><rights>1986 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3654-46522b8f22e8fd7d05fda530eac6d09ade44de881197c43e160600651e258d0e3</citedby><cites>FETCH-LOGICAL-c3654-46522b8f22e8fd7d05fda530eac6d09ade44de881197c43e160600651e258d0e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.1985.070301104$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.1985.070301104$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=8525666$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Pezzutti, Jose L.</creatorcontrib><creatorcontrib>Porter, Roger S.</creatorcontrib><title>Uniaxial orientation of linear low density polyethylene</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Only a few reported studies have involved the uniaxial orientation of LDPE and even less on LLDPE. It is our purpose to report on characteristics of uniaxially oriented films of LLDPE that contribute to property development. The LLDPE has been coextruded at 25 and at 80°C layered as ribbons within longitudinally split billets of HDPE. The LLDPE so drawn was characterized by thermal analysis, birefringence, elastic recovery, and wide angle X‐ray measurements. As a result, we can conclude that the drawing of LLDPE at the lower temperature produces a relatively high content of monoclinic crystals; the orientation behavior of LLDPE is similar to that of HDPE. The molecular network formed by entanglements and crystals reduces the draw to a maximum below 15.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Structure, morphology and analysis</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1985</creationdate><recordtype>article</recordtype><recordid>eNqNj81Kw0AURgdRsFZfwFUWblPvTOYv4KYUrUKtXbS4HMbMDY6OScgEat7elEhx6epuzvkuh5BrCjMKwG5t08xorsUMFGRAKfATMqGQq5RLpk_JZIBoqvNcnJOLGD9gYATICVG7yttvb0NStx6rzna-rpK6TIKv0LZJqPeJwyr6rk-aOvTYvfcBK7wkZ6UNEa9-75TsHu63i8d09bJ8WsxXaZFJwYfvgrE3XTKGunTKgSidFRmgLaSD3Drk3KHWlOaq4BlSCRJACopMaAeYTQkbd4u2jrHF0jSt_7JtbyiYQ7oZ0s0h3RzTB-lmlBobCxvK1laFj0dTCyaklAN2N2J7H7D_x7CZbzZ_v6Sj7mOH30fdtp9GqkwJ87peGk7pkm-flVlnP_NyebE</recordid><startdate>198511</startdate><enddate>198511</enddate><creator>Pezzutti, Jose L.</creator><creator>Porter, Roger S.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>198511</creationdate><title>Uniaxial orientation of linear low density polyethylene</title><author>Pezzutti, Jose L. ; Porter, Roger S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3654-46522b8f22e8fd7d05fda530eac6d09ade44de881197c43e160600651e258d0e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1985</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>Structure, morphology and analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pezzutti, Jose L.</creatorcontrib><creatorcontrib>Porter, Roger S.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pezzutti, Jose L.</au><au>Porter, Roger S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Uniaxial orientation of linear low density polyethylene</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>1985-11</date><risdate>1985</risdate><volume>30</volume><issue>11</issue><spage>4251</spage><epage>4259</epage><pages>4251-4259</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Only a few reported studies have involved the uniaxial orientation of LDPE and even less on LLDPE. It is our purpose to report on characteristics of uniaxially oriented films of LLDPE that contribute to property development. The LLDPE has been coextruded at 25 and at 80°C layered as ribbons within longitudinally split billets of HDPE. The LLDPE so drawn was characterized by thermal analysis, birefringence, elastic recovery, and wide angle X‐ray measurements. As a result, we can conclude that the drawing of LLDPE at the lower temperature produces a relatively high content of monoclinic crystals; the orientation behavior of LLDPE is similar to that of HDPE. The molecular network formed by entanglements and crystals reduces the draw to a maximum below 15.</abstract><cop>New York</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.1985.070301104</doi><tpages>9</tpages></addata></record> |
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subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization Structure, morphology and analysis |
title | Uniaxial orientation of linear low density polyethylene |
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