High-temperature redox-initiated emulsion polymerization of butadiene
The kinetics of the ferric ethylenediaminetetraacetate (EDTA)–diisopropylbenzene hydroperoxide (DIBHP)‐sodium formaldehyde sulfoxylate (SFS) redox system were determined. The rate constant is a function of the ionic strength μ. A plot of log10 (rate constant), for the rate‐limiting second‐order iron...
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| Veröffentlicht in: | Journal of applied polymer science 1982-04, Vol.27 (4), p.1385-1393 |
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| container_title | Journal of applied polymer science |
| container_volume | 27 |
| creator | Padwa, Allen R. Paster, Mark D. |
| description | The kinetics of the ferric ethylenediaminetetraacetate (EDTA)–diisopropylbenzene hydroperoxide (DIBHP)‐sodium formaldehyde sulfoxylate (SFS) redox system were determined. The rate constant is a function of the ionic strength μ. A plot of log10 (rate constant), for the rate‐limiting second‐order iron—SFS reaction, vs.μ1/2 has a slope of 1.3 with a limiting rate constant of 295 ± 15 L. mol−1. min−1 at μ = 0. The slope of this plot decreases to essentially zero for μ > 0.06M. Incorporation of these results into the Smith‐Ewart model for emulsion polymerization correctly predicts the dependence of latex particle size on Fe and DIBHP concentration, but a much lower dependence on SFS concentration is observed. |
| doi_str_mv | 10.1002/app.1982.070270427 |
| format | Article |
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The rate constant is a function of the ionic strength μ. A plot of log10 (rate constant), for the rate‐limiting second‐order iron—SFS reaction, vs.μ1/2 has a slope of 1.3 with a limiting rate constant of 295 ± 15 L. mol−1. min−1 at μ = 0. The slope of this plot decreases to essentially zero for μ > 0.06M. Incorporation of these results into the Smith‐Ewart model for emulsion polymerization correctly predicts the dependence of latex particle size on Fe and DIBHP concentration, but a much lower dependence on SFS concentration is observed.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.1982.070270427</identifier><language>eng</language><publisher>New York: Wiley Subscription Services, Inc., A Wiley Company</publisher><ispartof>Journal of applied polymer science, 1982-04, Vol.27 (4), p.1385-1393</ispartof><rights>Copyright © 1982 John Wiley & Sons, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3367-8d4eb7f14d9772046673d2138a43be8cd85a65ce74626ec31b380736b84d98823</citedby><cites>FETCH-LOGICAL-c3367-8d4eb7f14d9772046673d2138a43be8cd85a65ce74626ec31b380736b84d98823</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.1982.070270427$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.1982.070270427$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Padwa, Allen R.</creatorcontrib><creatorcontrib>Paster, Mark D.</creatorcontrib><title>High-temperature redox-initiated emulsion polymerization of butadiene</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The kinetics of the ferric ethylenediaminetetraacetate (EDTA)–diisopropylbenzene hydroperoxide (DIBHP)‐sodium formaldehyde sulfoxylate (SFS) redox system were determined. The rate constant is a function of the ionic strength μ. A plot of log10 (rate constant), for the rate‐limiting second‐order iron—SFS reaction, vs.μ1/2 has a slope of 1.3 with a limiting rate constant of 295 ± 15 L. mol−1. min−1 at μ = 0. The slope of this plot decreases to essentially zero for μ > 0.06M. Incorporation of these results into the Smith‐Ewart model for emulsion polymerization correctly predicts the dependence of latex particle size on Fe and DIBHP concentration, but a much lower dependence on SFS concentration is observed.</description><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1982</creationdate><recordtype>article</recordtype><recordid>eNqN0N9KwzAUBvAgCs7pC3jVF8jMnzZJwZsxdROmTph4GdLmVKPtWpIMN5_ejsnw0qvDgfM7fHwIXVIyooSwK9N1I5orNiKSMElSJo_QgJJc4lQwdYwG_RHFKs-zU3QWwgchlGZEDNDtzL294whNB97EtYfEg2032K1cdCaCTaBZ18G1q6Rr620D3n2buFvbKinW0VgHKzhHJ5WpA1z8ziF6ubtdTmZ4_jS9n4znuORcSKxsCoWsaGpzKRlJhZDcMsqVSXkBqrQqMyIrQfahBZScFlwRyUWheqEU40PE9n9L34bgodKdd43xW02J3hWh-yL0rgh9KKJH13v05WrY_kPo8WLxl-M9dyHC5sCN_9R9fJnp18epvhFk-bDkQj_zH2dDcnU</recordid><startdate>198204</startdate><enddate>198204</enddate><creator>Padwa, Allen R.</creator><creator>Paster, Mark D.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>198204</creationdate><title>High-temperature redox-initiated emulsion polymerization of butadiene</title><author>Padwa, Allen R. ; Paster, Mark D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3367-8d4eb7f14d9772046673d2138a43be8cd85a65ce74626ec31b380736b84d98823</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1982</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Padwa, Allen R.</creatorcontrib><creatorcontrib>Paster, Mark D.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Padwa, Allen R.</au><au>Paster, Mark D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High-temperature redox-initiated emulsion polymerization of butadiene</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>1982-04</date><risdate>1982</risdate><volume>27</volume><issue>4</issue><spage>1385</spage><epage>1393</epage><pages>1385-1393</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>The kinetics of the ferric ethylenediaminetetraacetate (EDTA)–diisopropylbenzene hydroperoxide (DIBHP)‐sodium formaldehyde sulfoxylate (SFS) redox system were determined. The rate constant is a function of the ionic strength μ. A plot of log10 (rate constant), for the rate‐limiting second‐order iron—SFS reaction, vs.μ1/2 has a slope of 1.3 with a limiting rate constant of 295 ± 15 L. mol−1. min−1 at μ = 0. The slope of this plot decreases to essentially zero for μ > 0.06M. Incorporation of these results into the Smith‐Ewart model for emulsion polymerization correctly predicts the dependence of latex particle size on Fe and DIBHP concentration, but a much lower dependence on SFS concentration is observed.</abstract><cop>New York</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.1982.070270427</doi><tpages>9</tpages></addata></record> |
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| ispartof | Journal of applied polymer science, 1982-04, Vol.27 (4), p.1385-1393 |
| issn | 0021-8995 1097-4628 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| title | High-temperature redox-initiated emulsion polymerization of butadiene |
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