Absorption phenomena in the treatment of cotton with formaldehyde and cyclic oxymethylenes

Monomeric formaldehyde and the cyclic oxymethylenes tetraoxane and pentaoxane were retained by cotton to similar extents at the high temperatures used in textile finishing, but the mechanisms of absorption appeared to differ. Trioxane, however, was not retained by cotton. The absorption of cyclic ox...

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Veröffentlicht in:Journal of applied polymer science 1974-05, Vol.18 (5), p.1423-1431
Hauptverfasser: Furukawa, M, Frick, J.G. Jr, Reinhardt, R.M, Reid, J.D
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Sprache:eng
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Zusammenfassung:Monomeric formaldehyde and the cyclic oxymethylenes tetraoxane and pentaoxane were retained by cotton to similar extents at the high temperatures used in textile finishing, but the mechanisms of absorption appeared to differ. Trioxane, however, was not retained by cotton. The absorption of cyclic oxymethylenes did not seem to involve bonding to cellulose by primary valence bonds. The presence of other substances had a greater effect on the absorption of monomeric formaldehyde than of cyclic oxymethylenes, but changes in extent of absorption were not large enough to influence textile properties of treated fabric.
ISSN:0021-8995
1097-4628
DOI:10.1002/app.1974.070180513