Plasma-enhanced synthesis of maltodextrin-polydimethylsiloxane graft copolymers
Ether‐extracted maltodextrin (MD) powder was surface functionalized under 13.56‐MHz RF–SiCl4‐plasma conditions, and consecutively in situ aminated and grafted using dichlorodimethylsilane. Survey and high‐resolution X‐ray photoelectron spectroscopy, FTIR evaluations, fluorescence‐labeling technique,...
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| Veröffentlicht in: | Journal of applied polymer science 2001-05, Vol.80 (8), p.1120-1129 |
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| container_issue | 8 |
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| container_title | Journal of applied polymer science |
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| creator | Ma, Y. C. Manolache, S. Sarmadi, M. Denes, F. |
| description | Ether‐extracted maltodextrin (MD) powder was surface functionalized under 13.56‐MHz RF–SiCl4‐plasma conditions, and consecutively in situ aminated and grafted using dichlorodimethylsilane. Survey and high‐resolution X‐ray photoelectron spectroscopy, FTIR evaluations, fluorescence‐labeling technique, SEM, and DTA/TG analyses prove the presence of a graft‐copolymer layer on the modified starch‐granule surfaces and the existence of a significantly changed surface morphology of the starch granules, as a result of the grafting reactions. The hydrophobic nature of the polydimethylsiloxane‐grafted starch and its significantly changed thermal behaviors were also evaluated. Potential applications of modified maltodextrins are discussed. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 1120–1129, 2001 |
| doi_str_mv | 10.1002/app.1195 |
| format | Article |
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J Appl Polym Sci 80: 1120–1129, 2001</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.1195</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>New York: John Wiley & Sons, Inc</publisher><subject>Applied sciences ; Exact sciences and technology ; functionalized surface ; maltodextrin ; Physicochemistry of polymers ; plasma ; polydimethylsiloxane grafted ; Polymers and radiations ; Properties and characterization ; silicon tetrachloride</subject><ispartof>Journal of applied polymer science, 2001-05, Vol.80 (8), p.1120-1129</ispartof><rights>Copyright © 2001 John Wiley & Sons, Inc.</rights><rights>2001 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3295-7a49b5f26c42c95a9c7f3a1fef38058f1f637229e07d9a7da9c5d750bcaf7f193</citedby><cites>FETCH-LOGICAL-c3295-7a49b5f26c42c95a9c7f3a1fef38058f1f637229e07d9a7da9c5d750bcaf7f193</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.1195$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.1195$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=950711$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ma, Y. C.</creatorcontrib><creatorcontrib>Manolache, S.</creatorcontrib><creatorcontrib>Sarmadi, M.</creatorcontrib><creatorcontrib>Denes, F.</creatorcontrib><title>Plasma-enhanced synthesis of maltodextrin-polydimethylsiloxane graft copolymers</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Ether‐extracted maltodextrin (MD) powder was surface functionalized under 13.56‐MHz RF–SiCl4‐plasma conditions, and consecutively in situ aminated and grafted using dichlorodimethylsilane. Survey and high‐resolution X‐ray photoelectron spectroscopy, FTIR evaluations, fluorescence‐labeling technique, SEM, and DTA/TG analyses prove the presence of a graft‐copolymer layer on the modified starch‐granule surfaces and the existence of a significantly changed surface morphology of the starch granules, as a result of the grafting reactions. The hydrophobic nature of the polydimethylsiloxane‐grafted starch and its significantly changed thermal behaviors were also evaluated. Potential applications of modified maltodextrins are discussed. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 1120–1129, 2001</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>functionalized surface</subject><subject>maltodextrin</subject><subject>Physicochemistry of polymers</subject><subject>plasma</subject><subject>polydimethylsiloxane grafted</subject><subject>Polymers and radiations</subject><subject>Properties and characterization</subject><subject>silicon tetrachloride</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNp10E9LwzAYBvAgCs4p-BEKXrxkJm3TNMc5dBOGG6LzGN6liYumf0gKtt_ejo3dPL2H58cD74PQLSUTSkj8AE0zoVSwMzSiRHCcZnF-jkZDRHEuBLtEVyF8E0IpI9kIrdYOQglYVzuolC6i0FftTgcbotpEJbi2LnTXelvhpnZ9YUvd7noXrKs7qHT05cG0kar3Yal9uEYXBlzQN8c7Rh_PT--zBV6u5i-z6RKrJBYMc0jFlpk4U2msBAOhuEmAGm2SnLDcUJMlPI6FJrwQwIsBsIIzslVguKEiGaP7Q6_ydQheG9l4W4LvJSVyP4QchpD7IQZ6d6ANBAXO-OFRG05eMMIpHRQ-qF_rdP9vm5yu18fWo7eh1d3Jg_-RGU84k5-vc7lZLt4e01kqN8kffLR9FA</recordid><startdate>20010523</startdate><enddate>20010523</enddate><creator>Ma, Y. 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C.</creatorcontrib><creatorcontrib>Manolache, S.</creatorcontrib><creatorcontrib>Sarmadi, M.</creatorcontrib><creatorcontrib>Denes, F.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Y. C.</au><au>Manolache, S.</au><au>Sarmadi, M.</au><au>Denes, F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Plasma-enhanced synthesis of maltodextrin-polydimethylsiloxane graft copolymers</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2001-05-23</date><risdate>2001</risdate><volume>80</volume><issue>8</issue><spage>1120</spage><epage>1129</epage><pages>1120-1129</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Ether‐extracted maltodextrin (MD) powder was surface functionalized under 13.56‐MHz RF–SiCl4‐plasma conditions, and consecutively in situ aminated and grafted using dichlorodimethylsilane. Survey and high‐resolution X‐ray photoelectron spectroscopy, FTIR evaluations, fluorescence‐labeling technique, SEM, and DTA/TG analyses prove the presence of a graft‐copolymer layer on the modified starch‐granule surfaces and the existence of a significantly changed surface morphology of the starch granules, as a result of the grafting reactions. The hydrophobic nature of the polydimethylsiloxane‐grafted starch and its significantly changed thermal behaviors were also evaluated. Potential applications of modified maltodextrins are discussed. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 1120–1129, 2001</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.1195</doi><tpages>10</tpages></addata></record> |
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| source | Wiley Online Library - AutoHoldings Journals |
| subjects | Applied sciences Exact sciences and technology functionalized surface maltodextrin Physicochemistry of polymers plasma polydimethylsiloxane grafted Polymers and radiations Properties and characterization silicon tetrachloride |
| title | Plasma-enhanced synthesis of maltodextrin-polydimethylsiloxane graft copolymers |
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