Relationship between thermodynamical parameters of activated complexes and initial reactants in the reaction of peroxides with amines

Relationship between thermodynamical parameters of activated complexes and initial reactants in the reaction of peroxides with amines

The linear dependence between heats of formation and entropies of initial reactants on the one hand and the corresponding thermodynamical parameters of activated complexes on the other hand was obtained for the reaction of peroxides with amines. This relationship allows one to estimate such paramete...

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Veröffentlicht in:Journal of applied polymer science 2003-01, Vol.87 (4), p.641-642
Hauptverfasser: Turovskiy, A. A., Turovskiy, N. A., Kopylets, V. I., Zagladko, E. A., Zaikov, G. A.
Format: Artikel
Sprache:eng
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Zusammenfassung:The linear dependence between heats of formation and entropies of initial reactants on the one hand and the corresponding thermodynamical parameters of activated complexes on the other hand was obtained for the reaction of peroxides with amines. This relationship allows one to estimate such parameters for other similar reactions of amines with peroxides. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 641–642, 2003
ISSN:0021-8995
1097-4628
DOI:10.1002/app.11326