Oxidizability of lactams and lactam-based polyamides
In the chain oxidation of N‐alkylamides with molecular oxygen, propagation is the ratedetermining step under conditions when the oxidation rate is independent of oxygen pressure. The oxidizability of lactams and lactam‐based polyamides correlates with the energy of the formation of N‐alkylamide radi...
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| Veröffentlicht in: | Die Angewandte makromolekulare Chemie 1997-12, Vol.252 (1), p.139-151 |
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| container_end_page | 151 |
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| container_issue | 1 |
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| container_title | Die Angewandte makromolekulare Chemie |
| container_volume | 252 |
| creator | Lánská, Božena |
| description | In the chain oxidation of N‐alkylamides with molecular oxygen, propagation is the ratedetermining step under conditions when the oxidation rate is independent of oxygen pressure. The oxidizability of lactams and lactam‐based polyamides correlates with the energy of the formation of N‐alkylamide radical by ion of hydrogen from the methylene group adjacent to nitrogen. While for lactams this energy depends on the number of carbons in the lactam ring, for N‐alkylamides and polylactams such dependence is not observed. |
| doi_str_mv | 10.1002/apmc.1997.052520110 |
| format | Article |
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| identifier | ISSN: 0003-3146 |
| ispartof | Die Angewandte makromolekulare Chemie, 1997-12, Vol.252 (1), p.139-151 |
| issn | 0003-3146 1522-9505 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_apmc_1997_052520110 |
| source | Wiley Online Library Journals Frontfile Complete |
| title | Oxidizability of lactams and lactam-based polyamides |
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