Reaction of phenyltrifluorosilane with 8-hydroxy- or 8-mercapto-quinoline and their derivatives as a route to new heterocyclic compounds of pentacoordinate silicon

The protodesilylation of phenyltrifluorosilane with 8‐hydroxy‐ and 8‐mercapto‐quinoline NC9H6YH (Y: O, 1a; S, 1b) affords the novel intramolecular pentacoordinate silanes (N $\longrightarrow$ Si) 8‐(trifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(trifluorosilylthio)‐quinoline respectively. The (N...

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Veröffentlicht in:	Applied organometallic chemistry 2005-04, Vol.19 (4), p.538-541
Hauptverfasser:	Voronkov, Mikhail G., Trofimova, Olga M., Chernov, Nikolai F., Albanov, Aleksandr I., Chipanina, Nina N., Grebneva, Ekaterina A.
Format:	Artikel
Sprache:	eng
Schlagworte:	8-(phenyldifluorosiloxy(thio))quinoline 8-(trifluorosiloxy(thio))quinoline pentacoordinate silicon phenyltrifluorosilane protodesilylation
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