Reaction of phenyltrifluorosilane with 8-hydroxy- or 8-mercapto-quinoline and their derivatives as a route to new heterocyclic compounds of pentacoordinate silicon
The protodesilylation of phenyltrifluorosilane with 8‐hydroxy‐ and 8‐mercapto‐quinoline NC9H6YH (Y: O, 1a; S, 1b) affords the novel intramolecular pentacoordinate silanes (N $\longrightarrow$ Si) 8‐(trifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(trifluorosilylthio)‐quinoline respectively. The (N...
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| Veröffentlicht in: | Applied organometallic chemistry 2005-04, Vol.19 (4), p.538-541 |
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| container_title | Applied organometallic chemistry |
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| creator | Voronkov, Mikhail G. Trofimova, Olga M. Chernov, Nikolai F. Albanov, Aleksandr I. Chipanina, Nina N. Grebneva, Ekaterina A. |
| description | The protodesilylation of phenyltrifluorosilane with 8‐hydroxy‐ and 8‐mercapto‐quinoline NC9H6YH (Y: O, 1a; S, 1b) affords the novel intramolecular pentacoordinate silanes (N $\longrightarrow$ Si) 8‐(trifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(trifluorosilylthio)‐quinoline respectively. The (N $\longrightarrow$ Si) 8‐(Phenyldifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(phenyldifluorosilylthio)‐quinolines prepared by the transsilylation reaction of trimethylsilyl derivatives of heterocycles 1a and 1b by phenyltrifluorosilane possess a similar pentacoordinate structure. Copyright © 2005 John Wiley & Sons, Ltd.
The protodesilylation of phenyltrifluorosilane with 8‐hydroxy‐ and 8‐mercapto‐quinoline NC9‐H6YH (Y:O, 1a; S, 1b) affords the novel intramolecular pentacoordinate silanes (N $\longrightarrow$ Si) 8‐(trifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(trifluorosilylthio)‐quinoline respectively. (N $\longrightarrow$ Si) 8‐(Phenyldifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(phenyldifluorosilylthio)‐quinolines prepared by the transsilylation reaction of trimethylsilyl derivatives of heterocycles 1a and 1b by phenyltrifluorosilane possess a similar pentacoordinate structure. |
| doi_str_mv | 10.1002/aoc.861 |
| format | Article |
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The protodesilylation of phenyltrifluorosilane with 8‐hydroxy‐ and 8‐mercapto‐quinoline NC9‐H6YH (Y:O, 1a; S, 1b) affords the novel intramolecular pentacoordinate silanes (N $\longrightarrow$ Si) 8‐(trifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(trifluorosilylthio)‐quinoline respectively. (N $\longrightarrow$ Si) 8‐(Phenyldifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(phenyldifluorosilylthio)‐quinolines prepared by the transsilylation reaction of trimethylsilyl derivatives of heterocycles 1a and 1b by phenyltrifluorosilane possess a similar pentacoordinate structure.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.861</identifier><identifier>CODEN: AOCHEX</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>8-(phenyldifluorosiloxy(thio))quinoline ; 8-(trifluorosiloxy(thio))quinoline ; pentacoordinate silicon ; phenyltrifluorosilane ; protodesilylation</subject><ispartof>Applied organometallic chemistry, 2005-04, Vol.19 (4), p.538-541</ispartof><rights>Copyright © 2005 John Wiley & Sons, Ltd.</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3291-1d8e09cf82608c57b048ea0af10d03f4ac726511d0950c4c9db363d1344873e73</citedby><cites>FETCH-LOGICAL-c3291-1d8e09cf82608c57b048ea0af10d03f4ac726511d0950c4c9db363d1344873e73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.861$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.861$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16585085$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Voronkov, Mikhail G.</creatorcontrib><creatorcontrib>Trofimova, Olga M.</creatorcontrib><creatorcontrib>Chernov, Nikolai F.</creatorcontrib><creatorcontrib>Albanov, Aleksandr I.</creatorcontrib><creatorcontrib>Chipanina, Nina N.</creatorcontrib><creatorcontrib>Grebneva, Ekaterina A.</creatorcontrib><title>Reaction of phenyltrifluorosilane with 8-hydroxy- or 8-mercapto-quinoline and their derivatives as a route to new heterocyclic compounds of pentacoordinate silicon</title><title>Applied organometallic chemistry</title><addtitle>Appl. Organometal. Chem</addtitle><description>The protodesilylation of phenyltrifluorosilane with 8‐hydroxy‐ and 8‐mercapto‐quinoline NC9H6YH (Y: O, 1a; S, 1b) affords the novel intramolecular pentacoordinate silanes (N $\longrightarrow$ Si) 8‐(trifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(trifluorosilylthio)‐quinoline respectively. The (N $\longrightarrow$ Si) 8‐(Phenyldifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(phenyldifluorosilylthio)‐quinolines prepared by the transsilylation reaction of trimethylsilyl derivatives of heterocycles 1a and 1b by phenyltrifluorosilane possess a similar pentacoordinate structure. Copyright © 2005 John Wiley & Sons, Ltd.
The protodesilylation of phenyltrifluorosilane with 8‐hydroxy‐ and 8‐mercapto‐quinoline NC9‐H6YH (Y:O, 1a; S, 1b) affords the novel intramolecular pentacoordinate silanes (N $\longrightarrow$ Si) 8‐(trifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(trifluorosilylthio)‐quinoline respectively. (N $\longrightarrow$ Si) 8‐(Phenyldifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(phenyldifluorosilylthio)‐quinolines prepared by the transsilylation reaction of trimethylsilyl derivatives of heterocycles 1a and 1b by phenyltrifluorosilane possess a similar pentacoordinate structure.</description><subject>8-(phenyldifluorosiloxy(thio))quinoline</subject><subject>8-(trifluorosiloxy(thio))quinoline</subject><subject>pentacoordinate silicon</subject><subject>phenyltrifluorosilane</subject><subject>protodesilylation</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNp1kNFqFTEQhoMoeKzFV8iNeCFbJ5vdbPayHGwrlhZapZchTWbZ6J5kTXJ6us_TFzW6olfCwDDwzT_z_4S8YXDCAOoPOpgTKdgzsmHQ9xV0vH9ONlALWdUC2pfkVUrfAKAXrNmQpxvUJrvgaRjoPKJfphzdMO1DDMlN2iM9uDxSWY2LjeFxqWiIZdphNHrOofqxdz5MrnDaW5pHdJFajO5BZ_eAiepSNIZ9RpoD9XigI2aMwSxmcoaasJvD3tv0-z76rE0I0Tqvy0J5wJngX5MXg54SHv_pR-Tr2ccv24vq8vr80_b0sjK87lnFrETozSCLTWna7h4aiRr0wMACHxptulq0jFnoWzCN6e09F9wy3jSy49jxI_Ju1TXFe4o4qDm6nY6LYqB-ZatKtqpkW8i3KznrZPQ0RO2NS_9w0coWZFu49yt3cBMu_5NTp9fbVbVaaZcyPv6ldfyuRMe7Vt1dnSu4PROfu_5KXfCf7hKaBQ</recordid><startdate>200504</startdate><enddate>200504</enddate><creator>Voronkov, Mikhail G.</creator><creator>Trofimova, Olga M.</creator><creator>Chernov, Nikolai F.</creator><creator>Albanov, Aleksandr I.</creator><creator>Chipanina, Nina N.</creator><creator>Grebneva, Ekaterina A.</creator><general>John Wiley & Sons, Ltd</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200504</creationdate><title>Reaction of phenyltrifluorosilane with 8-hydroxy- or 8-mercapto-quinoline and their derivatives as a route to new heterocyclic compounds of pentacoordinate silicon</title><author>Voronkov, Mikhail G. ; Trofimova, Olga M. ; Chernov, Nikolai F. ; Albanov, Aleksandr I. ; Chipanina, Nina N. ; Grebneva, Ekaterina A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3291-1d8e09cf82608c57b048ea0af10d03f4ac726511d0950c4c9db363d1344873e73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>8-(phenyldifluorosiloxy(thio))quinoline</topic><topic>8-(trifluorosiloxy(thio))quinoline</topic><topic>pentacoordinate silicon</topic><topic>phenyltrifluorosilane</topic><topic>protodesilylation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Voronkov, Mikhail G.</creatorcontrib><creatorcontrib>Trofimova, Olga M.</creatorcontrib><creatorcontrib>Chernov, Nikolai F.</creatorcontrib><creatorcontrib>Albanov, Aleksandr I.</creatorcontrib><creatorcontrib>Chipanina, Nina N.</creatorcontrib><creatorcontrib>Grebneva, Ekaterina A.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Voronkov, Mikhail G.</au><au>Trofimova, Olga M.</au><au>Chernov, Nikolai F.</au><au>Albanov, Aleksandr I.</au><au>Chipanina, Nina N.</au><au>Grebneva, Ekaterina A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reaction of phenyltrifluorosilane with 8-hydroxy- or 8-mercapto-quinoline and their derivatives as a route to new heterocyclic compounds of pentacoordinate silicon</atitle><jtitle>Applied organometallic chemistry</jtitle><addtitle>Appl. Organometal. Chem</addtitle><date>2005-04</date><risdate>2005</risdate><volume>19</volume><issue>4</issue><spage>538</spage><epage>541</epage><pages>538-541</pages><issn>0268-2605</issn><eissn>1099-0739</eissn><coden>AOCHEX</coden><abstract>The protodesilylation of phenyltrifluorosilane with 8‐hydroxy‐ and 8‐mercapto‐quinoline NC9H6YH (Y: O, 1a; S, 1b) affords the novel intramolecular pentacoordinate silanes (N $\longrightarrow$ Si) 8‐(trifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(trifluorosilylthio)‐quinoline respectively. The (N $\longrightarrow$ Si) 8‐(Phenyldifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(phenyldifluorosilylthio)‐quinolines prepared by the transsilylation reaction of trimethylsilyl derivatives of heterocycles 1a and 1b by phenyltrifluorosilane possess a similar pentacoordinate structure. Copyright © 2005 John Wiley & Sons, Ltd.
The protodesilylation of phenyltrifluorosilane with 8‐hydroxy‐ and 8‐mercapto‐quinoline NC9‐H6YH (Y:O, 1a; S, 1b) affords the novel intramolecular pentacoordinate silanes (N $\longrightarrow$ Si) 8‐(trifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(trifluorosilylthio)‐quinoline respectively. (N $\longrightarrow$ Si) 8‐(Phenyldifluorosiloxy)‐ and (N $\longrightarrow$ Si) 8‐(phenyldifluorosilylthio)‐quinolines prepared by the transsilylation reaction of trimethylsilyl derivatives of heterocycles 1a and 1b by phenyltrifluorosilane possess a similar pentacoordinate structure.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/aoc.861</doi><tpages>4</tpages></addata></record> |
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| ispartof | Applied organometallic chemistry, 2005-04, Vol.19 (4), p.538-541 |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | 8-(phenyldifluorosiloxy(thio))quinoline 8-(trifluorosiloxy(thio))quinoline pentacoordinate silicon phenyltrifluorosilane protodesilylation |
| title | Reaction of phenyltrifluorosilane with 8-hydroxy- or 8-mercapto-quinoline and their derivatives as a route to new heterocyclic compounds of pentacoordinate silicon |
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