The synthesis and tin-119m Mössbauer spectra of a series of di (4-substituted phenyl) tin dichloride complexes with nitrogen-donor ligands
The synthesis and 119mSn Mössbauer spectra of a series of 12 new and 3 other organotin complexes of general structure (4‐ZC6H4)2SnCl2.L2.(Z = CH3, CF3, F, Cl, OCH3, L2=2,2′‐bipyridyl, 1,10‐phenanthroline, 2‐aminomethylpyridine) arereported. A convenient method for the preparation of the intermediate...
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Veröffentlicht in: | Applied organometallic chemistry 1987, Vol.1 (3), p.261-265 |
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creator | Biddle, B N Gray, J S Crowe, A J |
description | The synthesis and 119mSn Mössbauer spectra of a series of 12 new and 3 other organotin complexes of general structure (4‐ZC6H4)2SnCl2.L2.(Z = CH3, CF3, F, Cl, OCH3, L2=2,2′‐bipyridyl, 1,10‐phenanthroline, 2‐aminomethylpyridine) arereported. A convenient method for the preparation of the intermediate diaryltin(IV) dihalides is given. The complexes fall into two isomeric types with either a trans‐ or cis‐[ArSnAr] geometry. For this series 2‐aminomethylpyridine gives exclusively the cis‐[ArSnAr] geometry in its complexes. |
doi_str_mv | 10.1002/aoc.590010308 |
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A convenient method for the preparation of the intermediate diaryltin(IV) dihalides is given. The complexes fall into two isomeric types with either a trans‐ or cis‐[ArSnAr] geometry. For this series 2‐aminomethylpyridine gives exclusively the cis‐[ArSnAr] geometry in its complexes.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.590010308</identifier><identifier>CODEN: AOCHEX</identifier><language>eng</language><publisher>Essex: Longman Group UK Ltd</publisher><subject>Anti-tumour agents ; Aryltin chlorides ; Chemistry ; Exact sciences and technology ; Ge, sn, pb derivatives ; Mössbauer spectra ; Organic chemistry ; Organometalloidal and organometallic compounds ; Organotin complexes ; Preparations and properties</subject><ispartof>Applied organometallic chemistry, 1987, Vol.1 (3), p.261-265</ispartof><rights>Copyright © 1987 Longman Group UK Ltd.</rights><rights>1988 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2678-ca6d2d9dae2bc0a97c9e2d92099ace54bb3789b5df338714616663ff9ff8eb193</citedby><cites>FETCH-LOGICAL-c2678-ca6d2d9dae2bc0a97c9e2d92099ace54bb3789b5df338714616663ff9ff8eb193</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.590010308$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.590010308$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,4010,27900,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7406618$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Biddle, B N</creatorcontrib><creatorcontrib>Gray, J S</creatorcontrib><creatorcontrib>Crowe, A J</creatorcontrib><title>The synthesis and tin-119m Mössbauer spectra of a series of di (4-substituted phenyl) tin dichloride complexes with nitrogen-donor ligands</title><title>Applied organometallic chemistry</title><addtitle>Appl. Organometal. Chem</addtitle><description>The synthesis and 119mSn Mössbauer spectra of a series of 12 new and 3 other organotin complexes of general structure (4‐ZC6H4)2SnCl2.L2.(Z = CH3, CF3, F, Cl, OCH3, L2=2,2′‐bipyridyl, 1,10‐phenanthroline, 2‐aminomethylpyridine) arereported. A convenient method for the preparation of the intermediate diaryltin(IV) dihalides is given. The complexes fall into two isomeric types with either a trans‐ or cis‐[ArSnAr] geometry. For this series 2‐aminomethylpyridine gives exclusively the cis‐[ArSnAr] geometry in its complexes.</description><subject>Anti-tumour agents</subject><subject>Aryltin chlorides</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Ge, sn, pb derivatives</subject><subject>Mössbauer spectra</subject><subject>Organic chemistry</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Organotin complexes</subject><subject>Preparations and properties</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNp9UM1u1DAQjiqQurQcufvAAQ4udpzY8bFaSlupP5eFHi3HHjeGbBJ5vGr3GXgfXoAXI6utVpx6mhnN9zPzFcUHzs44Y-UXO7qzWjPGmWDNUbHgTGvKlNBvigUrZUNLyerj4h3iT8aYlrxaFL9XHRDcDrkDjEjs4EmOA-Vcr8nt3z-Ird1AIjiBy8mSMRBLEFIE3PU-kk8VxU2LOeZNBk-mDoZt_3knMm9d148peiBuXE89PM-sp5g7MsScxkcYqB-HMZE-Ps7GeFq8DbZHeP9ST4rv3y5Wyyt6c395vTy_oa6UqqHOSl967S2UrWNWK6dhnsv5W-ugrtpWqEa3tQ9CNIpXkkspRQg6hAZarsVJQfe6Lo2ICYKZUlzbtDWcmV2SZk7SHJKc8R_3-Mmis31IdnARDyRVMSn5Dqb2sKfYw_Z1TXN-v_zf4OWgiBmeD0ybfhmphKrNw92luXsQjfxxuzJfxT9-P5XR</recordid><startdate>1987</startdate><enddate>1987</enddate><creator>Biddle, B N</creator><creator>Gray, J S</creator><creator>Crowe, A J</creator><general>Longman Group UK Ltd</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>1987</creationdate><title>The synthesis and tin-119m Mössbauer spectra of a series of di (4-substituted phenyl) tin dichloride complexes with nitrogen-donor ligands</title><author>Biddle, B N ; Gray, J S ; Crowe, A J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2678-ca6d2d9dae2bc0a97c9e2d92099ace54bb3789b5df338714616663ff9ff8eb193</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>Anti-tumour agents</topic><topic>Aryltin chlorides</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Ge, sn, pb derivatives</topic><topic>Mössbauer spectra</topic><topic>Organic chemistry</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Organotin complexes</topic><topic>Preparations and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Biddle, B N</creatorcontrib><creatorcontrib>Gray, J S</creatorcontrib><creatorcontrib>Crowe, A J</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Biddle, B N</au><au>Gray, J S</au><au>Crowe, A J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The synthesis and tin-119m Mössbauer spectra of a series of di (4-substituted phenyl) tin dichloride complexes with nitrogen-donor ligands</atitle><jtitle>Applied organometallic chemistry</jtitle><addtitle>Appl. Organometal. Chem</addtitle><date>1987</date><risdate>1987</risdate><volume>1</volume><issue>3</issue><spage>261</spage><epage>265</epage><pages>261-265</pages><issn>0268-2605</issn><eissn>1099-0739</eissn><coden>AOCHEX</coden><abstract>The synthesis and 119mSn Mössbauer spectra of a series of 12 new and 3 other organotin complexes of general structure (4‐ZC6H4)2SnCl2.L2.(Z = CH3, CF3, F, Cl, OCH3, L2=2,2′‐bipyridyl, 1,10‐phenanthroline, 2‐aminomethylpyridine) arereported. A convenient method for the preparation of the intermediate diaryltin(IV) dihalides is given. The complexes fall into two isomeric types with either a trans‐ or cis‐[ArSnAr] geometry. For this series 2‐aminomethylpyridine gives exclusively the cis‐[ArSnAr] geometry in its complexes.</abstract><cop>Essex</cop><pub>Longman Group UK Ltd</pub><doi>10.1002/aoc.590010308</doi><tpages>5</tpages></addata></record> |
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subjects | Anti-tumour agents Aryltin chlorides Chemistry Exact sciences and technology Ge, sn, pb derivatives Mössbauer spectra Organic chemistry Organometalloidal and organometallic compounds Organotin complexes Preparations and properties |
title | The synthesis and tin-119m Mössbauer spectra of a series of di (4-substituted phenyl) tin dichloride complexes with nitrogen-donor ligands |
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