The synthesis and tin-119m Mössbauer spectra of a series of di (4-substituted phenyl) tin dichloride complexes with nitrogen-donor ligands

The synthesis and 119mSn Mössbauer spectra of a series of 12 new and 3 other organotin complexes of general structure (4‐ZC6H4)2SnCl2.L2.(Z = CH3, CF3, F, Cl, OCH3, L2=2,2′‐bipyridyl, 1,10‐phenanthroline, 2‐aminomethylpyridine) arereported. A convenient method for the preparation of the intermediate...

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Veröffentlicht in:Applied organometallic chemistry 1987, Vol.1 (3), p.261-265
Hauptverfasser: Biddle, B N, Gray, J S, Crowe, A J
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container_title Applied organometallic chemistry
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creator Biddle, B N
Gray, J S
Crowe, A J
description The synthesis and 119mSn Mössbauer spectra of a series of 12 new and 3 other organotin complexes of general structure (4‐ZC6H4)2SnCl2.L2.(Z = CH3, CF3, F, Cl, OCH3, L2=2,2′‐bipyridyl, 1,10‐phenanthroline, 2‐aminomethylpyridine) arereported. A convenient method for the preparation of the intermediate diaryltin(IV) dihalides is given. The complexes fall into two isomeric types with either a trans‐ or cis‐[ArSnAr] geometry. For this series 2‐aminomethylpyridine gives exclusively the cis‐[ArSnAr] geometry in its complexes.
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A convenient method for the preparation of the intermediate diaryltin(IV) dihalides is given. The complexes fall into two isomeric types with either a trans‐ or cis‐[ArSnAr] geometry. 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Organometal. Chem</addtitle><description>The synthesis and 119mSn Mössbauer spectra of a series of 12 new and 3 other organotin complexes of general structure (4‐ZC6H4)2SnCl2.L2.(Z = CH3, CF3, F, Cl, OCH3, L2=2,2′‐bipyridyl, 1,10‐phenanthroline, 2‐aminomethylpyridine) arereported. A convenient method for the preparation of the intermediate diaryltin(IV) dihalides is given. The complexes fall into two isomeric types with either a trans‐ or cis‐[ArSnAr] geometry. For this series 2‐aminomethylpyridine gives exclusively the cis‐[ArSnAr] geometry in its complexes.</description><subject>Anti-tumour agents</subject><subject>Aryltin chlorides</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Ge, sn, pb derivatives</subject><subject>Mössbauer spectra</subject><subject>Organic chemistry</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Organotin complexes</subject><subject>Preparations and properties</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNp9UM1u1DAQjiqQurQcufvAAQ4udpzY8bFaSlupP5eFHi3HHjeGbBJ5vGr3GXgfXoAXI6utVpx6mhnN9zPzFcUHzs44Y-UXO7qzWjPGmWDNUbHgTGvKlNBvigUrZUNLyerj4h3iT8aYlrxaFL9XHRDcDrkDjEjs4EmOA-Vcr8nt3z-Ird1AIjiBy8mSMRBLEFIE3PU-kk8VxU2LOeZNBk-mDoZt_3knMm9d148peiBuXE89PM-sp5g7MsScxkcYqB-HMZE-Ps7GeFq8DbZHeP9ST4rv3y5Wyyt6c395vTy_oa6UqqHOSl967S2UrWNWK6dhnsv5W-ugrtpWqEa3tQ9CNIpXkkspRQg6hAZarsVJQfe6Lo2ICYKZUlzbtDWcmV2SZk7SHJKc8R_3-Mmis31IdnARDyRVMSn5Dqb2sKfYw_Z1TXN-v_zf4OWgiBmeD0ybfhmphKrNw92luXsQjfxxuzJfxT9-P5XR</recordid><startdate>1987</startdate><enddate>1987</enddate><creator>Biddle, B N</creator><creator>Gray, J S</creator><creator>Crowe, A J</creator><general>Longman Group UK Ltd</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>1987</creationdate><title>The synthesis and tin-119m Mössbauer spectra of a series of di (4-substituted phenyl) tin dichloride complexes with nitrogen-donor ligands</title><author>Biddle, B N ; Gray, J S ; Crowe, A J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2678-ca6d2d9dae2bc0a97c9e2d92099ace54bb3789b5df338714616663ff9ff8eb193</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>Anti-tumour agents</topic><topic>Aryltin chlorides</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Ge, sn, pb derivatives</topic><topic>Mössbauer spectra</topic><topic>Organic chemistry</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Organotin complexes</topic><topic>Preparations and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Biddle, B N</creatorcontrib><creatorcontrib>Gray, J S</creatorcontrib><creatorcontrib>Crowe, A J</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Biddle, B N</au><au>Gray, J S</au><au>Crowe, A J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The synthesis and tin-119m Mössbauer spectra of a series of di (4-substituted phenyl) tin dichloride complexes with nitrogen-donor ligands</atitle><jtitle>Applied organometallic chemistry</jtitle><addtitle>Appl. Organometal. Chem</addtitle><date>1987</date><risdate>1987</risdate><volume>1</volume><issue>3</issue><spage>261</spage><epage>265</epage><pages>261-265</pages><issn>0268-2605</issn><eissn>1099-0739</eissn><coden>AOCHEX</coden><abstract>The synthesis and 119mSn Mössbauer spectra of a series of 12 new and 3 other organotin complexes of general structure (4‐ZC6H4)2SnCl2.L2.(Z = CH3, CF3, F, Cl, OCH3, L2=2,2′‐bipyridyl, 1,10‐phenanthroline, 2‐aminomethylpyridine) arereported. A convenient method for the preparation of the intermediate diaryltin(IV) dihalides is given. The complexes fall into two isomeric types with either a trans‐ or cis‐[ArSnAr] geometry. For this series 2‐aminomethylpyridine gives exclusively the cis‐[ArSnAr] geometry in its complexes.</abstract><cop>Essex</cop><pub>Longman Group UK Ltd</pub><doi>10.1002/aoc.590010308</doi><tpages>5</tpages></addata></record>
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subjects Anti-tumour agents
Aryltin chlorides
Chemistry
Exact sciences and technology
Ge, sn, pb derivatives
Mössbauer spectra
Organic chemistry
Organometalloidal and organometallic compounds
Organotin complexes
Preparations and properties
title The synthesis and tin-119m Mössbauer spectra of a series of di (4-substituted phenyl) tin dichloride complexes with nitrogen-donor ligands
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