The promoting effect of organotin compounds upon peroxidation of oleic acid
The effect of the organotin compounds R nSnCl4−n (n = 1–3; where R = Me, Et, n‐Bu and Ph) upon oleic ((Z)‐9‐octadecenoic) acid oxidation by dioxygen has been studied at 25, 37, 65, and 95 °C. The promoting effect of organotins upon the formation of oleic acid hydroperoxides is temperature dependent...
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Veröffentlicht in: | Applied organometallic chemistry 2002-11, Vol.16 (11), p.655-659 |
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creator | Petrosyan, V. S. Milaeva, E. R. Gracheva, Yu. A. Grigoriev, E. V. Tyurin, V. Yu Pimenov, Yu. T. Berberova, N. T. |
description | The effect of the organotin compounds R
nSnCl4−n (n = 1–3; where R = Me, Et, n‐Bu and Ph) upon oleic ((Z)‐9‐octadecenoic) acid oxidation by dioxygen has been studied at 25, 37, 65, and 95 °C. The promoting effect of organotins upon the formation of oleic acid hydroperoxides is temperature dependent and is at a maximum at a temperature close to the physiological one, but the impact of organotins upon oleic acid peroxidation decreases in the presence of 2,6‐di‐tert‐butylphenol. The role of organic free radicals derived from the SnC bond cleavage in the oxidation of oleic acid is discussed. Copyright © 2002 John Wiley & Sons, Ltd. |
doi_str_mv | 10.1002/aoc.360 |
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nSnCl4−n (n = 1–3; where R = Me, Et, n‐Bu and Ph) upon oleic ((Z)‐9‐octadecenoic) acid oxidation by dioxygen has been studied at 25, 37, 65, and 95 °C. The promoting effect of organotins upon the formation of oleic acid hydroperoxides is temperature dependent and is at a maximum at a temperature close to the physiological one, but the impact of organotins upon oleic acid peroxidation decreases in the presence of 2,6‐di‐tert‐butylphenol. The role of organic free radicals derived from the SnC bond cleavage in the oxidation of oleic acid is discussed. Copyright © 2002 John Wiley & Sons, Ltd.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.360</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>free radicals ; oleic acid ; organotin compounds ; peroxidation</subject><ispartof>Applied organometallic chemistry, 2002-11, Vol.16 (11), p.655-659</ispartof><rights>Copyright © 2002 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2970-a9f8f5070bd861bf6d7f67327fff02bed675cef014e1a30c9bf75abe888e32113</citedby><cites>FETCH-LOGICAL-c2970-a9f8f5070bd861bf6d7f67327fff02bed675cef014e1a30c9bf75abe888e32113</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.360$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.360$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Petrosyan, V. S.</creatorcontrib><creatorcontrib>Milaeva, E. R.</creatorcontrib><creatorcontrib>Gracheva, Yu. A.</creatorcontrib><creatorcontrib>Grigoriev, E. V.</creatorcontrib><creatorcontrib>Tyurin, V. Yu</creatorcontrib><creatorcontrib>Pimenov, Yu. T.</creatorcontrib><creatorcontrib>Berberova, N. T.</creatorcontrib><title>The promoting effect of organotin compounds upon peroxidation of oleic acid</title><title>Applied organometallic chemistry</title><addtitle>Appl. Organometal. Chem</addtitle><description>The effect of the organotin compounds R
nSnCl4−n (n = 1–3; where R = Me, Et, n‐Bu and Ph) upon oleic ((Z)‐9‐octadecenoic) acid oxidation by dioxygen has been studied at 25, 37, 65, and 95 °C. The promoting effect of organotins upon the formation of oleic acid hydroperoxides is temperature dependent and is at a maximum at a temperature close to the physiological one, but the impact of organotins upon oleic acid peroxidation decreases in the presence of 2,6‐di‐tert‐butylphenol. The role of organic free radicals derived from the SnC bond cleavage in the oxidation of oleic acid is discussed. Copyright © 2002 John Wiley & Sons, Ltd.</description><subject>free radicals</subject><subject>oleic acid</subject><subject>organotin compounds</subject><subject>peroxidation</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNp10EFLwzAUB_AgCs4pfoXcPEjnS7Im7XEMnWLZQCYTLyFNkxndmpJ0uH17OyrePD3e48efxx-hawIjAkDvlNcjxuEEDQjkeQKC5adoAJRnCeWQnqOLGD8BIOdkPEDPyw-Dm-C3vnX1GhtrjW6xt9iHtaqPR6z9tvG7uop41_gaNyb4vatU67rlCDfGaay0qy7RmVWbaK5-5xC9Ptwvp49JsZg9TSdFomkuIFG5zWwKAsoq46S0vBKWC0aFtRZoaSouUm0skLEhioHOSytSVZosywyjhLAhuulzdfAxBmNlE9xWhYMkII8dyK4D2XXQydtefruNOfzH5GQx7XXSaxdbs__TKnzJ7j-RytV8Jldk_lK8Lwv5xn4Am7FtPA</recordid><startdate>200211</startdate><enddate>200211</enddate><creator>Petrosyan, V. S.</creator><creator>Milaeva, E. R.</creator><creator>Gracheva, Yu. A.</creator><creator>Grigoriev, E. V.</creator><creator>Tyurin, V. Yu</creator><creator>Pimenov, Yu. T.</creator><creator>Berberova, N. T.</creator><general>John Wiley & Sons, Ltd</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200211</creationdate><title>The promoting effect of organotin compounds upon peroxidation of oleic acid</title><author>Petrosyan, V. S. ; Milaeva, E. R. ; Gracheva, Yu. A. ; Grigoriev, E. V. ; Tyurin, V. Yu ; Pimenov, Yu. T. ; Berberova, N. T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2970-a9f8f5070bd861bf6d7f67327fff02bed675cef014e1a30c9bf75abe888e32113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>free radicals</topic><topic>oleic acid</topic><topic>organotin compounds</topic><topic>peroxidation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Petrosyan, V. S.</creatorcontrib><creatorcontrib>Milaeva, E. R.</creatorcontrib><creatorcontrib>Gracheva, Yu. A.</creatorcontrib><creatorcontrib>Grigoriev, E. V.</creatorcontrib><creatorcontrib>Tyurin, V. Yu</creatorcontrib><creatorcontrib>Pimenov, Yu. T.</creatorcontrib><creatorcontrib>Berberova, N. T.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Petrosyan, V. S.</au><au>Milaeva, E. R.</au><au>Gracheva, Yu. A.</au><au>Grigoriev, E. V.</au><au>Tyurin, V. Yu</au><au>Pimenov, Yu. T.</au><au>Berberova, N. T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The promoting effect of organotin compounds upon peroxidation of oleic acid</atitle><jtitle>Applied organometallic chemistry</jtitle><addtitle>Appl. Organometal. Chem</addtitle><date>2002-11</date><risdate>2002</risdate><volume>16</volume><issue>11</issue><spage>655</spage><epage>659</epage><pages>655-659</pages><issn>0268-2605</issn><eissn>1099-0739</eissn><abstract>The effect of the organotin compounds R
nSnCl4−n (n = 1–3; where R = Me, Et, n‐Bu and Ph) upon oleic ((Z)‐9‐octadecenoic) acid oxidation by dioxygen has been studied at 25, 37, 65, and 95 °C. The promoting effect of organotins upon the formation of oleic acid hydroperoxides is temperature dependent and is at a maximum at a temperature close to the physiological one, but the impact of organotins upon oleic acid peroxidation decreases in the presence of 2,6‐di‐tert‐butylphenol. The role of organic free radicals derived from the SnC bond cleavage in the oxidation of oleic acid is discussed. Copyright © 2002 John Wiley & Sons, Ltd.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/aoc.360</doi><tpages>5</tpages></addata></record> |
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subjects | free radicals oleic acid organotin compounds peroxidation |
title | The promoting effect of organotin compounds upon peroxidation of oleic acid |
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