The promoting effect of organotin compounds upon peroxidation of oleic acid

The effect of the organotin compounds R nSnCl4−n (n = 1–3; where R = Me, Et, n‐Bu and Ph) upon oleic ((Z)‐9‐octadecenoic) acid oxidation by dioxygen has been studied at 25, 37, 65, and 95 °C. The promoting effect of organotins upon the formation of oleic acid hydroperoxides is temperature dependent...

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Veröffentlicht in:Applied organometallic chemistry 2002-11, Vol.16 (11), p.655-659
Hauptverfasser: Petrosyan, V. S., Milaeva, E. R., Gracheva, Yu. A., Grigoriev, E. V., Tyurin, V. Yu, Pimenov, Yu. T., Berberova, N. T.
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container_end_page 659
container_issue 11
container_start_page 655
container_title Applied organometallic chemistry
container_volume 16
creator Petrosyan, V. S.
Milaeva, E. R.
Gracheva, Yu. A.
Grigoriev, E. V.
Tyurin, V. Yu
Pimenov, Yu. T.
Berberova, N. T.
description The effect of the organotin compounds R nSnCl4−n (n = 1–3; where R = Me, Et, n‐Bu and Ph) upon oleic ((Z)‐9‐octadecenoic) acid oxidation by dioxygen has been studied at 25, 37, 65, and 95 °C. The promoting effect of organotins upon the formation of oleic acid hydroperoxides is temperature dependent and is at a maximum at a temperature close to the physiological one, but the impact of organotins upon oleic acid peroxidation decreases in the presence of 2,6‐di‐tert‐butylphenol. The role of organic free radicals derived from the SnC bond cleavage in the oxidation of oleic acid is discussed. Copyright © 2002 John Wiley & Sons, Ltd.
doi_str_mv 10.1002/aoc.360
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source Wiley Online Library Journals Frontfile Complete
subjects free radicals
oleic acid
organotin compounds
peroxidation
title The promoting effect of organotin compounds upon peroxidation of oleic acid
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