Aqueous Photoelectrochemical CO 2 Reduction to CO and Methanol over a Silicon Photocathode Functionalized with a Cobalt Phthalocyanine Molecular Catalyst

We report a precious-metal-free molecular catalyst-based photocathode that is active for aqueous CO reduction to CO and methanol. The photoelectrode is composed of cobalt phthalocyanine molecules anchored on graphene oxide which is integrated via a (3-aminopropyl)triethoxysilane linker to p-type sil...

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Veröffentlicht in:Angewandte Chemie International Edition 2023-01, Vol.62 (4), p.e202215213
Hauptverfasser: Shang, Bo, Rooney, Conor L, Gallagher, David J, Wang, Bernie T, Krayev, Andrey, Shema, Hadar, Leitner, Oliver, Harmon, Nia J, Xiao, Langqiu, Sheehan, Colton, Bottum, Samuel R, Gross, Elad, Cahoon, James F, Mallouk, Thomas E, Wang, Hailiang
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Sprache:eng
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