Ligand Fluorination to Mitigate the Raman Relaxation of Dy III Single-Molecule Magnets: A Combined Terahertz, Far-IR and Vibronic Barrier Model Study

The fast Raman relaxation process via a virtual energy level has become a puzzle for how to chemically engineer single-molecule magnets (SMMs) with better performance. Here, we use the trifluoromethyl group to systematically substitute the methyl groups in the axial position of the parent bis-butoxi...

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Veröffentlicht in:	Angewandte Chemie International Edition 2022-06, Vol.61 (26), p.e202206022
Hauptverfasser:	Ma, Yan, Zhai, Yuan-Qi, Luo, Qian-Cheng, Ding, You-Song, Zheng, Yan-Zhen
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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