Solvent-Switched Oxidation Selectivities with O 2 : Controlled Synthesis of α-Difluoro(thio)methylated Alcohols and Ketones

The solvent-switched hydroxylation and oxygenation of α-difluoro(thio)methylated carbanions with molecular oxygen under mild conditions are reported. This strategy tames the redox reactions of the in situ generated hydroperoxy difluoromethylsulfides, in which solvent-bonding can alter their reactivi...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-05, Vol.60 (21), p.12038-12045
Hauptverfasser:	Liu, Chi, Zhu, Chuanle, Cai, Yingying, Jiang, Huanfeng
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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