A Gas-Phase Ca n Mn 4-n O 4 + Cluster Model for the Oxygen-Evolving Complex of Photosystem II

One of the fundamental processes in nature, the oxidation of water, is catalyzed by a small CaMn O ⋅MnO cluster located in photosystem II (PS II). Now, the first successful preparation of a series of isolated ligand-free tetrameric Ca Mn O (n=0-4) cluster ions is reported, which are employed as stru...

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Veröffentlicht in:	Angewandte Chemie International Edition 2019-06, Vol.58 (25), p.8504-8509
Hauptverfasser:	Mauthe, Silvia, Fleischer, Irene, Bernhardt, Thorsten M, Lang, Sandra M, Barnett, Robert N, Landman, Uzi
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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