Inside Back Cover: Organocatalyzed Domino [3+2] Cycloaddition/Payne‐Type Rearrangement using Carbon Dioxide and Epoxy Alcohols (Angew. Chem. Int. Ed. 35/2018)

An organocatalytic domino process was developed towards elusive heterocyclic compounds that is based on the use of carbon dioxide and epoxy alcohols as reagents. In their Communication on page 11203 ff., A. W. Kleij and co‐workers report a process reminiscent of the well‐known Payne rearrangement of epoxides. Highly substituted epoxy alcohols first undergo substrate‐controlled CO2 activation, thereby forming a cyclic carbonate; this is followed by in situ base‐mediated carbonate isomerization and trapping of the desired product.