Pb 2 BO 3 Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation
A meticulously designed, polar, non‐centrosymmetric lead borate chloride, Pb 2 BO 3 Cl, was synthesized using KBe 2 BO 3 F 2 (KBBF) as a model. Single‐crystal X‐ray diffraction revealed that the structure of Pb 2 BO 3 Cl consists of cationic [Pb 2 (BO 3 )] + honeycomb layers and Cl − anions. Powder...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2016-09, Vol.55 (39), p.12078-12082 |
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| creator | Zou, Guohong Lin, Chensheng Jo, Hongil Nam, Gnu You, Tae‐Soo Ok, Kang Min |
| description | A meticulously designed, polar, non‐centrosymmetric lead borate chloride, Pb
2
BO
3
Cl, was synthesized using KBe
2
BO
3
F
2
(KBBF) as a model. Single‐crystal X‐ray diffraction revealed that the structure of Pb
2
BO
3
Cl consists of cationic [Pb
2
(BO
3
)]
+
honeycomb layers and Cl
−
anions. Powder second harmonic generation (SHG) measurements on graded polycrystalline Pb
2
BO
3
Cl indicated that the title compound is phase‐matchable (type I) and exhibits a remarkably strong SHG response, which is approximately nine times stronger than that of potassium dihydrogen phosphate, and the largest efficiency observed in materials with structures similar to KBBF. Further characterization suggested that the compound melts congruently at high temperature and has a wide transparency window from the near‐UV to the mid‐IR region. |
| doi_str_mv | 10.1002/anie.201606782 |
| format | Article |
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2
BO
3
Cl, was synthesized using KBe
2
BO
3
F
2
(KBBF) as a model. Single‐crystal X‐ray diffraction revealed that the structure of Pb
2
BO
3
Cl consists of cationic [Pb
2
(BO
3
)]
+
honeycomb layers and Cl
−
anions. Powder second harmonic generation (SHG) measurements on graded polycrystalline Pb
2
BO
3
Cl indicated that the title compound is phase‐matchable (type I) and exhibits a remarkably strong SHG response, which is approximately nine times stronger than that of potassium dihydrogen phosphate, and the largest efficiency observed in materials with structures similar to KBBF. Further characterization suggested that the compound melts congruently at high temperature and has a wide transparency window from the near‐UV to the mid‐IR region.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201606782</identifier><language>eng</language><ispartof>Angewandte Chemie International Edition, 2016-09, Vol.55 (39), p.12078-12082</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c842-f24a3c0dbecdcc4dc96cb5bac437b9584b9349fb23a6fd9c187af7b272b0a3d33</citedby><cites>FETCH-LOGICAL-c842-f24a3c0dbecdcc4dc96cb5bac437b9584b9349fb23a6fd9c187af7b272b0a3d33</cites><orcidid>0000-0002-7195-9089</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Zou, Guohong</creatorcontrib><creatorcontrib>Lin, Chensheng</creatorcontrib><creatorcontrib>Jo, Hongil</creatorcontrib><creatorcontrib>Nam, Gnu</creatorcontrib><creatorcontrib>You, Tae‐Soo</creatorcontrib><creatorcontrib>Ok, Kang Min</creatorcontrib><title>Pb 2 BO 3 Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation</title><title>Angewandte Chemie International Edition</title><description>A meticulously designed, polar, non‐centrosymmetric lead borate chloride, Pb
2
BO
3
Cl, was synthesized using KBe
2
BO
3
F
2
(KBBF) as a model. Single‐crystal X‐ray diffraction revealed that the structure of Pb
2
BO
3
Cl consists of cationic [Pb
2
(BO
3
)]
+
honeycomb layers and Cl
−
anions. Powder second harmonic generation (SHG) measurements on graded polycrystalline Pb
2
BO
3
Cl indicated that the title compound is phase‐matchable (type I) and exhibits a remarkably strong SHG response, which is approximately nine times stronger than that of potassium dihydrogen phosphate, and the largest efficiency observed in materials with structures similar to KBBF. Further characterization suggested that the compound melts congruently at high temperature and has a wide transparency window from the near‐UV to the mid‐IR region.</description><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNo9kMtKw0AYhQdRsFa3rv8XSJ1bMhN3bdBWqLTQ4jb8c4kdSTMyKUh3PoLP6JOYorg6B85l8RFyy-iEUcrvsAt-wikraKE0PyMjlnOWCaXE-eClEJnSObskV33_NvS1psWIuLUBDrMVCKjae5jCFkMb0_fn1zM6D-vYYoKlRwezmPDgodoNcRiij3DYwYtPR9gcUuxeYeNt7BwsMO1jFyzMfeeHSYjdNblosO39zZ-OyfbxYVstsuVq_lRNl5nVkmcNlygsdcZbZ610tiysyQ1aKZQpcy1NKWTZGC6waFxpmVbYKMMVNxSFE2JMJr-3NsW-T76p31PYYzrWjNYnRPUJUf2PSPwAgMdakA</recordid><startdate>20160919</startdate><enddate>20160919</enddate><creator>Zou, Guohong</creator><creator>Lin, Chensheng</creator><creator>Jo, Hongil</creator><creator>Nam, Gnu</creator><creator>You, Tae‐Soo</creator><creator>Ok, Kang Min</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-7195-9089</orcidid></search><sort><creationdate>20160919</creationdate><title>Pb 2 BO 3 Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation</title><author>Zou, Guohong ; Lin, Chensheng ; Jo, Hongil ; Nam, Gnu ; You, Tae‐Soo ; Ok, Kang Min</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c842-f24a3c0dbecdcc4dc96cb5bac437b9584b9349fb23a6fd9c187af7b272b0a3d33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zou, Guohong</creatorcontrib><creatorcontrib>Lin, Chensheng</creatorcontrib><creatorcontrib>Jo, Hongil</creatorcontrib><creatorcontrib>Nam, Gnu</creatorcontrib><creatorcontrib>You, Tae‐Soo</creatorcontrib><creatorcontrib>Ok, Kang Min</creatorcontrib><collection>CrossRef</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zou, Guohong</au><au>Lin, Chensheng</au><au>Jo, Hongil</au><au>Nam, Gnu</au><au>You, Tae‐Soo</au><au>Ok, Kang Min</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pb 2 BO 3 Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation</atitle><jtitle>Angewandte Chemie International Edition</jtitle><date>2016-09-19</date><risdate>2016</risdate><volume>55</volume><issue>39</issue><spage>12078</spage><epage>12082</epage><pages>12078-12082</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>A meticulously designed, polar, non‐centrosymmetric lead borate chloride, Pb
2
BO
3
Cl, was synthesized using KBe
2
BO
3
F
2
(KBBF) as a model. Single‐crystal X‐ray diffraction revealed that the structure of Pb
2
BO
3
Cl consists of cationic [Pb
2
(BO
3
)]
+
honeycomb layers and Cl
−
anions. Powder second harmonic generation (SHG) measurements on graded polycrystalline Pb
2
BO
3
Cl indicated that the title compound is phase‐matchable (type I) and exhibits a remarkably strong SHG response, which is approximately nine times stronger than that of potassium dihydrogen phosphate, and the largest efficiency observed in materials with structures similar to KBBF. Further characterization suggested that the compound melts congruently at high temperature and has a wide transparency window from the near‐UV to the mid‐IR region.</abstract><doi>10.1002/anie.201606782</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-7195-9089</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 2016-09, Vol.55 (39), p.12078-12082 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_anie_201606782 |
| source | Wiley Online Library Journals Frontfile Complete |
| title | Pb 2 BO 3 Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation |
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