Krypton Derivatization of an O 2 ‐Tolerant Membrane‐Bound [NiFe] Hydrogenase Reveals a Hydrophobic Tunnel Network for Gas Transport

[NiFe] hydrogenases are metalloenzymes catalyzing the reversible heterolytic cleavage of hydrogen into protons and electrons. Gas tunnels make the deeply buried active site accessible to substrates and inhibitors. Understanding the architecture and function of the tunnels is pivotal to modulating th...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-04, Vol.55 (18), p.5586-5590
Hauptverfasser:	Kalms, Jacqueline, Schmidt, Andrea, Frielingsdorf, Stefan, van der Linden, Peter, von Stetten, David, Lenz, Oliver, Carpentier, Philippe, Scheerer, Patrick
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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