CpRh III ‐Catalyzed Arylation of C(sp 3 )H Bonds
The first Cp*Rh III ‐catalyzed arylation of unactivated C(sp 3 )H bonds is presented. The unactivated primary C(sp 3 )H bond of 2‐alkylpyridines can be activated by Rh III and further reacts with triarylboroxines to efficiently build new C(sp 3 )aryl bonds. The methodology also provides a facile...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2015-08, Vol.54 (35), p.10280-10283 |
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| container_issue | 35 |
| container_start_page | 10280 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 54 |
| creator | Wang, Xiaoming Yu, Da‐Gang Glorius, Frank |
| description | The first Cp*Rh
III
‐catalyzed arylation of unactivated C(sp
3
)H bonds is presented. The unactivated primary C(sp
3
)H bond of 2‐alkylpyridines can be activated by Rh
III
and further reacts with triarylboroxines to efficiently build new C(sp
3
)aryl bonds. The methodology also provides a facile and efficient synthesis of unsymmetrical triarylmethanes by Rh
III
‐catalyzed C(sp
3
)H arylation of diarylmethanes. |
| doi_str_mv | 10.1002/anie.201503888 |
| format | Article |
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III
‐catalyzed arylation of unactivated C(sp
3
)H bonds is presented. The unactivated primary C(sp
3
)H bond of 2‐alkylpyridines can be activated by Rh
III
and further reacts with triarylboroxines to efficiently build new C(sp
3
)aryl bonds. The methodology also provides a facile and efficient synthesis of unsymmetrical triarylmethanes by Rh
III
‐catalyzed C(sp
3
)H arylation of diarylmethanes.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201503888</identifier><language>eng</language><ispartof>Angewandte Chemie International Edition, 2015-08, Vol.54 (35), p.10280-10283</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c239t-d5fbdb79e041b668a1b0825757d6698820e2d39ec63c24f5268417251f1999043</citedby><cites>FETCH-LOGICAL-c239t-d5fbdb79e041b668a1b0825757d6698820e2d39ec63c24f5268417251f1999043</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Wang, Xiaoming</creatorcontrib><creatorcontrib>Yu, Da‐Gang</creatorcontrib><creatorcontrib>Glorius, Frank</creatorcontrib><title>CpRh III ‐Catalyzed Arylation of C(sp 3 )H Bonds</title><title>Angewandte Chemie International Edition</title><description>The first Cp*Rh
III
‐catalyzed arylation of unactivated C(sp
3
)H bonds is presented. The unactivated primary C(sp
3
)H bond of 2‐alkylpyridines can be activated by Rh
III
and further reacts with triarylboroxines to efficiently build new C(sp
3
)aryl bonds. The methodology also provides a facile and efficient synthesis of unsymmetrical triarylmethanes by Rh
III
‐catalyzed C(sp
3
)H arylation of diarylmethanes.</description><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNo9z0FKxDAYBeAgCo6jW9dZ6qI1f9Ikf5ZjcZzCgCC6LmmTYKW2pemmrjyCd_Ag3sULeAVnUFy9t3g8-Ag5B5YCY_zKdo1POQPJBCIekAVIDonQWhzueiZEolHCMTmJ8Xm3R2RqQWQ-3D_Roijo19t7bifbzq_e0dU4t3Zq-o72geYXcaCCXn5_fG7odd-5eEqOgm2jP_vLJXlc3zzkm2R7d1vkq21Sc2GmxMlQuUobzzKolEILFUMutdROKYPImedOGF8rUfMsSK4wA80lBDDGsEwsSfr7W499jKMP5TA2L3acS2DlHl3u0eU_WvwAAvRI4Q</recordid><startdate>20150824</startdate><enddate>20150824</enddate><creator>Wang, Xiaoming</creator><creator>Yu, Da‐Gang</creator><creator>Glorius, Frank</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20150824</creationdate><title>CpRh III ‐Catalyzed Arylation of C(sp 3 )H Bonds</title><author>Wang, Xiaoming ; Yu, Da‐Gang ; Glorius, Frank</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c239t-d5fbdb79e041b668a1b0825757d6698820e2d39ec63c24f5268417251f1999043</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Xiaoming</creatorcontrib><creatorcontrib>Yu, Da‐Gang</creatorcontrib><creatorcontrib>Glorius, Frank</creatorcontrib><collection>CrossRef</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Xiaoming</au><au>Yu, Da‐Gang</au><au>Glorius, Frank</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>CpRh III ‐Catalyzed Arylation of C(sp 3 )H Bonds</atitle><jtitle>Angewandte Chemie International Edition</jtitle><date>2015-08-24</date><risdate>2015</risdate><volume>54</volume><issue>35</issue><spage>10280</spage><epage>10283</epage><pages>10280-10283</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>The first Cp*Rh
III
‐catalyzed arylation of unactivated C(sp
3
)H bonds is presented. The unactivated primary C(sp
3
)H bond of 2‐alkylpyridines can be activated by Rh
III
and further reacts with triarylboroxines to efficiently build new C(sp
3
)aryl bonds. The methodology also provides a facile and efficient synthesis of unsymmetrical triarylmethanes by Rh
III
‐catalyzed C(sp
3
)H arylation of diarylmethanes.</abstract><doi>10.1002/anie.201503888</doi><tpages>4</tpages></addata></record> |
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| title | CpRh III ‐Catalyzed Arylation of C(sp 3 )H Bonds |
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