Water in Organocatalytic Processes: Debunking the Myths

Water in Organocatalytic Processes: Debunking the Myths

All this talk of water: Aqueous‐based organocatalytic processes involve a complex set of parameters, and a holistic approach is the key to making informed decisions on the benefits on a case‐by‐case basis. A fundamental mechanistic understanding of the role of water in any reaction is necessary befo...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2007-01, Vol.46 (21), p.3798-3800
Hauptverfasser: Blackmond, Donna G., Armstrong, Alan, Coombe, Vyv, Wells, Andrew
Format: Artikel
Sprache:eng
Schlagworte:
aldol reaction
Amines - chemistry
asymmetric catalysis
Catalysis
green chemistry
organocatalysis
Water - chemistry
Water Pollution, Chemical - prevention & control
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:All this talk of water: Aqueous‐based organocatalytic processes involve a complex set of parameters, and a holistic approach is the key to making informed decisions on the benefits on a case‐by‐case basis. A fundamental mechanistic understanding of the role of water in any reaction is necessary before its general use in organocatalytic reactions may be advocated. Copyright of the picture (water drops 1): Adam Hart‐Davis.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200604952