Recognition of Anions through NHπ Hydrogen Bonds in a Bicyclic Cyclophane-Selectivity for Nitrate

A combination of geometric and electrostatic complemetarity explains why nitrate is bound only slightly less strongly than acetate within the bicyclic cyclophane 1, although nitrate is a significantly weaker base. The crystal structure of the acetate complex of 1 depicts the binding of the anion in...

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Veröffentlicht in:	Angewandte Chemie International Edition 1997-11, Vol.36 (21), p.2340-2342
Hauptverfasser:	Bisson, Adrian P., Lynch, Vincent M., Monahan, Mary-Katherine C., Anslyn, Eric V.
Format:	Artikel
Sprache:	eng
Schlagworte:	anion recognition cyclophanes host-guest chemistry hydrogen bonds
Online-Zugang:	Volltext
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