Synthesis of Rotaxanes by Brief Melting of Wheel and Axle Components

Synthesis of Rotaxanes by Brief Melting of Wheel and Axle Components

Fast and simple: Rotaxanes and pseudorotaxanes are synthesized by simply melting their wheel and axle components for one minute. The complementarity between the cavity of the wheel and the spatial demands of the stopper groups was designed to permit a temperature‐controlled “slipping off” process in...

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Veröffentlicht in:Angewandte Chemie International Edition 1997-06, Vol.36 (11), p.1199-1201
Hauptverfasser: Händel, Mirko, Plevoets, Marcus, Gestermann, Sven, Vögtle, Fritz
Format: Artikel
Sprache:eng
Schlagworte:
macrocycles
mechanical binding
rotaxanes
supramolecular chemistry
synthetic methods
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container_end_page 1201
container_issue 11
container_start_page 1199
container_title Angewandte Chemie International Edition
container_volume 36
creator Händel, Mirko
Plevoets, Marcus
Gestermann, Sven
Vögtle, Fritz
description Fast and simple: Rotaxanes and pseudorotaxanes are synthesized by simply melting their wheel and axle components for one minute. The complementarity between the cavity of the wheel and the spatial demands of the stopper groups was designed to permit a temperature‐controlled “slipping off” process in solution.
doi_str_mv 10.1002/anie.199711991
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source Wiley Online Library - AutoHoldings Journals
subjects macrocycles
mechanical binding
rotaxanes
supramolecular chemistry
synthetic methods
title Synthesis of Rotaxanes by Brief Melting of Wheel and Axle Components
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