Synthesis of Rotaxanes by Brief Melting of Wheel and Axle Components

Synthesis of Rotaxanes by Brief Melting of Wheel and Axle Components

Fast and simple: Rotaxanes and pseudorotaxanes are synthesized by simply melting their wheel and axle components for one minute. The complementarity between the cavity of the wheel and the spatial demands of the stopper groups was designed to permit a temperature‐controlled “slipping off” process in...

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Veröffentlicht in:Angewandte Chemie International Edition 1997-06, Vol.36 (11), p.1199-1201
Hauptverfasser: Händel, Mirko, Plevoets, Marcus, Gestermann, Sven, Vögtle, Fritz
Format: Artikel
Sprache:eng
Schlagworte:
macrocycles
mechanical binding
rotaxanes
supramolecular chemistry
synthetic methods
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Beschreibung
Zusammenfassung:Fast and simple: Rotaxanes and pseudorotaxanes are synthesized by simply melting their wheel and axle components for one minute. The complementarity between the cavity of the wheel and the spatial demands of the stopper groups was designed to permit a temperature‐controlled “slipping off” process in solution.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199711991