Dialdehyde + Diamine-Polymer or Macrocycle?

Dialdehyde + Diamine-Polymer or Macrocycle?

The 24‐membered macrocycle 1 is surprisingly generated from (S)‐2,2′‐dihydroxy‐1,1′‐binaphthyl‐3,3′‐dialdehyde [(S)‐(2)] and (R,R)‐1,2‐diamino‐1,2‐diphenylethane, whereas in the same reaction (R)‐2 yields the polymeric Schiff base as expected. Macrocycle 1 can be used for an economical and simple en...

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Veröffentlicht in:Angewandte Chemie (International ed.) 1994-01, Vol.33 (1), p.125-126
Hauptverfasser: Brunner, Henri, Schiessling, Hubert
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Sprache:eng
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Chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings
Organic chemistry
Preparations and properties
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container_title Angewandte Chemie (International ed.)
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creator Brunner, Henri
Schiessling, Hubert
description The 24‐membered macrocycle 1 is surprisingly generated from (S)‐2,2′‐dihydroxy‐1,1′‐binaphthyl‐3,3′‐dialdehyde [(S)‐(2)] and (R,R)‐1,2‐diamino‐1,2‐diphenylethane, whereas in the same reaction (R)‐2 yields the polymeric Schiff base as expected. Macrocycle 1 can be used for an economical and simple enantiomeric resolution of 2.
doi_str_mv 10.1002/anie.199401251
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subjects Chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings
Organic chemistry
Preparations and properties
title Dialdehyde + Diamine-Polymer or Macrocycle?
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